Abstract
Alternative energy sources are currently worldwide under development to contribute to the increasing energy demand. Along with the introduction of new technologies, heavy metals, such as radionuclides from nuclear power plant leaks, might be released into the environment and contaminate waters, air, and soil. Among the investigated methods, the use of adsorbents has been proven the most suitable one, able to extensively remove heavy metals, e.g., radioactive 137Cs+. Prussian blue analogs (PBAs) have been demonstrated to be effective adsorbents toward the sequestration of a variety of heavy metals, including the recovery and valorization of rare earth elements. Here, we point out the structure-property link of PBAs: the large channels and cavities are able to accommodate a variety of ions, ranging from monovalent to multivalent ones, while the ion exchange may be either diffusion-controlled or electrochemically driven. While distribution coefficients are shown to be key parameters in the diffusion driven process, resulting in high affinities of PBAs toward metals such as Cs+, Tl+, Cu2+, and Zn2+, electrochemical ion exchange is considered to be promising due to the effectiveness in the removal of metals and the possibility to reversibly restore the adsorbent to its initial state. Related examples concerning the capture of Cs+ from wastewaters and the recovery of rare earth elements are herein presented and commented.
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References
Abdi MR, Kamali M, Vaezifar S (2008) Distribution of radioactive pollution of 238U, 232Th, 40K and 137Cs in northwestern coasts of Persian Gulf, Iran. Mar Pollut Bull 56:751–757. https://doi.org/10.1016/j.marpolbul.2007.12.010
Altagracia-Martinez M, Kravzov-Jinich J, Martínez-Núñez J, Ríos-Castañeda C, López-Naranjo F (2012) Prussian blue as an antidote for radioactive thallium and cesium poisoning. Orphan Drugs Res Rev 2012:13. https://doi.org/10.2147/odrr.s31881
Arisaka M, Watanabe M, Ishizaki M, Kurihara M, Chen R, Tanaka H (2015) Cesium adsorption ability and stability of metal hexacyanoferrates irradiated with gamma rays. J Radioanal Nucl Chem 303:1543–1547. https://doi.org/10.1007/s10967-014-3710-0
Berrettoni M, Giorgetti M, Zamponi S, Conti P, Ranganathan D, Zanotto A, Saladino ML, Caponetti E (2010) Synthesis and characterization of nanostructured cobalt hexacyanoferrate. J Phys Chem C 114:6401–6407. https://doi.org/10.1021/jp100367p
Borai EH, Harjula R, Malinen L, Paajaneen A (2009) Efficient removal of cesium from low-level radioactive liquid waste using natural and impregnated zeolite minerals. J Hazard Mater 172:416–422. https://doi.org/10.1016/j.jhazmat.2009.07.033
Bordage A, Moulin R, Fonda E, Fornasieri G, Riviere E, Bleuzen A (2018) Evidence of the core-shell structure of (photo)magnetic CoFe Prussian blue analogue nanoparticles and peculiar behavior of the surface species. J Am Chem Soc 140:10332–10343. https://doi.org/10.1021/jacs.8b06147
Bueno PR, Ferreira FF, Giménez-Romero D, Setti GO, Faria RC, Gabrielli C, Perrot H, García-Jareño JJ, Vicente F (2008) Synchrotron structural characterization of electrochemically synthesized hexacyanoferrates containing K+: a revisited analysis of electrochemical redox. J Phys Chem C 112:13264–13271. https://doi.org/10.1021/jp802070f
Buser HJ, Shwarzenbach D, Petter W, Ludi A (1977) The crystal structure of Prussian blue: Fe4[Fe(CN)6]3.xH2O. Inorg Chem 16:2704–2710. https://doi.org/10.1021/ic50177a008
Chae MS, Hyoung J, Jang M, Lee H, Hong S-T (2017) Potassium nickel hexacyanoferrate as a high-voltage cathode material for nonaqueous magnesium-ion batteries. J Power Sources 363:269–276. https://doi.org/10.1016/j.jpowsour.2017.07.094
Champion G, Escax V, Cartier dit Moulin C, Bleuzen A, Villain F, Baudelet F, Dartyge E, Verdaguer M (2001) Photoinduced ferrimagnetic systems in Prussian blue analogues CI xCo4[Fe(CN)6]y (CI = alkali cation). 4. Characterization of the ferrimagnetism of the photoinduced metastable state in Rb1.8Co4[Fe(CN)6]3.3·13H2O by K edges x-ray magnetic circular dichroism. J Am Chem Soc 123:12544–12546. https://doi.org/10.1021/ja011297j
Chen SM, Chan CM (2003) Preparation, characterization, and electrocatalytic properties of copper hexacyanoferrate film and bilayer film modified electrodes. J Electroanal Chem 543:161–173. https://doi.org/10.1016/S0022-0728(03)00017-2
Chen SM, Peng KT, Lin KC (2005) Preparation of thallium hexacyanoferrate film and mixed-film modified electrodes with cobalt(II) hexacyanoferrate. Electroanalysis 17:319–326. https://doi.org/10.1002/elan.200403065
Chen R, Tanaka H, Kawamoto T, Asai M, Fukushima C, Kurihara M, Watanabe M, Arisaka M, Nankawa T (2012) Preparation of a film of copper hexacyanoferrate nanoparticles for electrochemical removal of cesium from radioactive wastewater. Electrochem Commun 25:23–25. https://doi.org/10.1016/j.elecom.2012.09.012
