Abstract
Allanite from the Tertiary Rieserferner pluton (Austrian Alps) is texturally and chemically heterogeneous. Continuous covariation trends reflect coupled substitution of Ca+Al vs. Fe+REE+Th in allanite, whereas systematic variations in La/Nd demonstrate the increasingly stronger depletion of LREE in the melt during its crystallization. Allanite samples (corrected for 206Pbexcess) from two rocks scatter in the concordia diagram and define discordias from 31.8±0.4 Ma and 32.2±0.4 Ma to ca. 540 Ma. The apparent inheritance does not originate from the inclusion of older allanite or a high-μ phase, such as monazite, xenotime, or zircon, but from the incorporation of radiogenic Pb originating from a precursor. Since allanite requires a high enrichment of Th, (U), and LREE, it may form at the expense of a Th-LREE-rich precursor in metamorphic rocks or where such a phase had dissolved in melts. Likely precursors acquire with time radiogenic Pb isotopic compositions. This Pb, if incorporated in the product mineral, may give the illusion of inheritance. The allanite samples from the Rieserferner pluton show a tendency from high Th/Ucalc (30–50) in samples with an Alpine age to low Th/Ucalc (4–12) in samples with distinct inheritance. This relation between extent of inheritance and apparent Th/Ucalc indicates a lower Th/Ucalc for a possible precursor, falling into the Th/U range commonly encountered for monazite. Precursor monazite would have originated from assimilated Palaeozoic rocks and give rise to localized enrichments of Th and LREE in the melt, thus eventually enabling the growth of allanite.
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References
Barth S, Oberli F, Meier M (1989) U-Th-Pb systematics of morphologically characterized zircon and allanite: a high-resolution isotopic study of the Alpine Rensen pluton (northern Italy). Earth Planet Sci Lett 95:235–254
Barth S, Oberli F, Meier M (1994) Th-Pb versus U-Pb isotope systematics in allanite from co-genetic rhyolite and granodiorite: implications for geochronology. Earth Planet Sci Lett 124:149–159
Bellieni G (1978) Caratteri geochimici del massicco granodioritico tonalitico delle Vedrette di Ries (Rieserferner)-Alto Adige Orientale. Rend Soc Ital Min Petrol 34:527–548
Bellieni G, Cavazzini G, Fioretti A, Peccerillo A, Poli G, Zantedeschi P (1984) Petrology and geochemistry of microgranular mafic enclaves from the Vendrette di Ries plutonic complex (Eastern Alps). Periodico Miner 58:45–65
Bellieni G, Chiaromonti PC, Visona D (1976) Contributo alla conscenza del plutone delle Vedrette di Ries (Alpe Orientali). Boll Soc Geol Ital 95:351–370
Bellieni G, Peccerillo A, Poli G (1981) The Vedrette di Ries (Riesrferner) plutonic complex; petrological and geochemical data bearing on its genesis. Contrib Mineral Petrol 78:145–156
Bögel H, Schmidt K (1976) Kleine Geologie der Ostalpen. Ott Verlag, Thun, 231 pp
Borsi S, Del Moro A, Sassi FP, Zirpoli G (1979) On the age of the Vedrette di Ries (Rieserferner) massif and its geodynamic significance. Geol Rundsch 68:41–60
Cesare B (1992) Metamorfismo di contatto di rocce pelitiche nell’ aureola di Vedrette di Ries (Alps Orientali, Italy). Atti Ticinensi Scei Terra 35:1-7
Davis DW, Schandl ES, Wasteneys HA (1994) U-Pb dating of mineral alteration in halos of Superior Province massive sulfide deposits: syngenesis versus metamorphism. Contrib Mineral Petrol 115:427–437
Del Moro A, Ferrara G, Tonarini S, Callegari E (1983) Rb/Sr and K/Ar chronology of Adamello granitoids, Southern Alps. Mem Soc Geol Ital 26:285–299
Ferry JM (2000) Patterns of mineral occurrence in metamorphic rocks. Am Mineral 85:1573–1588
Finger F, Broska I, Roberts MP, Schermaier A (1998) Replacement of primary monazite by apatite-allanite-epidote coronas in an amphibolite facies granite gneiss from the Eastern Alps. Am Mineral 83:248–258
Förster H-J (1998) The chemical composition of REE-Y-Th-U-rich accessory minerals in peraluminous granites of the Erzgebirge-Fichtelgebirge region, Germany, Part I: The monazite-(Ce)-brabantite solid solution series. Am Mineral 83:259–272
Gerstenberger H, Haase G (1997) A highly effective emitter substance for mass spectrometric Pb isotope ratio determinations. Chem Geol 136:309–312
Hansmann W, Oberli F (1991) Zircon inheritance in an igneous rock suite: Implications for the petrogenesis of the southern Adamello batolith (Italian Alps). Contrib Mineral Petrol 107:501–518
Hawkins DP, Bowring SA (1997) U-Pb systematics of monazite and xenotime: case studies from the Paleoproterozoic of the Grand Canyon, Arizona. Contrib Mineral Petrol 127:87–103
Jaffey AH, Flynn KF, Glendenin LE, Bentley WC, Essling AM (1971) Precision measurement of half-lives and specific activities of 235U and 238U. Phys Rev C4:1889–1906
Lanzirotti A, Hanson GN (1995) U-Pb dating of major and accessory minerals formed during metamorphism and deformation of metapelites. Geochim Cosmochim Acta 59:2513–2526
