Skip to main content
Log in

The N-Ti (Nitrogen-Titanium) system

  • N-Ti
  • Published:
Bulletin of Alloy Phase Diagrams

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Cited references

  • 25Fri: E. Friederich and L. Sittig, “Production and Properties of Nitrides,”Z. Anorg. Chem., 143, 293–320 (1925) in German. (Equi Diagram; Experimental)

    Article  Google Scholar 

  • 31Agt: C. Agte and K. Moers, “Methods for Producing Pure High-Melting Nitrides and Borides and Description of Some of Their Properties,”Z. Anorg. Chem., 198, 233–275 (1931) in German. (Equi Diagram; Experimental)

    Article  Google Scholar 

  • 39Bra1: A. Brager, “An X-Ray Examination of Titanium Nitride I. Single Crystal Investigation,”Acta Physicochim. U.R.S.S., 10(4), 593–600 (1939). (Crys Structure; Experimental)

    Google Scholar 

  • 39Bra2: A. Brager, “An X-Ray Examination of Titanium Nitride III. Investigation by the Powder Method,”Acta Physicochim. U.R.S.S., 11(4), 617–632 (1939). (Crys Structure; Experimental)

    Google Scholar 

  • 49Cla: H.T. Clark, Jr., “The Lattice Parameters of High Purity α Titanium; The Effects of Oxygen and Nitrogen on Them,”Trans. AIME, 185, 588–589 (1949). (Crys Structure; Experimental)

    Google Scholar 

  • 49Ehr: P. Ehrlich, “On the Binary Systems of Titanium with the Elements Nitrogen, Carbon, Boron and Beryllium,”Z. Anorg. Chem., 259, 1–41 (1949). (Crys Structure, Equi Diagram; Experimental)

    Article  Google Scholar 

  • 50Duw: P. Duwez and F. Odell, “Phase Relationships in the Binary Systems of Nitrides and Carbides of Zirconium, Columbium, Titanium, and Vanadium,”J. Electrochem. Soc., 97(10), 299–304 (1950). (Crys Structure; Experimental)

    Article  Google Scholar 

  • 50Jaf: R.I. Jaffee, H.R. Ogden, and D.J. Maykuth, “Alloys of Titanium with Carbon, Oxygen, and Nitrogen,”Trans. AIME, 188, 1261–1266 (1950). (Equi Diagram Experimental)

    Google Scholar 

  • 53Sto: L. Stone and H. Margolin, “Titanium-Rich Regions of the Ti−C−N, Ti−C−O, and Ti−N−O Phase Diagrams,”Trans. AIME, 197, 1498–1503 (1953). (Equi Diagram; Experimental)

    Google Scholar 

  • Indicates key paper54Pal: A.E. Palty, H. Margolin, and J.P. Nielsen, “Titanium-Nitrogen and Titanium-Boron Systems,”Trans. ASM, 46, 312–328 (1954). (Equi Diagram; Experimental)

    Google Scholar 

  • 55Hoc: M. Hoch, D.P. Dingledy, and H.L. Johnston, “The Vaporization of TiN and ZrN,”J. Amer. Chem. Soc., 77, 304–306 (1955). (Thermo; Experimental)

    Article  Google Scholar 

  • 55Sza: I. Szántó, “On the Determination of High-Purity Alpha-Titanium Lattice Parameters,”Acta Tech. Acad. Sci. Hung., 13, 363–372 (1955). (Crys Structure; Experimental)

    Google Scholar 

  • 58Sku: P. Skulari and L. Chvátalová, “X-Ray Examination of Titanium,”Hutn. Listy, 13, 899–908 (1958) in Czech. (Crys Structure; Review)

    Google Scholar 

  • 59Kau: L. Kaufman, “The Lattice Stability of Metals I. Titanium and Zirconium,”Acta Metall., 7(8), 575–587 (1959). (Thermo; Theory)

    Article  Google Scholar 

  • 61Gor: N.S. Gorbunov, N.A. Shishakov, G.G. Sadikov, and A.A. Babad-Zakhryapin, “Neutronographic Study of Carbides and Nitrides of Titanium,”Izv. Akad. Nauk SSSR, Otdel. Khim. Nauk, (11), 2093–2095 (1961) in Russian; TR:Acad. Nauk SSSR, Bull. Div. Chem. Sci., (11), 1953–1955 (1961). (Crys Structure; Experimental)

    Google Scholar 

  • 61Now: H. Nowotny, F. Benesovsky, C. Brukl, and O. Schob, “The Ternaries: Titanium-Boron-Carbon and Titanium-Boron-Nitrogen,”Monatsh. Chem., 92, 403–414 (1961). (Crys Structure, Equi Diagram; Experimental)