Chen R, Tanaka H, Kawamoto T, Asai M, Fukushima C, Kurihara M, Ishizaki M, Watanabe M, Arisaka M, Nankawa T (2013a) Thermodynamics and mechanism studies on electrochemical removal of cesium ions from aqueous solution using a nanoparticle film of copper hexacyanoferrate. ACS Appl Mater Interfaces 5:12984–12990. https://doi.org/10.1021/am403748b
Chen R, Tanaka H, Kawamoto T, Asai M, Fukushima C, Na H, Kurihara M, Watanabe M, Arisaka M, Nankawa T (2013b) Selective removal of cesium ions from wastewater using copper hexacyanoferrate nanofilms in an electrochemical system. Electrochim Acta 87:119–125. https://doi.org/10.1016/j.electacta.2012.08.124
Ciabocco M, Berrettoni M, Zamponi S, Spinosi R, Conti P (2018) An overview on the facile and reversible cations intercalation in nickel-hexacyanoferrate open framework. Int J Electrochem Sci 13:5535–5551. https://doi.org/10.20964/2018.06.37
Cox JA, Das BK (1985) Voltammetric determination of nonelectroactive ions at a modified electrode. Anal Chem 57:2739–2740. https://doi.org/10.1021/ac00290a068
De Lara González GL, Kahlert H, Scholz F (2007) Catalytic reduction of hydrogen peroxide at metal hexacyanoferrate composite electrodes and applications in enzymatic analysis. Electrochim Acta 52:1968–1974. https://doi.org/10.1016/j.electacta.2006.08.006
Düssel H, Dostal A, Scholz F (1996) Hexacyanoferrate-based composite ion-sensitive electrodes for voltammetry. Fresenius J Anal Chem 355:21–28. https://doi.org/10.1007/s0021663550021
Eftekhari A (2004) Potassium secondary cell based on Prussian blue cathode. J Power Sources 126:221–228. https://doi.org/10.1016/j.jpowsour.2003.08.007
El-Bahy SM, Fadel DA, El-Bahy ZM, Metwally AM (2018) Rapid and highly efficient cesium removal by newly synthesized carbomer encapsulated potassium copper hexacyanoferrate composite. J Environ Chem Eng 6:1875–1885. https://doi.org/10.1016/j.jece.2018.02.030
Engel D, Grabner EW (1985) Copper hexacyanoferrate-modified glassy carbon: a novel type of potassium-selective electrode. Ber Bunsenges Phys Chem 89:982–986. https://doi.org/10.1002/bbpc.19850890911
Escax V, Bleuzen A, Cartier dit Moulin C, Villain F, Goujon A, Varret F, Verdaguer M (2001) Photoinduced ferrimagnetic systems in Prussian blue analogues CIxCo4[Fe(CN)6]y (CI = Alkali Cation). 3. Control of the photo- and thermally induced electron transfer by the [Fe(CN)6] vacancies in cesium derivatives. J Am Chem Soc 123:12536–12543. https://doi.org/10.1021/ja011296r
Faustino PJ, Yang Y, Progar JJ, Brownell CR, Sadrieh N, May JC, Leutzinger E, Place DA, Duffy EP, Houn F, Loewke SA, Mecozzi VJ, Ellison CD, Khan MA, Hussain AS, Lyon RC (2008) Quantitative determination of cesium binding to ferric hexacyanoferrate: Prussian blue. J Pharm Biomed Anal 47:114–125. https://doi.org/10.1016/j.jpba.2007.11.049
Giorgetti M, Scavetta E, Berrettoni M, Tonelli D (2001) Nickel hexacyanoferrate membrane as a coated wire cation-selective electrode. Analyst 126:2168–2171. https://doi.org/10.1039/b107034g
Giorgetti M, Aquilanti G, Ciabocco M, Berrettoni M (2015) Anatase-driven charge transfer involving a spin transition in cobalt iron cyanide nanostructures. Phys Chem Chem Phys 17:22519–22522. https://doi.org/10.1039/C5CP03580E
Guadagnini L, Tonelli D, Giorgetti M (2010) Improved performances of electrodes based on Cu2+-loaded copper hexacyanoferrate for hydrogen peroxide detection. Electrochim Acta 55:5036–5039. https://doi.org/10.1016/j.electacta.2010.04.019
Hartmann M, Grabner EW, Bergveld P (1991) Alkali ion sensor based on Prussian blue-covered interdigitated array electrodes. Sensors Actuators B Chem 4:333–336. https://doi.org/10.1016/0925-4005(91)80132-4
Herren F, Fisher P, Ludi A, Halg W (1980) Neutron diffraction study of Prussian blue, Fe4[Fe(CN)6]3.xH2O. Location of water molecules and long-range magnetic order. Inorg Chem 19:956–959. https://doi.org/10.1021/ic50206a032
Ho K-C, Lin C-L (2001) A novel potassium ion sensing based on Prussian blue thin films. Sensors Actuators B Chem 76:512–518. https://doi.org/10.1016/S0925-4005(01)00605-0
Huang C-Y, Lee J-D, Tseng C-L, Lo J-M (1994) A rapid method for the determination of 137Cs in environmental water samples. Anal Chim Acta 294:221–226. https://doi.org/10.1016/0003-2670(94)80198-3
International Atomic Energy Agency (1988) The radiological accident in Goiânia, Vienna. https://www-pub.iaea.org/mtcd/publications/pdf/pub815_web.pdf. ISBN 92–0–129088-8
Itaya K, Shoji N, Uchida I (1984) Catalysis of the reduction of molecular oxygen to water at Prussian blue modified electrodes. J Am Chem Soc 106:3423–3429. https://doi.org/10.1021/ja00324a007
Ito A, Suenaga M, