Abstract
Anionic polymerization high vacuum techniques (HVTs) are the most suitable for the preparation of polymer samples with well-defined complex macromolecular architectures. Though HVTs require glassblowing skill for designing and making polymerization reactor, it is the best way to avoid any termination of living polymers during the number of steps for the synthesis of polymers with complex structure. In this chapter, we describe the different polymerization reactors and HVTs for the purification of monomers, solvents, and other reagents for anionic polymerization as well as few model reactions for the synthesis of polymers with simple to complex structure.
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List of Abbreviations and Symbols
List of Abbreviations and Symbols
- 2VP:
-
2-Vinyl pyridine
- Bd:
-
1,3-Butadiene
- CaH2 :
-
Calcium hydride
- D3:
-
Hexamethylcyclotrisiloxane
- DBMg:
-
Dibutylmagnesium
- DCMSDPE:
-
4-(Dichloromethylsilyl)diphenylethylene
- DLI:
-
Dilithium initiator
- DPE:
-
1,1-Diphenylethylene
- EO:
-
Ethylene oxide
- GPC:
-
Gel permeation chromatography
- HVTs:
-
High Vacuum Techniques
- LN:
-
Liquid nitrogen
- M n :
-
Number-average molecular weight
- n-BuLi:
-
n-Butyl Lithium
- P2VP:
-
Poly(2-vinylpyridine)
- PBd:
-
Polybutadiene
- PDI:
-
Polydispersity Index
- PDMS:
-
Polydimethylsiloxane
- PEB:
-
1,3-bis(1-Phenylethenyl)benzene
- PI:
-
Polyisoprene
- PSLi:
-
Polystyryllithium
- SEC:
-
Size exclusion chromatography
- sec-BuLi:
-
sec-Butyl Lithium
- TEA:
-
Triethylamine
- THF:
-
Tetrahydrofuran
- TOA:
-
Trioctyl aluminum
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Ratkanthwar, K., Hadjichristidis, N., Mays, J. (2015). High Vacuum Techniques for Anionic Polymerization. In: Hadjichristidis, N., Hirao, A. (eds) Anionic Polymerization. Springer, Tokyo. https://doi.org/10.1007/978-4-431-54186-8_2
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DOI: https://doi.org/10.1007/978-4-431-54186-8_2
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