    Article  Google Scholar 

  • 62Aki: P.A. Akishin and Yu.S. Klodeev, “Mass Spectrometric Investigation of the Composition of the Vapour Phase Above the Nitrides of Zirconium, Titanium, and Boron,”Zh. Neorg. Khim., 7(4), 941–942 (1962); TR:Russ. J. Inorg. Chem., 7(4), 486 (1962). (Thermo; Experimental)

    Google Scholar 

  • 62Hol: B. Holmberg, “Structural Studies on the Titanium-Nitrogen System,”Acta Chem. Scand., 16(5), 1255–1261 (1962). (Crys Structure, Equi Diagram; Experimental)

    Google Scholar 

  • 62Woo: R.M. Wood, “The Lattice Constants of High Purity Alpha Titanium,”Proc. Phys. Soc., 80, 783–786 (1962). (Crys Structure; Experimental)

    Article  Google Scholar 

  • 64Hou: C.R. Houska, “Thermal Expansion and Atomic Vibration Amplitudes for TiC, TiN, ZrC, ZrN and Pure Titanium,”J. Phys. Chem. Sol., 25, 359–366 (1964). (Crys Structure; Experimental)

    Article  ADS  Google Scholar 

  • Indicates key paper65Mcc: L.A. McClaine and C.P. Coppel, “Equilibrium Studies of Refractory Nitrides, Part I. Details of the Apparatus and Studies of the Ti−N System,” U.S. Air Force Systems Command, Res. Technol. Div., Tech. Rept. AFML-TR-65-299 (1965) (AD-474087). (Equi Diagram; Experimental, Review)

  • 66Mor: M.P. Morozova and M.M. Khernburg, “Enthalpy of Formation of Titanium Nitrides as a Function of Their Composition,”Zh. Fiz. Khim., 40(5), 1125–1128 (1966) in Russian; TR:Russ. J. Phys. Chem., 40(5), 604–606 (1966). (Thermo; Experimental)

    Google Scholar 

  • 67Gri: P. Grieveson, “An Investigation of the Ti−C−N System,”Proc. Brit. Ceram. Soc., (8), 137–153 (1967). (Crys Structure, Equi Diagram, Thermo; Experimental)

    Google Scholar 

  • 67Str: M.E. Straumanis, C.A. Faunce, and W.J. James, “Bonding, Lattice Parameter, Density and Defect Structure of TiN Containing an Excess of N,”Acta Metall., 15(1), 65–71 (1967). (Crys Structure; Experimental)

    Article  Google Scholar 

  • 68Ren: E.H. Rennhack, W.C. Coons, and R.A. Perkins, “High-Temperature Stability of Epsilon Ti, N,”Trans. Metall. AIME, 242, 343–345 (1968). (Equi Diagram; Experimental)

    Google Scholar 

  • 69Lob: G. Lobier and J.-P. Marcon, “Study and Structure of a New Phase of the Sub-Nitride of Titanium Ti2N,”Compt. Rend. Acad., Sci. Paris (Ser. C), 268, 1132–1135 (1969) in French. (Crys Structure, Equi Diagram; Experimental)

    Google Scholar 

  • 69Ryk: E.A. Ryklis, A.S. Bolgar, and V.V. Fesenko, “Vaporization Rate and Thermodynamic Properties of Titanium Nitride,”Porosh. Met., 9(6), 62–64 (1969); TR:Sov. Powder Met. Met. Ceram., 9(6), 478–480 (1969). (Thermo; Experimental)

    Google Scholar 

  • 69Ste: C.A. Stearns and F.J. Kohl, “The Dissociation Energy of Gaseous Titanium Mononitride,” Nat. Aeronautics Space Admin. Tech. Note NASA-TN-D-5027 (1969). (Thermo; Experimental)

  • 70Koh: F.J. Kohl and C.A. Stearns, “Mass Spectrometric Studies of the Vaporization of Refractory Carbides and Nitrides,” Nat. Aeronaut. Space Admin. Report NASA SP-227, Aerospace Structural Materials, 173–185 (1970). (Thermo; Experimental)

  • 70Kou: M.K. Koul and J.F. Breedis, “Phase Transformations in Beta Isomorphous Titanium Alloys,”Acta Metall., 18, 579–588 (1970). (Meta Phases; Experimental)

    Article  Google Scholar 

  • 70Mcd: N.R. McDonald and G.R. Wallwork, “The Reaction of Nitrogen with Titanium Between 800 and 1200°C,”Oxid. Met., 2(3), 263–283 (1970). (Equi Diagram; Experimental)

