Skip to main content
Log in

The development of nitrogen concentration profiles on nitriding iron

  • Published:
Metallurgical Transactions A Aims and scope Submit manuscript

Abstract

On nitriding iron specimens nitrogen concentration profiles within the specimens are built up. A numerical method for the calculation of such concentration profiles was developed. The results calculated were compared with experimental data. It was found that during nitriding the nitrogen surface concentration approached relatively slowly the equilibrium value. This effect strongly influenced the development of the nitrogen concentration profile. The model predicted correctly the incubation time for compound(i. e., iron nitride) layer formation at the surface. If the fatigue resistance is strongly dependent on the (compressive) residual surface stress, the present treatment allows calculation of anoptimum nitriding time by determining when the maximum (compressive) residual surface stress occurs.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Source Book on Nitriding, ASM, Metals Park, OH, 1977.

  2. J. Crank:The Mathematics of Diffusion, 2nd edition, Clarendon Press, Oxford, 1979, pp. 47–49, 144–48.

    Google Scholar 

  3. Metals Handbook, 9th edition, ASM, Metals Park, OH, 1981, vol. 4 (Heat Treating), pp. 172–75.

  4. R. Collin, S. Gunnarson, and D. Thulin:Härterei Tech. Mitt., 1970, vol. 25, pp. 17–22.

    CAS  Google Scholar 

  5. J. Pavlossoglou:Härterei Tech. Mitt., 1977, vol. 32, pp. 169–76, 215–23.

    Google Scholar 

  6. J. I. Goldstein and A. E. Moren:Metall. Trans. A, 1978, vol. 9A, pp. 1515–20.

    CAS  Google Scholar 

  7. H. J. Grabke:Ber. Bunsenges. Phys. Chem., 1968, vol. 72, pp. 533–41, pp. 541–48.

    Google Scholar 

  8. E. J. Mittemeijer, H. C. F. Rozendaal, P. F. Colijn, P. J. van der Schaaf, and R. Th. Fumëe:Proc. Heat Treatment 1981, The Metals Society, London, 1982, in press.

    Google Scholar 

  9. B. J. Lightfoot and D. H. Jack:Proc. Heat Treatment 1973, The Metals Society, London, 1973, pp. 59–65.

    Google Scholar 

  10. L. I. van de Walle (ed.):Residual Stress for Designers and Metallurgists, ASM, Metals Park, OH, 1981.

    Google Scholar 

  11. E. Lehrer:Z. Elektrochem., 1930, vol. 36, pp. 383–92.

    CAS  Google Scholar 

  12. W. Pitsch:Arch. Eisenhüttenwes., 1956, vol. 27, pp. 281–84.

    CAS  Google Scholar 

  13. P. F. Colijn, W. H. Kool, E. I. Mittemeijer, and D. Schalkoord:Praktische Metallographie/Practical Metallography, Sonderband Metallographietagung, Augsburg, October 1–3, 1980, Dr. Riederer-Verlag, Stuttgart, 1981, vol. 12, pp. 81–91.

    Google Scholar 

  14. W. H. Kool, E. J. Mittemeijer, and D. Schalkoord: Proc. 10. Kolloquium über Metallkundliche Analyse, Vienna, November 3–5, 1980,Mikrochim. Acta, 1981, Suppl. 9, pp. 349–72.

  15. E. J. Mittemeijer:Härterei Tech. Mitt., 1981, vol. 36, pp. 57–68.

    CAS  Google Scholar 

  16. O. Richmond, W. C. Leslie, and H. A. Wriedt:Trans. ASM, 1964, vol. 57, pp. 294–300.

    CAS  Google Scholar 

  17. J. D. Fast and M. B. Verrijp:J. Iron and Steel Inst., 1954, vol. 176, pp. 24–27.

    CAS  Google Scholar 

  18. J. D. Fast and M. B. Verrijp:J. Iron and Steel Inst., 1955, vol. 177, pp. 337–43.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rozendaal, H.C.F., Mittemeijer, E.J., Colijn, P.F. et al. The development of nitrogen concentration profiles on nitriding iron. Metall Trans A 14, 395–399 (1983). https://doi.org/10.1007/BF02644217

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02644217

Keywords

Navigation