Lanzirotti A, Hanson GN (1996) Geochronology and geochemistry of multiple generations of monazite from the Wepawaug Schist, Connecticut, USA: implications for monazite stability in metamorphic rocks. Contrib Mineral Petrol 125:332–340
Mager M (1985) Geologische und petrographische Untersuchungen am Südrand des Rieserferner Plutons (Südtirol) unter Berücksichtigung des Intrusionsmechanismus. PhD Thesis, University Erlangen-Nürnberg
Manhès G, Minster JF, Allègre CJ (1978) Comparative uranium-thorium-lead and rubidium-strontium study of the Saint Séverin amphoterite: consequences for early solar system chronology. Earth Planet Sci Lett 39:14–24
Müller W, Mancktelow NS, Meier M (2000) Rb-Sr. Microchrons of synkinematic mica in mylonites: an example from the DAV-fault of the Eastern Alps. Earth Planet Sci Lett 180:385–397
Pan Y (1997) Zircon- and monazite-forming metamorphic reactions at Manitowadge, Ontario. Can Mineral 35:105–118
Poitrasson F (2002) In situ investigation of allanite hydrothermal alteration: examples from calc-alkaline and anorogenic granites of Corsica (southeast France). Contrib Mineral Petrol 142: 485–500
Romer RL (2001) Lead incorporation during crystal growth and the misinterpretation of geochronological data from low-238U/204Pb metamorphic minerals. Terra Nova 13:258–263
Romer RL, Rötzler J (2001) P–T-t evolution of ultrahigh-temperature granulites from the Saxon Granulite Massif, Germany. Part II: Geochronology. J Petrol 42:2015–2032
Romer RL, Rötzler J (2003) Effect of metamorphic reaction history on the U-Pb dating of titanite. Geol Soc Lond Spec Publ 220:147–158
Romer RL, Schärer U, Steck A (1996) Alpine and pre-Alpine magmatism in the root-zone of the western Central Alps. Contrib Mineral Petrol 123:138–158
Rosenberg C, Berger A, Schmid SM (1995) Observations from the floor of a granitoid pluton: inferences on the driving force of final emplacement. Geology 23:443–446
Schärer U (1984) The effect of initial 230Th disequilibrium on young U-Pb ages: the Makalu case, Himalaya. Earth Planet Sci Lett 67:191–204
Schärer U, Allègre CJ (1983) The Palung granite (Himalaya); high-resolution U-Pb systematics in zircon and monazite. Earth Planet Sci Lett 63:423–432
Schmid SM, Aebli HR, Heller F, Zingg A (1989) The role of the Periadriatic Line in the tectonic evolution of the Alps. In: Coward MP, Dietrich D, Park RG (eds) Alpine tectonics. Geol Soc Lond Spec Publ 45:153–171
Schönhofer R (1999) Das ostalpine Altkristallin der westlichen Lasörlinggruppe (Osttirol, Österreich): Kartierung, Stoffbestand und tektonometamorphe Entwicklung. Erlanger Geol Abh 130:1-128
Schulz B, Nollau G, Heinisch H, Godizart G (1993) Austro-Alpine basement complex to the south of the Tauern Window. In: von Raumer JF, Neubauer F (eds) Pre-Mesozoic geology of the Alps. Springer, Berlin Heidelberg New York, pp 495–514
Schulz B, Siegesmund S, Steenken A, Schönhofer R, Heinrichs T (2001) Geologie des Altkristallins südlich des Tauernfensters zwischen Virgen und Pustertal. Z Dtsch Geol Ges 152:261–307
Steenken A, Siegesmund S, Heinrichs T (2000) The emplacement of the Rieserferner pluton (Eastern Alps, Tyrol): Constraints from field observations, magnetic fabrics and microstructures. J Struct Geol 22:1855–1873
Steiger RH, Jäger E (1977) Subcommission of geochronology: Convention on the use of decay constants in geo- and cosmochronology. Earth Planet Sci Lett 36:359–362
Tilton GR (1973) Isotopic lead ages of chondritic meteorites. Earth Planet Sci Lett 19:321–329
von Blanckenburg F (1992) Combined high-precision chronometry and geochemical tracing using accessory minerals: applied to the Central-Alpine Bergell intrusion (central Europe). Chem Geol 100:19–40.
von Blanckenburg F, Davis JH (1996) Feasibility of double slab breakoff (Cretaceous and Tertiary) during the Alpine convergence. Eclogae Geol Helv 89:111–127
von Raumer JF, Neubauer F (1993) Late Precambrian and Palaeozoic evolution of the Alpine basement—an overview. In: von Raumer JF, Neubauer F (eds) Pre-Mesozoic geology of the Alps. Springer, Berlin Heidelberg New York, pp 625-639
Wang J, Tatsumoto M, Li X, Premo WR, Chao ECT (1994) A precise 232Th-208Pb chronology of fine-grained monazite: Age of Bayan Obo REE-Fe-Nb ore deposit, China. Geochim Cosmochim Acta 58:3155–3169
Acknowledgments
We thank Sten Littmann (GFZ Potsdam) for his work with the electron-microprobe, Andre Steenken (Göttingen) for the mineral separation, and Catrin Schulz (GFZ Potsdam) for help with the sample preparation in the clean laboratory. Fritz Finger (Salzburg) and Felix Oberli (ETH Zürich) provided detailed and constructive reviews. We gratefully appreciate their efforts that eventually resulted in a more focused presentation.
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Romer, R.L., Siegesmund, S. Why allanite may swindle about its true age. Contrib Mineral Petrol 146, 297–307 (2003). https://doi.org/10.1007/s00410-003-0494-6
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DOI: https://doi.org/10.1007/s00410-003-0494-6