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TiO2 quantum dots grown on graphene by atomic layer deposition as advanced photocatalytic hybrid materials

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Abstract

The interfacial charge transfer phenomenon between atomic layer deposition (ALD) TiO2 and graphene substrate was investigated. A significant photocatalytic enhancement of TiO2 quantum dots/graphene hybrid nanocomposite over P25 TiO2 and TiO2 ALD film/graphene was observed. A control experiment with a conformal Al2O3 ALD film between ALD TiO2 film and graphene substrates provides direct evidences for this photocatalytic enhancement.

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References

  1. J. Zhang, Q. Xu, Z. Feng, M. Li, C. Li, Angew. Chem. Int. Ed. 47, 1766 (2008)

    Article  Google Scholar 

  2. M. Ni, M.K.H. Leung, D.Y.C. Leung, K. Sumathy, Renew. Sustain. Energy Rev. 11, 401 (2007)

    Article  Google Scholar 

  3. K. Zhou, Y. Zhu, X. Yang, X. Jiang, C. Li, New J. Chem. 35, 353 (2011)

    Article  Google Scholar 

  4. E. Kowalska, H. Remita, C. Colbeau-Justin, J. Hupka, J. Belloni, J. Phys. Chem. C 112, 1124 (2008)

    Article  Google Scholar 

  5. V. Subramanian, E.E. Wolf, P.V. Kamat, J. Am. Chem. Soc. 126, 4943 (2004)

    Article  Google Scholar 

  6. L.Z. Zhang, J.C. Yu, H.Y. Yip, Q. Li, K.W. Kwong, A.W. Xu, P.K. Wong, Langmuir 19, 10372 (2003)

    Article  Google Scholar 

  7. J. Yu, J. Xiong, B. Cheng, S. Liu, Appl. Catal. B 60, 211 (2005)

    Article  Google Scholar 

  8. Y.Y. Liang, H.L. Wang, H.S. Casalongue, Z. Chen, H.J. Dai, Nano. Res. 3, 701 (2010)

    Article  Google Scholar 

  9. Z. Chen, J.H. Liu, S. Qiu, G. Dawson, W. Chen, Catal. Commun. 21, 1 (2012)

    Article  ADS  Google Scholar 

  10. H. Lin, C.P. Huang, W. Li, C. Ni, S.I. Shah, Y.H. Tseng, Appl. Catal. B-Environ. 68, 1 (2006)

    Article  Google Scholar 

  11. L.L. Tan, S.P. Chai, A.R. Mohamed, Chemsuschem 2012, 5 (1868)

    Google Scholar 

  12. V. Stengl, D. Popelkova, P. Vlacil, J. Phys. Chem. C 115, 25209 (2011)

    Article  Google Scholar 

  13. M.S.A.S. Shah, A.R. Park, K. Zhang, J.H. Park, P.J. Yoo, Acs Appl. Mater. Inter. 4, 3893 (2012)

    Article  Google Scholar 

  14. J.H. Liu, J.S. Chen, X.F. Wei, X.W. Lou, X.W. Liu, Adv. Mater. 23, 998 (2011)

    Article  Google Scholar 

  15. D.H. Wang, D.W. Choi, J. Li, Z.G. Yang, Z.M. Nie, R. Kou, D.H. Hu, C.M. Wang, L.V. Saraf, J.G. Zhang, I.A. Aksay, J. Liu, ACS Nano 3, 907 (2009)

    Article  Google Scholar 

  16. N. Li, G. Liu, C. Zhen, F. Li, L.L. Zhang, H.M. Cheng, Adv. Func. Mater. 21, 1717 (2011)

    Article  Google Scholar 

  17. S.M. George, Chem. Rev. 110, 111 (2010)

    Article  Google Scholar 

  18. J.W. Elam, D. Routkevitch, P.P. Mardilovich, S.M. George, Chem. Mater. 15, 3507 (2003)

    Article  Google Scholar 

  19. R.G. Gordon, D. Hausmann, E. Kim, J. Shepard, Chem. Vap. Deposition 9, 73 (2003)

    Article  Google Scholar 

  20. J.A. McCormick, K.P. Rice, D.F. Paul, A.W. Weimer, S.M. George, Chem. Vap. Depos. 13, 491 (2007)

    Article  Google Scholar 

  21. J.D. Ferguson, A.W. Weimer, S.M. George, Thin Solid Films 371, 95 (2000)

    Article  ADS  Google Scholar 

  22. X. Sun, M. Xie, G. Wang, H. Sun, A.S. Cavanagh, J.J. Travis, S.M. George, J. Lian, J. Electrochem. Soc. 159, A364 (2012)

