Abstract
In this paper, the influence of cooling rate on the undercooling of droplet solidification of metal melt has been investigated by employing the differential scanning calorimetry (DSC) method. The effect of cooling rate on the undercooling as well as its change tendency is analyzed theoretically. It is shown that the undercooling degree increases whereas the change rate of undercooling decreases with increasing cooling rate. Moreover, the change tendency approaches zero when the cooling rate exceedingly increased, indicating that an extremum of undercooling exists with increasing cooling rate.
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Ojha, S. N., Metastable phase formation during solidification of undercooled melt, Materials Science and Engineering A, 2001, 304-306: 114–118.
Liu, R. P., Volkmann, T., Herlach, D. M., Undercooling and solidification of Si by electromagnetic levitation, Acta Mater., 2001, 49: 439–444.
Liu, X. R., Cao, C. D., Wei, B., Microstructure evolution and solidification kinetics of undercooling Co-Ge eutectic alloys, Scripta Materialia, 2002, 46: 13–18.
Kim, Y. S., Hwang, C. W., Effect of composition and cooling rate on microstructure and tensile properties of Sn-Zn-Bi alloys, Journal of Alloys and Compounds, 2003, 237-245 (352): 237–245.
Wang, W. M., Bian, X. F., Qin, J. Y., The influence of Sb on the liquid structure of Al-12.5% Si alloy, Chinese Journal of Materials Research, 1999, 13(1): 58–62.
Liu, Y. Z., Chen, Z. H., Wang, J. N., Large undercooling rapid solidification and nucleation mechanism in multi-stage atomization, Science and Technology of Advanced Materials, 2001, 2: 181184.
Mizoguchi, T., Perepezko, J. H., Nucleation behavior during solidification of casting iron at high undercooling, Materials Science and Engineering A, 1997, 226: 813–817.
Cao, C. D., Letzig, T., Gorler, G. P. et al., Liquid phase separation in undercooled Co-Cu alloys processed by electromagnetic levitation and differential thermal analysis, Journal of Alloys and Compounds, 2001, 325: 113–117.
Mueller, B. A., Perepezko, J. H., The undercooling of aluminum, Metal Trans. A, 1987, 18: 1143–1150.
Li, Q., Zhu, Y. Y., He, Y. H. et al., DSC study on the undercooling and solidification of Ge melt, Science in China, Ser. G, 2004, 34(3): 241–246.
Guan, W. B., Gao, Y. L., Zhai, Q. J., Xu, K. D., Undercooling of droplet solidification for molten pure aluminum, Materials Letters, 2005, in press.
Jian, Z. Y., Chang, F. E., Ma, W. H. et al., Nucleation and undercooling of metal melt, Science in China, Ser. E, 2000, 43(2): 113–119.
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Wanbing, G., Yulai, G., Qijie, Z. et al. DSC study on the undercooling of droplet solidification of metal melt. Chin. Sci. Bull. 50, 929–931 (2005). https://doi.org/10.1007/BF02897389
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DOI: https://doi.org/10.1007/BF02897389