Skip to main content
SpringerLink
Log in

Preparation of high oxygen permeable transparent hybrid copolymers with silicone macro-monomers

  • Short Communication
  • Published:
Colloid and Polymer Science Aims and scope Submit manuscript

Abstract

In this study, high oxygen permeable transparent hybrid copolymers were prepared with hydrophilic monomer such as 2-hydroxyethylmethacrylate (HEMA) or N,N-dimethylacrylamide (DMAA) and mono- or difunctional silicone macro-monomer introduced methacryl groups. In HEMA-based hybrid copolymers, difunctional silicone macro-monomer and ethylene glycol dimethacrylate (EGDMA) as cross-linker were required in order to prepare transparent hybrid materials, while high transparent DMAA-based hybrid copolymers could be prepared without EGDMA cross-linker. The polymerization kinetics investigation revealed that this difference between HEMA and DMAA in preparation condition to transparent hybrid material originated to monomer reactivity in copolymerization and DMAA showed high reactivity compared with HEMA. Moreover, DMAA-based hybrid copolymers indicated high water content and high oxygen permeability as against HEMA-based hybrid copolymers because of its low cross-linking density.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4

References

  1. Redondo SUA, Radovanovic E, Torriani IL, Yoshida IVP (2001) Polymer 42:1319

    Article  CAS  Google Scholar 

  2. Senthilkumar U, Reddy BSR (2004) J Membr Sci 232:73

    Article  CAS  Google Scholar 

  3. Zielecka M, Bujnowska E (2006) Prog Org Coat 55:160

    Article  CAS  Google Scholar 

  4. Kumar SA, Balakrishnan T, Alagar M, Denchev Z (2006) Prog Org Coat 55:207

    Article  Google Scholar 

  5. Madhaven K, Reddy BSR (2006) J Membr Sci 283:357

    Article  Google Scholar 

  6. Kanai T, Mahato TK, Kumar D (2007) Prog Org Coat 58:259

    Article  CAS  Google Scholar 

  7. Tiwari A, Zhu J, Hihara LH (2008) Surf Coat Technol 202:4620

    Article  CAS  Google Scholar 

  8. Inoue H, Matsumoto A, Matsukawa K, Ueda A, Nagai S (1990) J Appl Polym Sci 41:1815

    Article  CAS  Google Scholar 

  9. Smith SD, Desimone JM, Huang H, York G, Dweight DW, Wilkes GL, McGrath JE (1992) Macromolecules 25:2575

    Article  CAS  Google Scholar 

  10. Chen SH, Lee MH, Lai JY (1996) Eur Polym J 32:1403

    Article  CAS  Google Scholar 

  11. Vlad S, Vlad A, Oprea S (2002) Eur Polym J 38:829

    Article  CAS  Google Scholar 

  12. Nakagawa T, Nishimura T, Higuchi A (2002) J Membr Sci 206:149

    Article  CAS  Google Scholar 

  13. Seon M, Kim SJ, Kim IY, Kim NG, Song CG, Kim SI (2002) J Appl Polym Sci 85:957

    Article  Google Scholar 

  14. Ma CCM, Du YC, Wang FY, Wang HC, Yang JC (2002) J Appl Polym Sci 83:1875

    Article  CAS  Google Scholar 

  15. Ma CCM, Wang FY, Du YC, Wu CL, Chiang CL, Hung AYC (2002) J Appl Polym Sci 86:962

    Article  CAS  Google Scholar 

  16. Hou Y, Tulevski GS, Valint JPL, Gardella JA (2002) Macromolecules 35:5953

    Article  CAS  Google Scholar 

  17. Chuai C, Li S, Almdal K, Alstrup J, Lyngaae-Jorgensen J (2004) J Appl Polym Sci 92:2747

    Article  CAS  Google Scholar 

  18. Ma M, Hill RM, Lowery JL, Fridrikh SV, Rutledge GC (2005) Langmur 21:5549

    Article  CAS  Google Scholar 

  19. Li Z, Han W, Kazodaev D, Brokken-Zijp JCM, Gijsbertus W, Thűne PC (2006) Polymer 47:1150

    Article  CAS  Google Scholar 

  20. Dong J, Liu Z, Cao X, Zhang C (2006) J Appl Polym Sci 101:2565

    Article  CAS  Google Scholar 

  21. Dong J, Liu Z, Feng Y, Zheng C (2006) J Appl Polym Sci 100:1547

    Article  CAS  Google Scholar 

  22. Kim MS, Lee GH, Hong JM, Lee H (2007) Mater Sci Eng C 27:1247

    Article  CAS  Google Scholar 

  23. Sonnenschein MF, Webb SP, Wendt BL (2008) Int J Adhes Adhes 28:126

    Article  CAS  Google Scholar 

  24. Ciolino AE, Gomez LR, Vega DA, Villar MA, Valles EM (2008) Polymer 49:5191

    Article  CAS  Google Scholar 

  25. Daimatsu K, Anno Y, Sugimoto H, Nakanishi E, Inomata K, Ikeda T, Yokoi K (2007) J Appl Polym Sci 108:362

    Article  Google Scholar 

  26. Nicolson PC, Vogt J (2001) Biomaterials 22:3273

    Article  CAS  Google Scholar 

  27. Tranodis I, Efron N (2004) Contact Lens & Anterior Eye 27:177

    Article  Google Scholar 

  28. Goda T, Watanabe J, Takai M, Ishihara K (2006) Polymer 47:1390

    Article  CAS  Google Scholar 

  29. Karlgard CCS, Sarkar DK, Jones LW, Moresoli C, Leung KT (2004) Appl Surf Sci 230:106

    Article  CAS  Google Scholar 

  30. Foulks GN (2006) Am J Ophthalmol 141:369

    Article  Google Scholar 

  31. Guillon M, Maissa C (2007) Contact Lens & Anterior Eye 30:5

    Article  Google Scholar 

  32. Efron N, Morgan PB, Cameron ID, Brennan NA, Goodwin M (2007) Optom Vis Sci 84:328

    Article  Google Scholar 

  33. Lai YC (1995) J Appl Polym Sci 56:301

    Article  CAS  Google Scholar 

  34. Madkour TM (2000) Polymer 41:7489

    Article  CAS  Google Scholar 

  35. Takahashi S, Nakagawa T, Yoshida M, Asano M (2002) J Membr Sci 206:165

    Article  CAS  Google Scholar 

  36. Chekina NA, Pavlyuchenko VN, Danilichev VF, Ushakov NA, Novikov SA, Ivanchev SS (2006) Polym Adv Technol 17:872

    Article  CAS  Google Scholar 

  37. Karunakaran R, Kennedy JP (2007) J of Polym Sci Part A: Polym Chem 45:308

    Article  CAS  Google Scholar 

  38. Bradrup J, Immergut EH, Grulke EA (ed) (1999) Polymer handbook, 4th edn, Vol. 1, Section II. Willy-Interscience, New York

  39. Ruiz-Trevino FA, Paul DR (1998) J Appl Polym Sci 68:403

    Article  CAS  Google Scholar 

  40. Jian XG, Dai Y, Zeng L, Xu RX (1999) J Appl Polym Sci 71:2385–2390

    Article  CAS  Google Scholar 

  41. Compan V, Tiemblo P, Garcia F, Garcia JM, Guzman J, Riande E (2005) Biomaterials 26:3783

    Article  CAS  Google Scholar 

  42. Lin H, Kai T, Freeman BD, Kalakkunnath S, Kalika DS (2005) Macromolecules 38:8381

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya, 466-8555, Japan

    Hideki Sugimoto, Go Nishino, Naoki Tsuzuki, Kazuki Daimatsu, Katsuhiro Inomata & Eiji Nakanishi

Authors
  1. Hideki Sugimoto
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Go Nishino
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Naoki Tsuzuki
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Kazuki Daimatsu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Katsuhiro Inomata
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Eiji Nakanishi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Hideki Sugimoto.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sugimoto, H., Nishino, G., Tsuzuki, N. et al. Preparation of high oxygen permeable transparent hybrid copolymers with silicone macro-monomers. Colloid Polym Sci 290, 173–181 (2012). https://doi.org/10.1007/s00396-011-2538-1

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00396-011-2538-1

Keywords

Search

Navigation