Conclusions
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1.
The synthesis of theα-phenylethyl- andα-phenylisopropylmagnesium chlorides in THF at 0 to − 10° was described. Whenα-phenylisopropylmagnesium chloride is synthesized in THF at 20–45° it reacts with the THF to yield 5-methyl-5-phenyl-1-hexanol.
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2.
When reacted with methyl borate, theα-phenylethyl- andα-phenylisopropylmagnesium chlorides give theα-phenylethyl- andα-phenylisopropylboronic acids. We also prepared the anhydride ofα-phenylethylboronic acid and the diethanolamine esters ofα-phenylethyl- andα-phenylisopropylboronic acid.α-Phenylethylmercury chloride was obtained from the and mercuric chloride.
Literature cited
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1662–1664, September, 1966.
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Kruglova, N.V., Freidlina, R.K. Synthesis of some derivatives of α-phenylethyl- and α-phenylisopropylboronic acids. Russ Chem Bull 15, 1608–1610 (1966). https://doi.org/10.1007/BF00848933
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DOI: https://doi.org/10.1007/BF00848933