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Etching of r.f. magnetron-sputtered indium tin oxide films

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Abstract

In this study, the etching of indium tin oxide (ITO) films with various acidic solutions are studied and the activation energies for etching calculated. On the basis of the etching data, a diluent hydrochloric acid is selected for further investigation. The surface morphology of the HCl-etched films are examined. Pinholes resulted from enhanced etching of the grain boundaries are found. Films with larger grains exhibit coarser etched surfaces. The opto-electrical properties of the films are studied and the figure of merits for these films evaluated.

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References

  1. R. LATZ, K. MICHAEL and M. SCHERER, Jpn. J. Appl. Phys. 30 (1991) L149.

    Google Scholar 

  2. I. HAMBERG, A. HJORTSBERG and C. G. GRANQVIST, Appl. Phys. Lett. 40 (1982) 362.

    Google Scholar 

  3. A. HJORTSBERG, I. HAMBERG and C. G. GRANQVIST, Thin Solid Films 90 (1982) 323.

    Google Scholar 

  4. G. FRANK, E. KAUER and H. KöSTLIN, ibid. Thin Solid Films 77 (1981) 107.

  5. D. K. Schroder, IEEE Trans. Electron Devices ED-25 (1978) 90.

  6. M. HOHEISEL, A. MITWALSKY and C. MROTZEK, Phys. Status Solidi (a) 123 (1991) 461.

    Google Scholar 

  7. B. S. CHIOU and S. T. HSIEH, Thin Solid Films 229 (1993) 146.

    Google Scholar 

  8. W. F. WU and B. S. CHIOU, Appl. Surf. Sci., 68 (1993) 497.

    Google Scholar 

  9. B. S. CHIOU, S. T. HSIEH and W. F. WU, J. Amer. Ceram. Soc. 77 (1994) 1740.

    Google Scholar 

  10. J. ECHIGOYA, S. KATO and H. ENOKI, J. Mater. Sci. Mater. Elec. 3 (1992) 168.

    Google Scholar 

  11. Y. SHIGESATO, S. TAKAKI and T. HARANOU, Appl. Surf. Sci. 48/49 (1991) 269.

    Google Scholar 

  12. M. A. MARTINEZ, J. HERRERO and M. T. GUTIERREZ, Sol. Energy Mater. 26 (1992) 309.

    Google Scholar 

  13. C. V. R. Vasant KUMAR and Abhai MANSINGH, J. Appl. Phys. 65 (1989) 1270.

    Google Scholar 

  14. T. KARASAWA and Y. MIYATA, Thin Solid Films 223 (1993) 135.

    Google Scholar 

  15. B. L. GEHMAN, S. JONSSON, T. RUDOLPH, M. WEIGERT and R. WERNER, ibid. Thin Solid Films 220 (1992) 333.

  16. N. BALASUBRAMANIAN and A. SUBRAHMANYAM, J. Phys. D: Appl. Phys. 22 (1989) 206.

    Google Scholar 

  17. N. MORI, J. Appl. Phys. 73 (1993) 1327.

    Google Scholar 

  18. S. ASHOK, P. P. SHARMA and S. J. FONASH, IEEE Trans. Electron Devices, ED-27 1980) 725.

    Google Scholar 

  19. B. BESSAÏS, N. MLIKI and R. BENNACEUR, Semicond. Sci. Technol. 8 (1993) 116.

    Google Scholar 

  20. M. INOUE, T. MATSUOKA, Y. FUJITA, and A. ABE, Jpn. J. Appl. Phys. 2 (1989) 274.

    Google Scholar 

  21. T. RATCHEVA and M. NANVA, Thin Solid Films 141 (1986) L87.

    Google Scholar 

  22. M. HOHEISEL, A. MITWALSKY and C. MROTZEK, Phys. Stat. Sol. (a) 123 (1991) 461.

    Google Scholar 

  23. Z. CALAHORRA, E. MINAMI, R. M. WHITE and R. S. MULLER, J. Electrochem. Soc. 136 (1989) 1839.

    Google Scholar 

  24. W. F. WU and B. S. CHIOU, Thin Solid Films 247 (1994) 201.

    Google Scholar 

  25. H. NANTO, T. MINAMI, S. ORITO and S. TAKATA, J. Appl. Phys. 63 (1988) 2711.

    Google Scholar 

  26. M. BUCHANAN, J. B. WEBB and D. F. WILLIAMS, Appl. Phys. Lett. 37 (1981) 213.

    Google Scholar 

  27. S. RAY, R. BENERJEE, N. BASU, A. K. BABABYAL and A. K. BARU, J. Appl. Phys. 54 (1983) 3497.

    Google Scholar 

  28. A. MUKHERJEE, Vacuum, 39 (1989) 537.

    Google Scholar 

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Chiou, BS., Lee, JH. Etching of r.f. magnetron-sputtered indium tin oxide films. J Mater Sci: Mater Electron 7, 241–246 (1996). https://doi.org/10.1007/BF00133122

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  • DOI: https://doi.org/10.1007/BF00133122

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