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Well-controlled SI-ARGET ATRP of EGDMA for maintaining the dimensions of waterlogged archaeological wood

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Abstract

Controls over the dimensions of waterlogged archaeological wood (WAW) upon drying are a critical issue for its conservation. Surface-initiated activator regenerated by electron transfer atom transfer radical polymerization (SI-ARGET ATRP) has been proven to be an effective consolidation method to increase the dimensional stability. However, the drawback of the current method is that the expansion stress generated during graft polymerization cannot be well controlled. An improved SI-ARGET ATRP system using a bifunctional monomer ethylene glycol dimethacrylate (EGDMA) to introduce a cross-linking process during the polymerization is presented in this paper. Both Pinus massoniana and Sapium sp. samples with different maximum moisture contents as 507% and 863%, respectively, show a reduced volumetric shrinkage of around 5% without any expansion phenomenon after the treatment. This method shows potential applications in the field of WAW conservation and may provide a new solution for consolidation of other organic archaeological objects as well as developing new wood-based materials.

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Data availability

The data sets analysed during the current study are available from the corresponding author upon reasonable request.

References

  • Babiński L (2015) Dimensional changes of waterlogged archaeological hardwoods pre-treated with aqueous mixtures of lactitol/trehalose and mannitol/trehalose before freeze-drying. J Cult Herit 16(6):876–882

    Article  Google Scholar 

  • Björdal CG (2012) Microbial degradation of waterlogged archaeological wood. J Cult Herit 13:S118–S122

    Article  Google Scholar 

  • Björdal CG, Nilsson T, Daniel G (1999) Microbial decay of waterlogged archaeological wood found in Sweden applicable to archaeology and conservation. Int Biodeter Biodegr 43:63–73

    Article  Google Scholar 

  • Blanchette RA (2000) A review of microbial deterioration found in archaeological wood from different environments. Int Biodeter Biodegr 46:189–204

    Article  Google Scholar 

  • Broda M, Hill CAS (2021) Conservation of waterlogged wood—past, present and future perspectives. Forests 12:1193

    Article  Google Scholar 

  • Broda M, Mazela B (2017) Application of methyltrimethoxysilane to increase dimensional stability of waterlogged wood. J Cult Herit 25:149–156

    Article  Google Scholar 

  • Broda M, Yelle DJ (2022) Reactivity of waterlogged archaeological elm wood with organosilicon compounds applied as wood consolidants: 2D 1H–13C solution-state NMR studies. Molecules 27:3407

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  • Broda M, Mazela B, Dutkiewicz A (2019a) Organosilicon compounds with various active groups as consolidants for the preservation of waterlogged archaeological wood. J Cult Herit 35:123–128

    Article  Google Scholar 

  • Broda M, Mazela B, Radka K (2019b) Methyltrimethoxysilane as a stabilising agent for archaeological waterlogged wood differing in the degree of degradation. J Cult Herit 35:129–139

    Article  Google Scholar 

  • Cavallaro G, Lazzara G, Milioto S, Parisi F, Sparacino V (2015) Thermal and dynamic mechanical properties of beeswax-halloysite nanocomposites for consolidating waterlogged archaeological woods. Polym Degrad Stabil 120:220–225

    Article  CAS  Google Scholar 

  • Cavallaro G, Lazzara G, Milioto S, Parisi F, Ruisi F (2017) Nanocomposites based on esterified colophony and halloysite clay nanotubes as consolidants for waterlogged archaeological woods. Cellulose 24:3367–3376

    Article  CAS  Google Scholar 

  • Christensen M, Larnøy E, Kutzke H, Hansen FK (2015) Treatment of waterlogged archaeological wood using chitosan- and modified chitosan solutions. part 1: chemical compatibility and microstructure. J American Inst Conserv 54:3–13

    Article  Google Scholar 

  • Endo R, Sugiyama J (2022) New attempts with the keratin-metal/magnesium process for the conservation of archaeological waterlogged wood. J Cult Herit 54:53–58

    Article  Google Scholar 

  • Endo R, Kamei K, Iida I, Kawahara Y (2008) Dimensional stability of waterlogged wood treated with hydrolyzed feather keratin. J Archaeol Sci 35:1240–1246

    Article  Google Scholar 

  • Endo R, Kamei K, Iida I, Yokoyama M, Kawahara Y (2010) Physical and mechanical properties of waterlogged wood treated with hydrolyzed feather keratin. J Archaeol Sci 37:1311–1316

