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Solubility diagram of system: RbAlH4-diethylene glycol dimethyl ether

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study was made of the reaction in the system: RbAlH4-diglyme (DG) in the temperature range from −65 to 50°C.

  2. 2.

    The existence of the solvates RbAlH4·4DG and RbAlH4·-3DG was established, which respectively melt incongruently at −20 and −3°.

  3. 3.

    The region for the crystallization of the unsolvated rubidium aluminum hydride was determined.

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Literature cited

  1. S. I. Bakum and T. N. Dymova, Izv. Akad. Nauk SSSR, Ser. Khim., 1890 (1970).

  2. T. N. Dymova, S. I. Bakum, C. C. Grazhulene, and M. Mukhidinov, ibid., 1892 (1970).

  3. S. I. Bakum, U. Mirsaidov, M. E. Kost, and T. N. Dymova, ibid., 2096 (1972).

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, USSR

    S. I. Bakum, U. Mirsaidov & T. N. Dymova

Authors
  1. S. I. Bakum
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  2. U. Mirsaidov
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  3. T. N. Dymova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2606–2607, November, 1972.

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Bakum, S.I., Mirsaidov, U. & Dymova, T.N. Solubility diagram of system: RbAlH4-diethylene glycol dimethyl ether. Russ Chem Bull 21, 2539–2540 (1972). https://doi.org/10.1007/BF00850117

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  • DOI: https://doi.org/10.1007/BF00850117

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