Abstract
As the development of electronic and communication technology, electromagnetic interference (EMI) shielding and attenuation is an effective strategy to ensure the operation of the electronic devices. Among the materials for high-performance shielding in aerospace industry and related high-temperature working environment, the thermally stable metal oxide semiconductors with narrow band gap are promising candidates. In this work, beta-manganese dioxide (β-MnO2) nanorods were synthesized by a hydrothermal method. The bulk materials of the β-MnO2 were fabricated to evaluate the EMI shielding performance in the temperature range of 20–500 °C between 8.2 and 12.4 GHz (X-band). To understand the mechanisms of high-temperature EMI shielding, the contribution of reflection and absorption to EMI shielding was discussed based on temperature-dependent electrical properties and complex permittivity. Highly sufficient shielding effectiveness greater than 20 dB was observed over all the investigated range, suggesting β-MnO2 nanorods as promising candidates for high-temperature EMI shielding. The results have also established a platform to develop high-temperature EMI shielding materials based on nanoscale semiconductors.
Similar content being viewed by others
References
N. Li, Y. Huang, F. Du, X.B. He, X. Lin, H.J. Gao et al., Nano. Lett. 6, 1141 (2006)
D.D.L. Chung, Carbon 50, 3342 (2012)
Q.M. Su, G. Zhong, J. Li, G.H. Du, B.S. Xu, Appl. Phys. A.106, 59 (2012)
R. Han, H.B. Yi, J.Q. Wei, L. Qiao, T. Wang, F.S. Li, Appl. Phys. A. 108, 665 (2012)
H.J. Wu, L.D. Wang, S.L. Guo, Z.Y. Shen, Appl. Phys. A 108, 439 (2012)
Q.C. Liu, Z.F. Zi, D.J. Wu, Y.P. Sun, J.M. Dai, J. Mater. Sci. 47, 1033 (2012)
Y.C. Qing, W.C. Zhou, S. Jia, F. Luo, D.M. Zhu, Appl. Phys. A 100, 1177 (2010)
D.D.L. Chung, Carbon 39, 279 (2001)
W.L. Song, M.S. Cao, M.M. Lu, J. Yang, H.F. Ju, Z.L. Hou et al., Nanotechnology 24, 115708 (2013)
M.S. Cao, W.L. Song, Z.L. Hou, B. Wen, J. Yuan, Carbon 48, 788 (2010)
M.H. Al-Saleh, U. Sundararaj, Carbon 47, 1738 (2009)
S.D. Hutagalung, N.H. Sahrol, Z.A. Ahmad, M.F. Ain, M. Othman, Ceram. Int. 38, 671 (2012)
M. Zhou, X. Zhang, J.M. Wei, S.L. Zhao, L. Wang, B.X. Feng, J. Phys. Chem. C 115, 1398 (2011)
X.H. Wang, S.B. Ni, G. Zhou, X.L. Sun, F. Yang, J.M. Wang et al., Mater. Lett. 64, 1496 (2010)
W.L. Song, M.S. Cao, Z.L. Hou, J. Yuan, X.Y. Fang, Scripta. Mater. 61, 201 (2009)
X.L. Shi, M.S. Cao, X.Y. Fang, J. Yuan, Y.Q. Kang, W.L. Song, Appl. Phys. Lett. 93, 223112 (2008)
P. Saini, V. Choudhary, N. Vijayan, R.K. Kotnala, J. Phys. Chem. C 116, 13403 (2012)
A.P. Singh, P. Garg, F. Alam, K. Singh, R.B. Mathur, R.P. Tandon et al., Carbon 50, 3868 (2012)
J.G. Park, J. Louis, Q. Cheng, J.W. Bao, J. Smithyman, R. Liang et al., Nanotechnology 20, 415702 (2009)
A.B. Kaiser, Adv Mater 13, 927 (2001)
S. Ramo, J.R. Whinnery, T.V. Duzer, Fields and Waves in Communication Electronics, 2nd edn. (John Wiley and Sons, New York, 1984)
E.C. Jordan, K.G. Balmain, Electromagnetic waves and radiating systems, 2nd edn. (Prentice-Hall, New Jersey, 1968)
W.L. Song, M.S. Cao, Z.L. Hou, X.Y. Fang, X.L. Shi, J. Yuan, Appl. Phys. Lett. 94, 233110 (2009)
N.T. Correia, J.J.M. Ramos, Phys. Chem. Chem. Phys. 2, 5712 (2000)
Acknowledgments
Financial supports from 973 Project (2013CB934001), NSF of China (Grant Nos. 51172024, 51372022 and 51302011), China PSF (2012M520165) and the Fundamental Research Funds for the Central Universities (FRF-TP-13-036A) are gratefully acknowledged.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Song, WL., Cao, MS., Hou, ZL. et al. Beta-manganese dioxide nanorods for sufficient high-temperature electromagnetic interference shielding in X-band. Appl. Phys. A 116, 1779–1783 (2014). https://doi.org/10.1007/s00339-014-8327-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00339-014-8327-1