Abstract
This volume on boron isotope geochemistry contains chapters reviewing the low- and high-temperature geochemistry, marine chemistry, and cosmochemistry of boron isotopes. It covers theoretical aspects of B isotope fractionation, experiments and atomic modeling, as well as all aspects of boron isotope analyses in geologic materials by the full range of solution and in situ methods. The book provides guidance for researchers on the analytical and theoretical end, and introduces the various scientific applications and research fields in which boron isotopes play a growing role today. This chapter provides a brief history of boron isotope research and analytical development and provides an overview of the other chapters of the volume “Boron Isotopes—The Fifth Element” in the series Advancements in Isotope Geochemistry.
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Notes
- 1.
\( \delta^{11} {\text{B}} \) values are calculated from the reported \( ^{11} {\text{B}}/{^{10}} {\text{B}} \) ratios relative to the certified ratio of SRM951.
References
Abernathey RM (1960) Isotopic analysis of boron as trimethyl borate, vol 14503. U. S. Atomic Energy Commision, IDO, Idaho Falls, Idaho
Aggarwal SK, You CF (2016) A review on the determination of isotope ratios of boron with mass spectrometry. Mass Spectrom Rev 9999:1–21
Aggarwal JK, Sheppard D, Mezger K, Pernicka E (2003) Precise and accurate determination of boron isotope ratios by multiple collector ICP-MS: origin of boron in the Ngawha geothermal system, New Zealand. Chem Geol 199:331–342
Aggarwal J, Böhm F, Foster G, Halas S, Hönisch B, Jiang SY, Košler J, Liba A, Rodushkin I, Sheehan T, Shen JJS, Tonarini S, Xie Q, You CF, Zhao ZQ, Zuleger E (2009) How well do non-traditional stable isotope results compare between different laboratories: results from interlaboratory comparison of boron isotope measurements. J Analyt Atom Spectrom 24:825–831
Agyei EK, McMullen CC (1968) A study of the isotopic abundance of boron from various sources. Can J Earth Sci 5:921–927
Al-Ammar AS, Reitznerová E, Barnes RM (2000) Improving boron isotope ratio measurement precision with quadropole inductively coupled plasma-mass spectrometry. Spectrochim Acta B 55:1861–1867
Altherr R, Topuz G, Marschall H, Zack T, Ludwig T (2004) Evolution of a tourmaline-bearing lawsonite eclogite from Elekdag area (Central Pontides, N Turkey): evidence for infiltration of slab-derived -rich fluids during exhumation. Contrib Mineral Petrol 148:409–425
Aston FW (1919) A positive ray spectrograph. Phil Mag 38:707–714
Aston FW (1920) The mass-spectra of chemical elements (Part 2.). Phil Mag 40:628–634
Aston FW (1927) Bakerian Lecture. A new mass-spectrograph and the whole number rule. Proc Royal Soc A 115:487–514
Aston FW (1931) The isotopic constitution and atomic weights of selenium, bromine, boron, tungsten, antimony, osmium, ruthenium, tellurium, germanium, rhenium and chlorine. Proc Royal Soc 132:487–498
Barth S (1998) 11B/10B variations of dissolved boron in a freshwater-seawater mixing plume (Elbe Estuary, North Sea). Marine Chem. 62:1–14
Baxter GP, Scott AF (1921) The atomic weight of boron. Science 54:524–525
Beams JW, Haynes FB (1936) The separation of isotopes by centrifuging. Phys Rev 50:491–492
Bentley PG (1960) Isotopic analysis of boron in boron trifluoride by mass spectrometery and measurement of natural boron 10 concentration. J Sci Instrum 37:323–328
