Abstract
We present a compositional analysis of different copper ore samples collected from Baluchistan, Pakistan. The qualitative as well as quantitative analysis was performed using laser-induced breakdown spectroscopy (LIBS) and laser ablation time-of-flight mass spectrometer (LA-TOF-MS). The laser-produced plasma on the surface of the samples was generated by focusing a high-power Nd: YAG laser and the time-integrated optical emission spectra were recorded using a set of four spectrometers coupled and equipped with charged coupled device (CCD). We used the Calibration-free laser-induced breakdown spectroscopy (CF-LIBS) for the quantitative determination of major and trace elements present in different ore samples. The quantitative analysis of these samples was also performed using LA-TOF-MS. Fifteen elements including lithium, sodium, magnesium, aluminum, silicon, potassium, calcium, manganese, titanium, iron, copper, zinc, silver, strontium and barium with varying concentrations have been detected in the optical emission spectra. Both the techniques, LIBS through CF and LA-TOF-MS, independently yield quantitative results that are in good agreement. It is demonstrated that LIBS and LA-TOF-MS are complementary, non-destructive and efficient techniques that can be used to analyze any solid material in a short time.
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Geological, Survey of Pakistan. http://www.gsp.gov.pk/index.php. Accessed 2018
The mineral industry, of Pakistan http://www.minerals.usgs.gov. 2011. Retrieved 2013-06-25
Magic Mountains, The Reko Diq gold and copper mining project. Herald (Pakistan). 11 November 2015. Retrieved 14 February 2016
R. Noll, C.F. Begemann, M. Brunk, S. Connemann, C. Meinhardt, M. Scharun, V. Sturm, J. Makowe, C. Gehlen, Spectrochim. Acta Part B 93, 41–51 (2014)
R. Noll, H. Bette, A. Brysch, M. Kraushaar, I. Monch, L. Peter, V. Sturm, Spectrochim. Acta Part B 56, 637–649 (2001)
D. Bulajic, G. Cristoforetti, M. Corsi, M. Hidalgo, S. Legnaioli, V. Palleschi, J. Martins, J. McKay, B. Tozer, D. Wells, R. Wells, M.A. Harith, A. Salvetti, E. Tognoni, S. Green, D. Bates, A. Steiger, J. Fonseca, Spectrochim. Acta Part B 57, 1181–1192 (2001)
I. Bassiotis, A. Diamantopoulou, A. Giannoudakos, F.R. Kalantzopoulou, M. Kompitsas, Spectrochim. Acta Part B 56, 671–683 (2001)
M.D. Mowery, R. Sing, J. Kirsch, A. Razaghi, S. Bechard, R.A. Reed, J. Pharm. Biomed. Anal. 28, 935–943 (2002)
V.K. Singh, A.K. Rai, Lasers Med. Sci. 26, 673–687 (2001)
M.A. Baig, A. Qamar, M.A. Fareed, M. Anwar-ul-Haq, R. Ali, Phys. Plasma 19, 063304 (2012)
E. Asamoah, Y. Hongbing, Appl. Phys. B 123, 22 (2017)
S. Hafeez, N.M. Sheikh, B. Rashid, M.A. Baig, J. Appl. Phys. 103, 083117 (2008)
J.M. Gomba, C.D. Angelo, D. Bertuccelli, Spectrochim. Acta Part B 56, 695–705 (2001)
B. Charfi, M.A. Harith, Spectrochim. Acta B 54, 1141–1153 (2002)
W.T.Y. Mohamed, Opt. Appl. 37, 1–2 (2007)
V. Hohreiter, D.W. Hahn, Anal. Chem. 77, 1118–1124 (2005)
D.A. Cremers, L.J. Radziemski, New York: Wiley (2006)
W. Demtroeder, Atoms molecules and photons. Heidelberg: Springer (2006)
J.A. Aguilera, C. Aragon, Spectrochimica. Acta B 59, 1861–1876 (2004)