    Article  Google Scholar 

  • 70Ryk: E.A. Ryklis, A.S. Bolgar, O.P. Kulik, S.A. Shvab, and V.V. Fesenko, “Evaporation of Titanium Nitride at High Temperatures,”Zh. Fiz. Khim., 44(5), 1295–1297 (1970) in Russian; TR:Russ. J. Phys. Chem., 44(5), 720–722 (1970). (Thermo; Experimental)

    Google Scholar 

  • 71Stu: D.R. Stull and H. Prophet, “JANAF Thermochemical Tables,” 2nd ed., NSRDS-NBS37, U.S. Govt. Printing Office, Washington, DC (1971). (Thermo; Review)

    Google Scholar 

  • 71Tot: L.E. Toth,Transition Metal Carbides and Nitrides, Academic Press, New York (1971). (Equi Diagram; Experimental)

    Google Scholar 

  • 72Bil: J. Billingham, P.S. Bell, and M.H. Lewis, “Vacancy Short-Range Order in Substoichiometric Transition Metal Carbides and Nitrides with the NaCl Structure. I. Electron Diffraction Studies of Short-Range Ordered Compounds,”Acta Crystallogr. A, 28, 602–608 (1972). (Crys Structure; Experimental)

    Article  ADS  Google Scholar 

  • 72Kha: V.V. Khaenko, E.T. Kachkovskaya, and O.A. Frenkel, “Condition of Titanium and Vanadium Mononitride Particles after Nitriding and Heat Treatment,”Porosh. Met., 11(7), 34–39 (1972) in Russian; TR:Sov. Powder Met. Met. Ceram., 11(7), 541–545 (1972). (Equi Diagram; Experimental)

    Google Scholar 

  • 73Arb: M.P. Arbuzov, B.V. Khaenko, and E.T. Kachkovskaya, “The Real Structure of Titanium Mononitride in Its Homogeneity Range,”Porosh. Met., 12(6), 69–74 (1973) in Russian; TR:Sov. Powder Met. Met. Ceram., 12(6), 490–493 (1973). (Crys Structure; Experimental)

    Google Scholar 

  • 73Sam: G.V. Samsonov and M.M. Antonova, “Formation of Compounds in Systems of Titanium and Zirconium Nitride Alloys with Hydrogen,”Zh. Prikl. Khim., 46(1), 13–17 (1973) in Russian; TR:Russ. J. Appl. Chem., 46(1), 11–15 (1973). (Equi Diagram; Experimental)

    Google Scholar 

  • 74Bar: J.-P. Bars, E. Etchessahar, J. Debuigne, and A. Lerous, “On the Nitriding of Titanium by Nitrogen at High Temperature,”Compt. Rend. Acad. Sci. Paris (Ser. C), 278, 581–584 (1974) in French. (Equi Diagram; Experimental)

    Google Scholar 

  • 74Ett: P. Ettmayer, R. Kieffer, and F. Hattinger, “Determination of Melting Points of Metal Nitrides Under Nitrogen Pressure,”Metall, 28(12), 1151–1156 (1974) in German. (Equi Diagram; Experimental)

    Google Scholar 

  • 74Lev: Yu.V. Levinskii, “P-T Projection of the Phase Diagram of the System Ti−N,”Izv. Akad. Nauk SSSR Neorg. Mater. 10(9), 1628–1631 (1974) in Russian; TR:Inorg. Mater., 10(9), 1403–1405 (1974). (Equi Diagram; Review)

    Google Scholar 

  • 74Woo: F.W. Wood, P.A. Romans, R.A. McCune, and O.G. Paasche, “Phases and Interdiffusion Between Titanium and Its Mononitride,” U.S. Bur. Mines, Rep. Inv. 7943 (1974). (Equi Diagram; Experimental)

  • 75Nag: S. Nagakura, T. Kusunoki, F. Kakimoto, and Y. Hirotsu, “Lattice Parameter of the Non-Stoichiometric TiN x ,”J. Appl. Crystallogr., 8, 65–66 (1975). (Crys Structure; Experimental)

    Article  Google Scholar 

  • 76Ero: M.A. Eron’yan, R.G. Avarbeac, and T.N. Danisina, “Effects of Equilibrium Nitrogen Pressure on the Melting Points of TiNn and HfNn,”Tepl. Vys. Temp., 14(2), 398–399 (1976) in Russian; TR:High Temp., 14(2), 359–360 (1976). (Equi Diagram; Experimental)

    Google Scholar 

  • 77Aiv: M.I. Aivazov and T.V. Rezchikova, “Nature of the Formation of the Phases in the M−Sc−N and M−Mn−N Systems,”Zh. Neorg. Khim., 22(2), 458–463 (1977) in Russian; TR:Russ. J. Inorg. Chem., 22(2), 250–253 (1977). (Crys Structure; Experimental)

