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Synthesis of analcime from volcanic sediments in sodium silicate solution

Experimental studies on the water-rock interaction. I

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Abstract

Analcime has been synthesized from natural rhyolitic tuff and green tuff (Miocene age) at 200° C and 20 kg/cm2 with solution of Na2SiO3 (12%) in 50- to 260-hr runs. From the diffraction intensities, it was found that the alteration products of green tuff contained more analcime than those of rhyolitic tuff. It has been concluded that the lithological character of starting materials and the chemical behavior of reaction products are important controlling factors in analcimization.

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References

  • Abe, H., Aoki, M., Konno, H.: Artificial hydrothermal alteration of Miocene tuffs in sodium hydroxide solution at 200° C and 20 kg/cm2, with special reference to analcimization (Hydrothermal studies on the wall-rock alteration -2-). J. Japan. Assoc. Mineral. Petrol. Econ. Geol. 68, 161–169 (1973)

    Google Scholar 

  • Barrer, R. M., Baynham, J. W., Bultitute, F. W., Meier, W. M.: Hydrothermal chemistry of the silicates. Part VIII, Low temperature crystal growth of aluminosilicates and of some gallium and germanium analogues. J. Chem. Soc. 36, 195–208 (1959)

    Google Scholar 

  • Barrer, R. M., White, E. A. D.: The hydrothermal chemistry of the silicates. Part II, Synthetic crystalline sodium aluminosilicates. J. Chem. Soc. 286, 1561–1571 (1952)

    Google Scholar 

  • Boles, J. R.: Synthesis of analcime from natural heulandite and clinoptilolite. Am. Mineralogist 56, 1724–1734 (1971)

    Google Scholar 

  • Coombs, D. S., Ellis, A. D., Fyfe, W. S., Taylor, A. M.: The zeolitic facies, with comments on the interpretation of hydrothermal synthesis. Geochim. Cosmochim. Acta 17, 53–107 (1971)

    Google Scholar 

  • Harada, K., Umeda, M., Nagashima, K.: Hydrothermal reaction of some zeolites. Japan. J. Geol. Geogr. 41, 33–39 (1971)

    Google Scholar 

  • Holler, H.: Untersuchungen über die Bildung von Analcime aus natürlichen Silikaten. Contr. Mineral. and Petrol. 27, 80–94 (1970)

    Google Scholar 

  • Iijima, A.: Argillaceous and zeolitic alteration zones surrounding Kuroko (Black ore) deposits in Odate district of Akita Prefecture. Mining Geol. 22, 1–22 (1972)

    Google Scholar 

  • Iijima, A.: Clay and zeolite alteration zones surrounding Kuroko-ore deposits in Hokuroko district, northern Akita, as a submarine hydrothermal-diagenetic alteration product. Mining Geol. Special Issue No. 5 (1973) (in press)

  • Iijima, A., Hay, R. L.: Analcime composition in tuffs of Green River Formation of Wyoming. Am. Mineralogist 53, 184–200 (1968)

    Google Scholar 

  • Kiriyama, R., Iwasaki, H.: Process of mineral formation from obsidian under hydrothermal conditions. J. Geol. Soc. Japan 66, 242–250 (1960)

    Google Scholar 

  • Kiriyama, R., Koizumi, M., Yamada, K., Kitagaki, R.: Hydrothermal reaction of dehydrated analcite (Hydrothermal reaction of zeolites, Part 3). J. Mineral. Soc. Japan 2, 464–470 (1956)

    Google Scholar 

  • Kiriyama, R., Koizumi, M., Yamada, K., Kitagaki, R.: Hydrothermal reaction of dehydrated natrolite (Hydrothermal reaction of zeolites, Part 4). J. Mineral. Soc. Japan 3, 107–123 (1957)

    Google Scholar 

  • Krauskopf, K. B.: Introduction to geochemistry. International series in the earth and planetary sciences. New York: McGraw-Hill 1967

    Google Scholar 

  • Morey, G. W., Fournier, R. O.: Decomposition of microcline, albite and nepheline in hot water. Am. Mineralogist 46, 688–699 (1961)

    Google Scholar 

  • Nakagawa, Z., Hatahira, S., Urabe, K., Yamada, H.: Studies on the crystallization process in the system feldspar-NaOH-H2O at low temperatures. J. Japan. Assoc. Mineral. Petrol. Econ. Geol. 68, 58–69 (1973)

    Google Scholar 

  • Noll, W.: Synthese von Montmorilloniten. Ein Beitrag zur Kenntnis der Bildungsbedingungen und des Chemismus von Montmorillonit. Chem. Erde 10, 129–154 (1936)

    Google Scholar 

  • Saha, P.: Geochemical and X-ray investigation of natural and synthetic analcites. Am. Mineralogist 44, 300–313 (1959)

    Google Scholar 

  • Saha, P.: The system NaAlSiO4 (nepheline)-NaAlSi3O8 (albite)-H2O. Am. Mineralogist 46, 859–884 (1961)

    Google Scholar 

  • Sand, L. B., Roy, R., Osborn, E. F.: Stability relations of some minerals in the Na2O-Al2O3-SiO2-H2O system. Econ. Geol. 52, 169–178 (1957)

    Google Scholar 

  • Sudo, T., Matsuoka, M.: Artificial crystallization of volcanic glass to sodalite and a zeolite structure. Geochim. Cosmochim. Acta 17, 1–5 (1959)

    Google Scholar 

  • Tomita, K.: Reaction products of clay minerals with sodium hydroxide under hydrothermal conditions. J. Japan. Assoc. Mineral. Petrol. Econ. Geol. 58, 55–66 (1967)

    Google Scholar 

  • Utada, M., Minato, H.: Analcime nodule from Yusato, Shimane Prefecture—the mode of occurrence and genetical relation to the migration of sodium. Sci. Paper Coll. General Educ., Univ. Tokyo 21, 63–78 (1971)

    Google Scholar 

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Abe, H., Aoki, M. & Konno, H. Synthesis of analcime from volcanic sediments in sodium silicate solution. Contr. Mineral. and Petrol. 42, 81–92 (1973). https://doi.org/10.1007/BF00371499

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