J. Sneddon, T.L. Thiem, Y.I. Lee (eds.), Lasers in analytical atomic spectroscopy (Wiley, New York, 1997), pp. 197–235
W.B. Brinckerhoff, G.G. Managadze, R.W. McEntire, A.F. Cheng, W. Green, J. Rev. Sci. Instrum. 71, 536 (2000)
K. Tanaka, N. Shirai, Appl. Surf. Sci. 135, 163–168 (1988)
D.W. Beekman, N. Thonnard, Inst. Phys. 94, 163 (1988)
L.A. King, I.B. Gornushkin, D. Pappas, B.W. Smith, J.D. Winefordner, Spectrochim. Acta Part B 54, 1771–1781 (1999)
K. Song, K.H. Hong, M. Yang, H. Cha, J. Lee, Korean Phys. Soc. 35, 217 (1999)
C.K. Piyadasa, P. Hakansson, T.R. Ariyaratne, Rapid Commun. Mass Spectrom. 13, 620 (1999)
A.A. Specht, M.W. Blades, Am. Soc. Mass Spectrom. 14, 562 (2003)
Y.M. Koo, Y.K. Choi, K.H. Lee, K.W. Jung, Bull. Korean Chem. Soc. 23, 309 (2002)
A. Ciucci, M. Corsi, V. Palleschi, S. Rastelli, A. Salvetti, E. Tognoni, Appl. Spectrosc. 53, 960–964 (1999)
N. Ahmed, Z.A. Umar, R. Ahmed, M.A. Baig, Spectrochim. Acta Part B 136, 39–44 (2017)
J. Iqbal, S. Mahmood, I. Tufail, H. Asghar, R. Ahmed, M.A. Baig, Spectrochim. Acta B. 111, 80–86 (2015)
N.M. Shaikh, S. Hafeez, M.A. Kalyar, R. Ali, M.A. Baig, J. Appl. Phys. 104, 103108 (2008)
N. Ahmed, R. Ahmed, Z.A. Umar, M.A. Baig, Laser Phys. 27, 086001 (2017)
N. Ahmed, R. Ahmed, M.A. Baig, Plasma Chem. Plasma Process. 38, 207–222 (2018)
NIST database, http://physics.nist.gov/PhysRefData/ASD/lines_form.html (2017). Accessed 2018
N. Ahmed, M. Abdullah, R. Ahmed, N.K. Piracha, M.A. Baig, Laser Phys. 28, 016002 (2018)
L. Sun, H. Yu, Talanta 79, 388–395 (2009)
J.A. Aguilera, C. Aragon, J. Phys. 59, 210–217 (2007)
D. Veža, XV Summer School and International Symposium on the physics of ionized gases, Dubrovnik. Zagreb: Institute of Physics of the University (1990) 340–341
N. Konjevic, J. Phys. Chem. Ref. Data. 31, 3 (1990)
M.A. Gigososa, M.A. Gnzalezb, V. Cardenoso, Spectrochim. Acta Part B 58, 1489–1504 (2003)
V.K. Unnikrishnan, K. Mridul, R. Nayak, K. Alti, V.B. Kartha, C. Santhosh, G.P. Gupta, Pramana J. Phys. 79, 299–310 (2012)
R.W.P. McWhirter, Plasma diagnostic techniques, ed. by R.H. Huddlestone, S.L. Leonard (New York, Academic, 1965)
G. Cristoforetti, A. De Giacomo, M. Dell’Aglio, S. Legnaioli, E. Togoni, V. Palleschi, N. Omenetto, Spectrochim. Acta Part B 65, 86–95 (2010)
G. Cristoforetti, E. Tognoni, L.A. Gizzi, Spectrochim. Acta Part B 90, 1–22 (2013)
Q. Abbass, N. Ahmed, R. Ahmed, M.A. Baig, Plasma Chem. Plasma Process. 36, 1287–1299 (2016)
B. Praher, V. Palleschi, R. Viskup, J. Heitz, J.D. Pedarnig, Spectrochim. Acta Part B 65, 671–679 (2010)
D. Diaz, A. Molina, D. Hahn, Spectrochim. Acta Part B 145, 86–95 (2018)
Acknowledgements
We are grateful to the Pakistan Academy of Sciences (PAS) and National Centre for Physics (NCP) for the financial assistance to acquire the laser system and for the fabrication of the laser ablation time-of-flight spectrometer.
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Ahmad, N., Ahmed, R., Umar, Z.A. et al. Qualitative and quantitative analyses of copper ores collected from Baluchistan, Pakistan using LIBS and LA-TOF-MS. Appl. Phys. B 124, 160 (2018). https://doi.org/10.1007/s00340-018-7032-8
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DOI: https://doi.org/10.1007/s00340-018-7032-8