    Google Scholar 

  • 77Arb1: M.P. Arbuzov, S.Ya. Golub, and B.V. Khaenko, “X-Ray Investigation of Titanium Nitrides,”Izv. Akad. Nauk SSSR, Neorg. Mater., 13(10), 1779–1789 (1977) in Russian; TR:Inorg. Mater., 13(10), 1434–1437 (1977). (Equi Diagram; Experimental)

    Google Scholar 

  • 77Arb2: M.P. Arbuzov, S.Ya. Golub, B.V. Khayenko, “Study of the Precipitation of an Ordered δ′ Phase from Titanium Mononitrides,”Fiz. Met. Metalloved, 44(3), 666–668 (1977) in Russian; TR:Phys. Met. Metallogr., 44(3), 194–197 (1977). (Crys Structure, Equi Diagram; Experimental)

    Google Scholar 

  • 77Bar: J.-P. Bars, E. Etchessahar, and J. Debuigne, “Kinetic Diffusional and Morphological Study of the Nitriding of Titanium by Nitrogen at High Temperature: Mechanical and Structural Properties of Alpha Solid Solution Ti-Nitrogen,”J. Less-Common Met., 52, 51–76 (1977). (Crys Structure, Equi Diagram; Experimental)

    Article  Google Scholar 

  • 77Chr: A.N. Christensen and S. Fregerslev, “Preparation, Composition, and Solid State Investigations of TiN, ZrN, NbN and Compounds from the Pseudo-Binary Systems NbN−NbC, NbN−TiC and NbN−TiN,”Acta Chem. Scand., A, 31(10), 861–868 (1977). (Crys Structure; Experimental)

    Article  Google Scholar 

  • 77Hoj: J. Hojo, O. Iwamoto, Y. Maruyama, and A. Kato, “Defect Structure, Thermal and Electrical Properties of Ti Nitride and V Nitride Powders,”J. Less-Common Met., 53, 277–286 (1977). (Crys Structure; Experimental)

    Article  Google Scholar 

  • 77Nag: S. Nagakura and T. Kusunoki, “Structure of TiN x Studied by Electron Diffraction and Microscopy,”J. Appl. Crystallogr., 10, 52–56 (1977). (Crys Structure, Equi Diagram; Experimental)

    Article  Google Scholar 

  • 78Mit: H. Mitsuhashi, Y. Igasaki, and M. Kanenko, “Properties of Titanium Solid Solutions Prepared by Reactive Sputtering,”J. Crystallogr. Growth, 45, 350–354 (1978). (Meta Phases; Experimental)

    Article  ADS  Google Scholar 

  • 80Sun: D. Sundararaman, V. Seetharaman, and V.S. Raghunathan, “Phase Transformations in a Ti-1.6 a/o N Alloy,”Titanium ’80, Vol. 2, 1521–1532, TMS-AIME, Warrendale, PA (1980). (Meta Phases, Equi Diagram; Experimental)

    Google Scholar 

  • 82Sae: Y. Saeki, R. Matsuzaki, A. Yajima, and M. Akiyama, “Reaction Process of Titanium Tetrachloride with Ammonia in the Vapor Phase and Properties of the Titanium Nitride Formed,”Bull. Chem. Soc. Jpn., 55(10), 3193–3196 (1982). (Crys Structure; Experimental)

    Article  Google Scholar 

  • 83And: R.A. Andrievskii, Yu.F. Khromov, D.E. Svistunov, and R.S. Yurkova, “Partial Thermodynamic Characteristics of Titanium Nitride,”Zh. Fiz. Khim., 57(7), 1641–1644 (1983) in Russian; TR:Russ. J. Phys. Chem., 57(7), 996–998 (1983). (Thermo; Experimental)

    Google Scholar 

  • 83Sun: D. Sundararaman, A.L.E. Terrance, V. Seetharaman, and V.S. Raghunathan, “Electron Microscopy Study of Microstructural Changes in a Ti-1.6 at.% N Alloy,”Trans. Jpn. Inst. Met., 24(7), 510–513 (1983). (Crys Structure, Meta Phases; Experimental)

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Work was supported by ASM INTERNATIONAL and the National Bureau of Standards (NBS). Literature searched through 1983. Part of the bibliographic search was provided by ASM. Drs. H.A. Wriedt and J.L. Murray are ASM/NBS Data Program Category Editors for binary nitrogen alloys and for binary titanium alloys, respectively.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wriedt, H.A., Murray, J.L. The N-Ti (Nitrogen-Titanium) system. Bulletin of Alloy Phase Diagrams 8, 378–388 (1987). https://doi.org/10.1007/BF02869274

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02869274

Keywords

Navigation