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Nitropyrroles

Communication 1. New method for the synthesis of the pyrrole ring

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A new reaction for the formation of the pyrrole ring was discovered; it consists in the condensation of the dipotassium salt of 2,3,3-trinitropropionaldehyde with formaldehyde and amines. 1-Methyl- and 1-ethyl-3,4-dinitropyrroles were prepared.

  2. 2.

    A mechanism is proposed for this reaction.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

    S. S. Novikov & V. M. Belikov

Authors
  1. S. S. Novikov
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  2. V. M. Belikov
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Novikov, S.S., Belikov, V.M. Nitropyrroles. Russ Chem Bull 8, 1059–1062 (1959). https://doi.org/10.1007/BF00916676

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  • DOI: https://doi.org/10.1007/BF00916676

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