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Heteroorganic betaines

1. Synthesis of betaines containing the+P−C−Si−S− and+P−C−C−S− fragments and their characterization by multinuclear NMR spectroscopy

  • Organic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

A method for the synthesis of a new class of betaines,viz., R3 1P+CR2R3SiR4R5S−, was developed. The experimental evidence for the intermediate formation of betaines R3 1P+−CR2R3−CR4R5−S− in the Wittig reaction for a series of thiocarbonyl compounds was obtained. A comparative analysis of the NMR spectra of betaines containing the+P−C−Si−S− and+P−C−C−S− fragments was performed.

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Authors and Affiliations

  1. State Research Institute of Chemistry and Technology of Organoelement Compounds, State Research Center of the Russian Federation, 38 sh. Entuziastov, 111123, Moscow, Russian Federation

    I. V. Borisova, N. N. Zemlyanskii, A. K. Shestakova & E. A. Chernyshev

  2. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119899, Moscow, Russian Federation

    Yu. A. Ustynyuk

Authors
  1. I. V. Borisova
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  2. N. N. Zemlyanskii
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  3. A. K. Shestakova
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  4. Yu. A. Ustynyuk
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  5. E. A. Chernyshev
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 922–930, May, 2000.

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Borisova, I.V., Zemlyanskii, N.N., Shestakova, A.K. et al. Heteroorganic betaines. Russ Chem Bull 49, 920–928 (2000). https://doi.org/10.1007/BF02494719

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  • DOI: https://doi.org/10.1007/BF02494719

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