Skip to main content
SpringerLink
Log in

The crystal structure of Fe(SeO2OH)(SeO4)·H2O

Die Kristallstruktur von Fe(SeO2OH)(SeO4)·H2O

  • Anorganische Und Physikalische Chemie
  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Summary

The crystal structure of the hydrothermally synthesized compound Fe(SeO2OH) (SeO4) · H2O was determined by single crystal diffraction methods:a=8.355(2) Å,b=8.696(2) Å,c=9.255(2) Å, β=93.72(1)°,V=670.95 Å3;Z=4, space group P21/c,R=0.029,R w=0.027 for 2430 independent reflections (sin θ/λ⩽0.76 Å−1). Isolated FeO5(H2O)-octahedra share five corners with [SeO2OH] and [SeO4] groups to form sheets parallel to (100). These sheets are interconnected via hydrogen bonds only.

Zusammenfassung

Die Kristallstruktur der hydrothermal dargestellten Verbindung Fe(SeO2OH) (SeO4)·H2O wurde mittels Einkristallbeugungsmethoden bestimmt:a=8.355(2) Å,b=8.696(2) Å,c=9.255(2) Å, β=93.72(1)°,V=670.95 Å3;Z=4, Raumgruppe P21/c,R=0.029,R w=0.027 für 2 430 unabhängige Reflexe (sin θ/λ ⩽ 0.76 Å−1). Isolierte FeO5(H2O)-Oktaeder teilen fünf Ecken mit [SeO2OH]- und [SeO4]-Gruppen, wobei sie Schichten parallel (100) bilden. Diese Schichten sind nur über Wasserstoffbrücken miteinander verbunden.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Giester G., Wildner M. (1992) N. Jb. Miner. Mh. 135

  2. Effenberger H. (1987) Min. Petr.36: 3

    Google Scholar 

  3. Giester G. (1989) Mh. Chem.120: 661

    Google Scholar 

  4. Valkonen J., Koskenlinna M. (1978) Acta Chem. Scand.A 32: 603

    Google Scholar 

  5. Giester G., Wildner M. (1991) Mh. Chem.122: 617

    Google Scholar 

  6. Giester G. (1992) J. Solid Stat. Chem. (in press)

  7. Ibers J., Hamilton W. H. (eds.) (1974): International Tables for X-ray Crystallography, Vol. IV. Kynoch Press, Birmingham

    Google Scholar 

  8. Zachariasen W. H. (1967) Acta Crystallogr.23: 558

    Google Scholar 

  9. STRUCSY-Structure system program package. 1984, Stoe & Cie, Darmstadt

  10. Brown I. D., Altermatt G. (1985) Acta Crystallogr. Sect.B 41: 244

    Google Scholar 

  11. Baur W. H. (1981) Structure and bonding in crystals O'Keefe M., Navrotsky A. (eds.) Vol. II, 31. New York, Academic press

    Google Scholar 

  12. Gibbs G. V., Chiari G., Louisnathan S. J. (1976) Z. Kristallogr.143: 166

    Google Scholar 

  13. Hawthorne F. C., Groat L. A., Ercit T. S. (1987) Acta Crystallogr. Sect.C 43: 2042

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institut für Mineralogie und Kristallographie, Universität Wien, A-1010, Wien, Austria

    Gerald Giester

Authors
  1. Gerald Giester
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Giester, G. The crystal structure of Fe(SeO2OH)(SeO4)·H2O. Monatsh Chem 123, 957–963 (1992). https://doi.org/10.1007/BF00810925

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00810925

Keywords

Search

Navigation