    Article  Google Scholar 

  23. C. Ban, M. Xie, X. Sun, J.J. Travis, G.K. Wang, H.T. Sun, A.C. Dillon, J. Lian, S.M. George, Nanotechnology 24(42), 424002 (2013)

    Article  ADS  Google Scholar 

  24. X. Sun, M. Xie, J.J. Travis, G. Wang, H. Sun, J. Lian, S.M. George, J. Phys Chem. C 117, 22497 (2013)

    Article  Google Scholar 

  25. D. Shao, X. Sun, M. Xie, H. Sun, F. Lu, S.M. George, J. Lian, S. Sawyer, Mater. Lett. 112, 165 (2013)

    Article  Google Scholar 

  26. W.S. Hummers, R.E. Offeman, J. Am. Chem. Soc. 80, 1339 (1958)

    Article  Google Scholar 

  27. M.J. McAllister, J.L. Li, D.H. Adamson, H.C. Schniepp, A.A. Abdala, J. Liu, M. Herrera-Alonso, D.L. Milius, R. Car, R.K. Prud’homme, I.A. Aksay, Chem. Mater. 19, 4396 (2007)

    Article  Google Scholar 

  28. J.A. McCormick, B.L. Cloutier, A.W. Weimer, S.M. George, J. Vac. Sci. Technol. A 25, 67 (2007)

    Article  Google Scholar 

  29. A.S. Cavanagh, C.A. Wilson, A.W. Weimer, S.M. George, Nanotechnology 20, 255602 (2009)

    Article  ADS  Google Scholar 

  30. M. Ritala, M. Leskela, E. Nykanen, P. Soininen, L. Niinisto, Thin Solid Films 225, 288 (1993)

    Article  ADS  Google Scholar 

  31. D.B. Farmer, R.G. Gordon, Nano Lett. 6, 699 (2006)

    Article  ADS  Google Scholar 

  32. A.C. Dillon, A.W. Ott, J.D. Way, S.M. George, Surf. Sci. 322, 230 (1995)

    Article  ADS  Google Scholar 

  33. J. Aarik, A. Aidla, A.-A. Kiisler, T. Uustare, V. Sammelselg, Thin Solid Films 305, 270 (1997)

    Article  ADS  Google Scholar 

  34. J. Aarik, A. Aidla, T. Uustare, V. Sammelselg, J. Cryst. Growth 148, 268 (1995)

    Article  ADS  Google Scholar 

  35. B.S. Huang, H.H. Tseng, M.Y. Wey, J. Ceram. Soc. Jpn. 117, 753 (2009)

    Article  Google Scholar 

  36. Q. Wang, D. Yang, D.M. Chen, Y.B. Wang, Z.Y. Jiang, J. Nanopart. Res. 2007, 9 (1087)

    Google Scholar 

  37. G.M. An, W.H. Ma, Z.Y. Sun, Z.M. Liu, B.X. Han, S.D. Miao, Z.J. Miao, K.L. Ding, Carbon 45, 1795 (2007)

    Article  Google Scholar 

  38. J.W. Elam, D. Routkevitch, P.P. Mardilovich, S.M. George, Chem. Mater. 15, 3507 (2003)

    Article  Google Scholar 

  39. J.A. McCormick, K.P. Rice, D.F. Paul, A.W. Weimer, S.M. George, Chem. Vap. Depos. 13, 491 (2007)

    Article  Google Scholar 

  40. X.H. Wang, J.G. Li, H. Kamiyama, Y. Moriyoshi, T. Ishigaki, J. Phys. Chem. B 110, 6804 (2006)

    Article  Google Scholar 

  41. S.D. Perera, R.G. Mariano, K. Vu, N. Nour, O. Seitz, Y. Chabal, K.J. Balkus, ACS Catalysis 2, 949 (2012)

    Article  Google Scholar 

  42. G. Williams, B. Seger, P.V. Kamat, ACS Nano 2, 1487 (2008)

    Article  Google Scholar 

  43. K. Woan, G. Pyrgiotakis, W. Sigmund, Adv. Mater. 21, 2233 (2009)

    Article  Google Scholar 

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Acknowledgements

The work at Chongqing Normal University was supported by the Chongqing Municipal Education Commission (KJ130601), the Natural Science Foundation of China (No. 21271192), and the Natural Science Foundation of Chongqing Municipality (cstc2014jcyjA50035).

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Correspondence to Yun Zhou.

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Yang, L., Jiang, L., Fu, W. et al. TiO2 quantum dots grown on graphene by atomic layer deposition as advanced photocatalytic hybrid materials. Appl. Phys. A 123, 416 (2017). https://doi.org/10.1007/s00339-017-1018-y

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  • DOI: https://doi.org/10.1007/s00339-017-1018-y

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