Abstract
Real time observations of submicrometre scale failure mechanisms of injection moulded multiphase blends are extremely difficult to perform. This has been accomplished using a specially designed tensile fixture and sample preparation techniques for a polycarbonate-polyester blend. Blunt or sharp cracks could be developed in the blend which were dependent on the shape of the polyester domains. Their initiation and propagation mechanisms have been examined at the submicrometre and bulk scales. The failures observed in the thin-sections were similar to failure mechanisms observed in the bulk.
Similar content being viewed by others
References
Y. I. NAKAMURA, R. I. HASEGAWA and H. I. KUBOTA, US Patent No. 3 864 428, Teijin Ltd. (1975).
S. R. MURFF, J. W. BARLOW and D. R. PAUL, J. Appl. Polym. Sci. 29 (1984) 3231.
H. C. FROMUTH and K. M. SHELL, US Patent No. 4 264 487, Rohm and Haas (1981).
C. P. BOSNYAK, K. SEHANOBISH and E. G. RIGHTOR, Amer. Che. Soc. Polym. Prepr. 33 (1992) 624.
L. A. UTRACKI, “Polymer Alloys and Blends, Thermodynamics and Rheology” (Hanser, Munich, 1989) Ch. 1.
M. K. LAUGHNER, B. N. HERRON and C. P. BOSNYAK, US Patent No. 5 124 402, The Dow Chemical Co. (1992).
S. R. SEIBEL, A. MOET, D. H. BANK and K. NICHOLS, Proceedings of SPE Antec (Society of Plastics Engineers, Brookfield, Connecticut, 1993) p. 902.
H. J. SUE, E. I. GARCIA-MEITIN, B. L. BURTON and C. C. GARRISON, J. Polym. Sci. Part B Polym. Phys 29 (1991) 1623.
R. P. KAMBOUR, J. Polym. Sci. D7 (1973) 1.
C. MAESTRINI and E. J. KRAMER, Polymer 32 (1991) 609.
B. D. LAUTERWASSER and E. J. KRAMER, Phil. Mag. A 39 (1979) 469.
L. BERGER and E. J. KRAMER, J. Mater. Sci. 22 (1987) 2739.
W. W. ADAMS, D. YANG and E. L. THOMAS, ibid. 21 (1986) 2239.
A. DONALD and E. J. KRAMER, ibid. 16 (1981) 2967.
E. G. RIGHTOR, G. P. YOUNG, K. SEHANOBISH, J. C. CONBOY, C. P. BOSNYAK, ibid. 16 (1981) 2967 in press.
H. T. PHAM, K. SEHANOBISH, E. G. RIGHTOR, Proceedings of SPE Antec (Society of Plastics Engineers, Brookfield, Connecticut, 1994) p. 1713.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Rightor, E.G., Sehanobish, K., Young, G.P. et al. Real time study of failure events in polymers. JOURNAL OF MATERIALS SCIENCE 30, 2083–2090 (1995). https://doi.org/10.1007/BF00353038
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF00353038