Brand WA, Coplen TB, Vogl J, Rosner M, Prohaska T (2014) Assessment of international reference materials for isotope-ratio analysis (IUPAC Technical Report). Pure Appl Chem 86:425–467
Branson O (2017) Boron incorporation into marine CaCO3. In: Marschall HR, Foster GL (eds) Boron isotopes—The fifth element, advances in isotope geochemistry, vol 7. Springer, Heidelberg
Briscoe HVA, Robinson PL (1925) A redetermination of the atomic weight of boron. J Chem Soc Transact 127:696–720
Catanzaro EJ, Champion CE, Garner EL, Marinenko G, Sappenfield KM, Shields WR (1970) Boric acid: isotopic and assay standard reference materials. NBS (US) Spec Publ 260–17:1–71
Chadwick J (1933) Bakerian Lecture. The neutron. Proc Royal Soc A 142:1–25
Chakraborty S, Dingwell DB, Chaussidon M (1993) Chemical diffusivity of boron in melts of haplogranitic composition. Geochim Cosmochim Acta 57:1741–1751
Chaussidon M, Albarède F (1992) Secular boron isotope variations in the continental crust: an ion microprobe study. Earth Planet Sci Lett 108:229–241
Chaussidon M, Jambon A (1994) Boron content and isotopic composition of oceanic basalts: geochemical and cosmochemical implications. Earth Planet Sci Lett 121:277–291
Chaussidon M, Robert F (1995) Nucleosynthesis of 11B-rich boron in the pre-solar cloud recorded in meteoritic chondrules. Nature 374:337–339
Chaussidon M, Robert F, Mangin D, Hanon P, Rose EF (1997) Analytical procedures for the measurement of boron isotope composition by ion microprobe in meteorites and mantle rocks. Geostand Newsl 21:7–17
Christie WH, Eby RE, Warmack RJ, Landau L (1981) Determination of boron and lithium in nuclear materials by secondary ion mass spectrometry. Anal Chem 53:13–17
Conger AD (1953) The effect of boron enrichment on slow neutron-irradiated tissues. Genetics 38:128–133
De Hoog CJ, Savov IP (2017) Subduction zones, dehydration, metasomatism, mud and serpentinite volcanoes, and arc magmatism. In: Marschall HR, Foster GL (eds) Boron isotopes—The fifth element, advances in isotope geochemistry, vol. 7. Springer, Heidelberg
Dempster AJ (1918) A new method of positive ray analysis. Phys Rev 11:316–325
Duchateau NL, De Bièvre P (1983) Boron isotopic measurements by thermal ionization mass spetrometry using the negative BO2 − ion. Internat. J. Mass Spectrom 54:289–297
Elliott A (1930a) Determination of the abundance ratios of isotopes from band spectra. Nature 126:845–846
Elliott A (1930b) Isotope effect in the spectrum of boron monoxide: intensity measurements and structure of the β-bands. Nature 126:203–204
Fietzke J, Heinemann A, Taubner I, Böhm F, Erez J, Eisenhauer A (2010) Boron isotope ratio determination in carbonates via LA-MC-ICP-MS using soda-lime glass standards as reference material. J Analyt Atom Spectrom 25:1953–1957
Finley HO, Eberle AR, Rodden CJ (1962) Isotopic boron composition of certain boron minerals. Geochim Cosmochim Acta 26:911–914
Foster GL (2008) Seawater pH, pCO2 and [CO3 2−] variations in the Caribbean Sea over the last 130kyr: a boron isotope and B/Ca study of planktic foraminifera. Earth Planet Sci Lett 271:254–266
Foster GL, Hönisch B, Paris G, Dwyer GS, Rae JWB, Elliott T, Gaillardet J, Hemming NG, Louvat P, Vengosh A (2013) Interlaboratory comparison of boron isotope analyses of boric acid, seawater and marine CaCO3 by MC-ICPMS and NTIMS. Chem Geol 358:1–14
Foster GL, Lécuyer C, Marschall HR (2016) Boron stable isotopes. In: White WM (ed) Encyclopedia of geochemistry, encyclopedia earth science series. Springer, Berlin, pp 1–6
