Skip to main content
Log in

The Preparation of Biochar Particles from Sludge and Corncobs and Its Pb2+ Adsorption Properties

  • Published:
Bulletin of Environmental Contamination and Toxicology Aims and scope Submit manuscript

Abstract

In the present study, biochar particles (BPs) produced by the co-pyrolysis of sewage sludge and corncobs at temperatures of 300, 500, and 700°C were characterized. The Pb2+ adsorption properties and the heavy metal leaching toxicity rates of the BPs were investigated. It was found that the adsorption kinetics of the Pb2+ can be accurately described by a pseudo-second-order model, and the equilibrium adsorption data were well represented by both the Langmuir and the Freundilich Equations. The toxicity characteristic leaching procedure (TCLP) results indicated that the leaching concentrations of all the heavy metals were below the set limit of China’s national standard (Identification Standard for Hazardous Waste Extraction Toxicity Identification, China National Standard, GB 5085.3-2007). The results of this study can successfully provide scientific support for future corncob treatment and sludge pollution control.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  • Alshameri A, Yan C, Al-Ani Y, Dawood AS, Ibrahim A, Zhou CY, Wang HQ (2014) An investigation into the adsorption removal of ammonium by salt activated Chinese (Hulaodu) natural zeolite: Kinetics, isotherms, and thermodynamics. J Taiwan Inst Chem Eng 45:554–564

    Article  CAS  Google Scholar 

  • Chen T, Zhang YX, Wang HT, Lu WJ, Zhou ZY, Zhang YC, Ren LL (2014) Influence of pyrolysis temperature on characteristics and heavy metal adsorptive performance of biochar derived from municipal sewage sludge. Bio Technol 164:47–54

    Article  CAS  Google Scholar 

  • Chung HK, Kim WH, Park J, Cho J, Jeong TY, Park PK (2015) Application of Langmuir and Freundlich isotherms to predict adsorbate removal efficiency or required amount of adsorbent. J Ind Eng Chem 28:241–246

    Article  CAS  Google Scholar 

  • Fan SS, Wang Y, Wang Z, Tang J, Tang J, Li XD (2017) Removal of methylene blue from aqueous solution by sewage sludge-derived biochar: adsorption kinetics, equilibrium, thermodynamics and mechanism. J Environ Chem Eng 5:601–611

    Article  CAS  Google Scholar 

  • Huang HJ, Yang T, Lai FY, Wu GQ (2017) Co-pyrolysis of sewage sludge and sawdust/rice straw for the production of biochar. J Anal Appl Pyrol 125:61–68

    Article  CAS  Google Scholar 

  • Jin JW, Li YN, Zhang JC, Wu SC, Cao YC, Liang P, Zhang J, Wong MH, Wang MY, Shan SD, Christie P (2016) Influence of pyrolysis temperature on properties and environmental safety of heavy metals in biochars derived from municipal sewage sludge. J Hazard Mater 320:417–426

    Article  CAS  Google Scholar 

  • Kim WK, Shim T, Kim YS, Hyun S, Ryu C, Park YK, Jung J (2013) Characterization of cadmium removal from aqueous solution by biochar produced from a giant Miscanthus at different pyrolytic temperatures. Bio Technology 138C:266–270

    Article  Google Scholar 

  • Kolodynska D, Wnetrzak R, Leahy JJ, Hayes MHB, Kwapinshi W, Hubicki Z (2012) Kinetic and adsorptive characterization of biochar in metal ions removal. Chem Eng J 197:295–305

    Article  CAS  Google Scholar 

  • Manara P, Zabaniotou A (2012) Towards sewage sludge based biofuels via thermochemical conversion: a review. Renew Sust Energ Rev 16:2566–2582

    Article  CAS  Google Scholar 

  • Park JK, Song MJ (1998) Feasibility study on vitrification of low-and intermediate-level radioactive waste from pressurized water reactors. Waste Manag 18:157–167

    Article  CAS  Google Scholar 

  • Pituello C, Francioso O, Simonetti G, Pisi A, Torreggiani A, Berti A, Morari F (2014) Characterization of chemical–physical, structural and morphological properties of biochars from biowastes produced at different temperatures. J Soil Sediment 15:792–804

    Article  Google Scholar 

  • Tian Y, Zhang J, Zuo W, Chen L, Cui YN, Tan T (2013) Nitrogen conversion in relation to NH3 and HCN during microwave pyrolysis of sewage sludge. Environ Sci Technol 47:3498

    Article  CAS  Google Scholar 

  • Vu TM, Trinh VT, Doan DP, Van HT, Nguyen TV, Vigneswaran S, Ngo HH (2017) Removing ammonium from water using modified corncob-biochar. Sci Total Environ 579:612–619

    Article  CAS  Google Scholar 

  • Xu DY, Hong YJ, Tang H, Cheng WM, Song ZX, Zhan LL, Yao QF (2017a) Optimization treatment of sludge heavy metals by citric acid and GLDA. CIESC J 68:2535–2545 (in Chinese)

    CAS  Google Scholar 

  • Xu XY, Zhao B, Sun ML, Chen X, Zhang MC, Li HB, Xu SC (2017b) Co-pyrolysis characteristics of municipal sewage sludge and hazelnut shell by TG-DTG-MS and residue analysis. Waste Manag 62:91–100

    Article  CAS  Google Scholar 

  • Yang XM, Wang YJ, Qiu L, Zhao LX, Meng CL (2017) Effect of temperature on physicochemical properties of biochar prepared by pyrolysis of three components of biomass. Trans Chin Soc Agric Mach 48:289–295 (in Chinese)

    Google Scholar 

  • Yuan HR, Lu T, Huang HY, Zhao DD, Kobayashi N, Chen Y (2015) Influence of pyrolysis temperature on physical and chemical properties of biochar made from sewage sludge. J Anal Appl Pyrol 112:284–289

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This research study was financially supported by the National Natural Science Foundation of China (51408001); University Natural Science Foundation of Anhui Province (KJ2018A0103); and the Anhui Polytechnic University "Young and Middle-Aged Top Talent" Training Program.

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Chenglian Feng or Dayong Xu.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Electronic supplementary material 1 (DOCX 25 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Hong, Y., Xu, Z., Feng, C. et al. The Preparation of Biochar Particles from Sludge and Corncobs and Its Pb2+ Adsorption Properties. Bull Environ Contam Toxicol 103, 848–853 (2019). https://doi.org/10.1007/s00128-019-02736-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00128-019-02736-5

Keywords

Navigation