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Synthesis of succinylated carboxymethyl starches and their role as adsorbents for the removal of phenol

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Abstract

Phenol is the toxicant present in cigarette smoke that causes pulmonary diseases, eyes infection, and even various kinds of cancer. So, in this research, an attempt was done to prepare a suitable absorbent to remove phenol from cigarette smoke. A novel bio-based adsorbent succinylated carboxymethyl starch (S-CMS) was prepared by reacting carboxymethyl starch (CMS) with succinic anhydride (SA) in the presenting of N, N-dimethylformamide (DMF) solvent and pyridine. The structure of the S-CMS was confirmed by spectroscopic techniques including proton nuclear magnetic resonance and Fourier transform infrared. The S-CMS crystallinity and thermal properties were checked by x-ray diffraction and thermogravimetric analysis. The results showed a decrease in thermal properties and crystallinity for S-CMS. The S-CMS were tested as adsorbents for the removal of phenol. The adsorption efficiencies of CMS, S-CMS1, S-CMS2, and S-CMS3 towards phenol were shown to be 0.297 g/g, 0.321 g/g, 0.322 g/g, and 0.324 g/g, respectively.

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Authors and Affiliations

  1. State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, 310027, People’s Republic of China

    Fazal Haq, Haojie Yu, Li Wang, Sahid Mehmood, Muhammad Haroon,  Bilal-Ul-Amin, Md Alim Uddin, Shah Fahad & Di Shen

  2. Oncological Surgery and Cancer Center, The First Affiliated Hospital, Zhejiang University, Hangzhou, 310003, People’s Republic of China

    Lison Teng

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  1. Fazal Haq
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  2. Haojie Yu
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Haq, F., Yu, H., Wang, L. et al. Synthesis of succinylated carboxymethyl starches and their role as adsorbents for the removal of phenol. Colloid Polym Sci 299, 1833–1841 (2021). https://doi.org/10.1007/s00396-021-04901-x

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  • DOI: https://doi.org/10.1007/s00396-021-04901-x

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