Foster GL, Marschall HR, Palmer MR (2017) Boron isotope analysis of geologic materials. In: Marschall HR, Foster GL (eds) Boron isotopes—The fifth element, advances in isotope geochemistry, vol 7. Springer, Heidelberg
Gäbler HE, Bahr A (1999) Boron isotope ratio measurements with a double-focusing magnetic sector ICP mass spectrometer for tracing anthropogenic input into surface and ground water. Chem Geol 156:323–330
Gaillardet J, Lemarchand D (2017) Boron isotopes in riverine systems and the weathering environment. In: Marschall HR, Foster GL (eds) Boron isotopes—The fifth element, Advances in Isotope Geochemistry, vol. 7. Springer, Heidelberg
Gensho R, Honda M (1971) Measurement of the isotopic ratio of boron. J Mass Spectrom Soc Japan 19:134–143. (Japanese with English abstract)
Gonfiantini R, Tonarini S, Gröning M, Adorni-Braccesi A, Al-Ammar AS, Astner M, Bächler S, Barnes RM, Basset RL, Cocherie A, Deyhle A, Dini A, Ferrara G, Gaillardet J, Grimm J, Guerrot C, Krähenbühl U, Layne G, Lemarchand D, Meixner A, Northington DJ, Pennisi M, Reitznerová E, Rodushkin I, Sugiura N, Surberg R, Tonn S, Wiedenbeck M, Wunderli S, Xiao Y, Zack T (2003) Intercomparison of boron isotope and concentration measurements. Part II: evaluation of results. Geostand Newsl 27:41–57
Gounelle M, Chaussidon M, Rollion-Bard C (2013) Variable and extreme irradiation conditions in the early solar system inferred from the initial abundance of 10Be in Isheyevo CAIs. Astrophys J Lett 763:L33
Gregoire DC (1987) Determination of boron isotope ratios in geological materials by inductively coupled plasma mass spectrometry. Anal Chem 59:2479–2484
Grew ES, Anovitz LM (1996) Boron: mineralogy, petrology and geochemistry, reviews in mineralogy, vol 33. Mineralogical Society of America, Washington, D.C., 864p
Gurenko AA, Schmincke HU (2002) Orthopyroxene-bearing tholeiites of the Iblean Plateau (Sicily): constraints on magma origin and evolution from glass inclusions in olivine and orthopyroxene. Chem Geol 183:305–331
Hawthorne FC, Burns PC, Grice JD (1996) The crystal chemistry of boron. In: Grew E, LM A (eds) Boron: mineralogy, petrology and geochemistry, reviews in mineralogy, vol 33. Mineralogical Society of America, Washington, D.C., pp 41–116
Hemming NG, Hanson GN (1992) Boron isotopic composition and concentration in modern marine carbonates. Geochim Cosmochim Acta 56:537–543
Hemming NG, Reeder RJ, Hanson GN (1995) Mineral-fluid partitioning and isotopic fractionation of boron in synthetic calcium carbonate. Geochim Cosmochim Acta 59:371–379
Hervig RL, Moore GM, Williams LB, Peacock SM, Holloway JR, Roggensack K (2002) Isotopic and elemental partitioning of boron between hydrous fluid and silicate melt. Am Mineral 87:769–774
Hönisch B, Hemming NG (2005) Surface ocean pH response to variations in pCO2 through two full glacial cycles. Earth Planet Sci Lett 236:305–314
Hoppe P, Goswami JN, Krähenbühl U, Marti K (2001) Boron in chondrules. Meteor Planet Sci 36:1331–1343
Hou KJ, Li YH, Xiao YK, Liu F, Tian YR (2010) In situ boron isotope measurements of natural geological materials by LA-MC-ICP-MS. Chinese Sci Bull 55:3305–3311
Inghram MG (1946) The isotopic constitution of tungsten, silicon, and boron. Phys Rev 70:653–660
Ishikawa T, Nakamura E (1994) Origin of the slab component in arc lavas from across-arc variation of B and Pb isotopes. Nature 370:205–208
Jenkins FA, McKellar A (1932) Mass ratio of the boron isotopes from the spectrum of BO. Phys Rev 42:464–487