    Article  Google Scholar 

  • Jones SPP, Slater NKH, Jones M et al (2009) Investigating the processes necessary for satisfactory freeze-drying of waterlogged archaeological wood. J Archaeol Sci 36(10):2177–2183

    Article  Google Scholar 

  • Kaye B, Cole-Hamilton DJ, Morphet K (2000) Supercritical drying: a new method for conserving waterlogged archaeological materials. Stud Conserv 45(4):233–252

    CAS  Google Scholar 

  • Kennedy A, Pennington ER (2014) Conservation of chemically degraded waterlogged wood with sugars. Stud Conserv 59:194–201

    Article  CAS  Google Scholar 

  • Klaassen RKWM (2014) Speed of bacterial decay in waterlogged wood in soil and open water. Int Biodeter Biodegr 86:129–135

    Article  Google Scholar 

  • Lisuzzo L, Hueckel T, Cavallaro G, Sacanna S, Lazzara G (2021) Pickering emulsions based on wax and halloysite nanotubes: an ecofriendly protocol for the treatment of archaeological woods. ACS Appl Mater Interfaces 13:1651–1661

    Article  CAS  PubMed  Google Scholar 

  • Lisuzzo L, Cavallaro G, Milioto S, Lazzara G (2022) Pickering emulsions stabilized by halloysite nanotubes: from general aspects to technological applications. Adv Mater Interfaces 9:2102346

    Article  CAS  Google Scholar 

  • Liu L, Zhang L, Zhang B, Hu Y (2018) A comparative study of reinforcement materials for waterlogged wood relics in laboratory. J Cult Herit 36:94–102

    Article  CAS  Google Scholar 

  • Popescu CM, Broda M (2021) Interactions between different organosilicons and archaeological waterlogged wood evaluated by infrared spectroscopy. Forests 12:268

    Article  Google Scholar 

  • Tahira A, Howard W, Pennington ER, Kennedy A (2017) Mechanical strength studies on degraded waterlogged wood treated with sugars. Stud Conserv 62:223–228

    Article  CAS  Google Scholar 

  • Walsh Z, Janeček E, Jones M, Scherman OA (2015) Natural polymers as alternative consolidants for the preservation of waterlogged archaeological wood. Stud Conserv 54:45–56

    Google Scholar 

  • Zhou Y, Wang K, Hu D (2019) High retreatability and dimensional stability of polymer grafted waterlogged archaeological wood achieved by ARGET ATRP. Sci Rep 9:9879

    Article  PubMed  PubMed Central  Google Scholar 

  • Zhou Y, Wang K, Hu D (2021) An aqueous approach to functionalize waterlogged archaeological wood followed by improved surface-initiated ARGET ATRP for maintaining dimensional stability. Cellulose 28:2433–2443

    Article  CAS  Google Scholar 

  • Zhou Y, Wang K, Hu D (2022) Surface-initiated arget atrp for maintaining the dimension of waterlogged archaeological wood (pinus massoniana): polymer distribution behaviors and anti-shrinkage mechanism. Wood Sci Technol 56(1):205–218

    Article  CAS  Google Scholar 

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Acknowledgements

The research is supported by National Key R&D Program of China (2020YFC1521803) and National Social Science Foundation of China (Grant No. 19CKG032).

Funding

The research is supported by National Key R&D Program of China (2020YFC1521803) and National Social Science Foundation of China (Grant No. 19CKG032).

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Authors and Affiliations

  1. School of Archaeology and Museology, Peking University, Beijing, 100871, China

    Yihang Zhou, Yue Zhang, Kai Wang & Dongbo Hu

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  1. Yihang Zhou
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  2. Yue Zhang
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  3. Kai Wang
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  4. Dongbo Hu
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Contributions

YZ conducted the experiments and analysed the data. YZ and YZ wrote the main manuscript text and prepared the figures. KW and DH revised the manuscript. All authors reviewed the manuscript.

Corresponding author

Correspondence to Kai Wang.

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Zhou, Y., Zhang, Y., Wang, K. et al. Well-controlled SI-ARGET ATRP of EGDMA for maintaining the dimensions of waterlogged archaeological wood. Wood Sci Technol 57, 523–535 (2023). https://doi.org/10.1007/s00226-023-01454-w

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  • DOI: https://doi.org/10.1007/s00226-023-01454-w

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