Kakihana H, Kotaka M, Satoh S, Nomura M, Okamoto M (1977) Fundamental studies on the ion exchange separation of boron isotopes. Bull Chem Soc Japan 50:158–163
Kasemann S, Meixner A, Rocholl A, Vennemann T, Rosner M, Schmitt AK, Wiedenbeck M (2001) Boron and oxygen isotopic composition of certified reference materials NIST SRM 610/612 and reference materials JB-2 and JR-2. Geostand Newsl 25:405–416
Kasemann SA, Schmidt DN, Bijma J, Foster GL (2009) In situ boron isotope analysis in marine carbonates and its application for foraminifera and palaeo-pH. Chem Geol 260:138–147
Klochko K, Kaufmann AJ, Yao W, Byrne RH, Tossell JA (2006) Experimental measurement of boron isotope fractionation in seawater. Earth Planet Sci Lett 248:276–285
Kobayashi K, Tanaka R, Moriguti T, Shimizu K, Nakamura E (2004) Lithium, boron, and lead isotope systematics of glass inclusions in olivines from Hawaiian lavas: evidence for recycled components in the Hawaiian plume. Chem Geol 212:143–161
Kowalski P, Wunder B (2017) Boron-isotope fractionation among solids-fluids-melts: experiments and atomic modeling. In: Marschall HR, Foster GL (eds) Boron isotopes—The fifth element, advances in isotope geochemistry, vol 7. Springer, Heidelberg
Kowalski PM, Wunder B, Jahn S (2013) Ab initio prediction of equilibrium boron isotope fractionation between minerals and aqueous fluids at high P and T. Geochim Cosmochim Acta 101:285–301
le Roux PJ, Shirey SB, Benton L, Hauri EH, Mock TD (2004) In situ, multiple-multiplier, laser ablation ICP-MS measurement of boron isotopic composition (δ 11B) at the nanogram level. Chem Geol 203:123–138
Lécuyer C, Grandjean P, Reynard B, Albarède F, Telouk P (2002) 11B10B analysis of geological materials by ICP-MS Plasma 54: application to the boron fractionation between brachiopod calcite and seawater. Chem Geol 186:45–55
Leeman WP, Sisson VB (1996) Geochemistry of boron and its implications for crustal and mantle processes. In: Grew ES, Anovitz LM (eds) Boron: mineralogy, petrology and geochemistry, reviews in mineralogy, Vol 33. Mineralogical Society of America, Washington, D.C., pp 645–695
Lehmann WJ, Shapiro I (1959) Isotopic composition of boron and its atomic weight. Nature 183:1324
Lemarchand D, Schott J, Gaillardet J (2007) How surface complexes impact boron isotope fractionation: evidence from Fe and Mn oxides sorption experiments. Earth Planet Sci Lett 260:277–296
Liu MC, Chaussidon M (2017) The cosmochemistry of boron isotopes. In: Marschall HR, Foster GL (eds) Boron isotopes—The fifth element, advances in isotope geochemistry, vol 7. Springer, Heidelberg
MacPherson GJ, Huss GR, Davis AM (2003) Extinct 10Be in Type A calcium-aluminum-rich inclusions from CV chondrites. Geochim Cosmochim Acta 67:3165–3179
Marschall HR (2017) Boron isotopes in the ocean floor realm and the mantle. In: Marschall HR, Foster GL (eds) Boron isotopes—The fifth element, advances in isotope geochemistry, vol 7. Springer, Heidelberg
Marschall HR, Wanless VD, Shimizu N, Pogge von Strandmann PAE, Elliott T, Monteleone BD (2017) The boron and lithium isotopic composition of mid-ocean ridge basalts and the mantle. Geochimica et Cosmochimca Acta 207:102–138. doi:10.1016/j.gca.2017.03.028
Martnez-Bot MA, Marino G, Foster GL, Ziveri P, Henehan MJ, Rae JWB, Mortyn PG, Vance D (2015) Boron isotope evidence for oceanic carbon dioxide leakage during the last deglaciation. Nature 518:219–222
McCulloch MT, D’Olivio JP, Falter J, Georgiou L, Holcomb M, Montagna P, Trotter J (2017) Boron isotopes in corals. In: Marschall HR, Foster GL (eds) Boron isotopes—The fifth element, advances in isotope geochemistry, vol 7. Springer, Heidelberg
McKeegan KD, Chaussidon M, Robert F (2000) Incorporation of short-lived 10Be in a calciu-aluminium-rich inclusion from the Allende meteorite. Science 289:1334–1337
McMullen CC, Cragg CB, Thode HG (1961) Absolute ratio of 11B/10B in Searles Lake borax. Geochim Cosmochim Acta 23:147–150
Nakano T, Nakamura E (2001) Boron isotope geochemistry of metasedimentary rocks and tourmalines in a subduction zone metamorphic suite. Phys Earth Planet Inter 127:233–252
Ornstein LS, Vreeswijk JA (1933) Messung des Intensitätsverhältnisses der Bor-Isotope B10 und B11. Zeitschr Phys 80:57–58
Osberghaus O (1950) Die Isotopenhäufigkeit des Bors. Massenspektrometrische Untersuchung der Elektronenstoßprodukte von BF3 und BCl3. Zeitschr Phys 128:366–377
Palmer MR, Swihart GH (1996) Boron isotope geochemistry: an overview. In: Grew ES, Anovitz LM (eds) Boron: mineralogy, petrology and geochemistry, Reviews in Mineralogy, 1st edn, Vol 33. Mineralogical Society of America, Washington, DC, pp 709–740
Parwel A, von Ubisch H, Wickman FE (1956) On the variations in the relative abundance of boron isotopes in nature. Geochim Cosmochim Acta 10:185–190
Peacock SM, Hervig RL (1999) Boron isotopic composition of subduction-zone metamorphic rocks. Chem Geol 160:281–290
Phinney D, Whitehead B, Anderson D (1979) Li, Be, and B in minerals of a refractory-rich Allende inclusion. In: Proceedings 10th Lunar and Planetary Science Conference, pp 885–905
Porteous NC, Walsh JN, Jarvis KE (1995) Measurement of boron isotope ratios in groundwater studies. Analyst 120:1397–1400
Rae JWB (2017) Boron isotopes in foraminfera. In: Marschall HR, Foster GL (eds) Boron isotopes—the fifth element, advances in isotope geochemistry, vol 7. Springer, Heidelberg
Ramakumar KL, Parab AR, Khodade PS, Almaula AI, Chitambar SA, Jain HJ (1985) Determination of isotopic composition of boron. Radioanal Nucl Chem Lett 94:53–62
Rose E, Shimizu N, Layne G, Grove TL (2001) Melt production beneath Mt. Shasta from boron data in primitive melt inclusions. Science 293:281–283
Rosner M, Meixner A (2004) Boron isotopic composition and concentration of ten geological reference materials. Geostand Geoanal Res 28:431–441
Rustad JR, Bylaska EJ (2007) Ab initio calculation of isotopic fractionation in BH(OH)3(aq) and BHOH4 −(aq). J Am Chem Soc 129:2222–2223
Sanyal A, Nugent M, Reeder RJ, Bijma J (2000) Seawater pH control on the boron isotopic composition of calcite: evidence from inorganic calcite precipitation experiments. Geochim Cosmochim Acta 64:1551–1555
Scambelluri M, Tonarini S (2012) Boron isotope evidence for shallow fluid transfer across subduction zones by serpentinized mantle. Geology 40:907–910
Sears VF (1992) Neutron scattering lengths and cross sections. Neutr News 3:26–37
Shima M (1962) Boron in Meteorites. J Geophys Res 67:4521–4523
Shima M (1963) Geochemical study of boron isotopes. Geochim Cosmochim Acta 27:911–913
Shimizu N, Hart SR (1982) Isotope fractionation in secondary ion mass spectometry. J Appl Phys 53:1303–1311
Smith MP, Yardley BWD (1996) The boron isotopic composition of tourmaline as a guide to fluid processes in the southwestern England orefield: an ion microprobe study. Geochim Cosmochim Acta 60:1415–1427
Spivack AJ, Edmond JM (1986) Determination of boron isotope ratios by thermal ionization mass spectrometry of the dicesium metaborate cation. Anal Chem 58:31–35
Spivack AJ, Edmond JM (1987) Boron isotope exchange between seawater and the oceanic crust. Geochim Cosmochim Acta 51:1033–1043
Sugiura N, Shuzou Y, Ulyanov A (2001) Beryllium-boron and aluminium-magnesium chronology of calcium-aluminium-rich inclusions in CV chondrites. Meteor Planet Sci 36:1397–1408
Thode HG, Macnamara J, Lossing FP, Collins CB (1948) Natural variations in the isotopic content of boron and its chemical atomic weight. J Am Chem Soc 70:3008–3011
Thomson JJ (1913) Bakterian Lecture: rays of positive electricity. Proc Royal Soc A 89:1–20
Tiepolo M, Bouman C, Vannucci R, Schwieters J (2006) Laser ablation multicollector ICP-MS determination of δ 11B in geological samples. Appl Geochem 21:788–801
Tonarini S, Pennisi M, Adorno-Braccesi A, Dini A, Ferrara G, Gonfiantini R, Wiedenbeck M, Gröning M (2003) Intercomparison of boron isotope and concentration measurements. Part I: selection, preparation and homogeneity tests of the intercomparison materials. Geostand Newsl 27:21–39
Trumbull RB, Slack JF (2017) Continental crust, granites, pegmatites, high-T crustal metamorphism, and ore deposits. In: Marschall HR, Foster GL (eds) Boron isotopes—The fifth element, advances in isotope geochemistry, vol 7. Springer, Heidelberg
Urey HC, Greiff LJ (1935) Isotopic exchange equilibria. J Am Chem Soc 57:321–327
Williams LB, Hervig RL (2005) Lithium and boron isotopes in illite-smectite: the importance of crystal size. Geochim Cosmochim Acta 69:5705–5716
Williams LB, Hervig RL, Holloway JR, Hutcheon I (2001) B isotope geochemistry during diagenesis. Part I. Experimental determination of fractionation during illitization of smectite. Geochim Cosmochim Acta 65:1769–1782
Wunder B, Meixner A, Romer RL, Wirth R, Heinrich W (2005) The geochemical cycle of boron: constraints from boron isotope partitioning experiments between mica and fluid. Lithos 84:206–216
Yates EL (1938) The separation of isotopes for the investigation of nuclear transmutations. Proc Royal Soc 168:148–158
You CF (2004) Thermal ionization mass spectrometry techniques for boron isotopic analysis: a review. In: de Groot PA (ed) Handbook of Stable Isotope Analytical Techniques, vol 1. Elsevier, Amsterdam, pp 142–152
Zahl PA, Cooper FS (1941) Physical and biological considerations in the use of slow neutrons for cancer therapy. Radiology 37:673–682
Zeininger H, Heumann KG (1983) Boron isotope ratio measurements by negative ionization mass spectrometry. Internat J Mass Spectrom 48:377–380
Acknowledgements
We would like to thank series editor Jochen Hoefs for inviting us to contribute this volume on boron isotopes to the Springer series Advances in Isotope Geochemistry. We are also grateful to Springer editors Annett Büttner and Chris Bendall for their support at various stages of the project. James Rae is thanked for editorial handling of Chaps. 1 and 2. Preparation of this review chapter was financially supported by a WHOI Independent Study Award from the Andrew W. Mellon Foundation to HRM.
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Marschall, H.R., Foster, G.L. (2018). Boron Isotopes in the Earth and Planetary Sciences—A Short History and Introduction. In: Marschall, H., Foster, G. (eds) Boron Isotopes. Advances in Isotope Geochemistry. Springer, Cham. https://doi.org/10.1007/978-3-319-64666-4_1
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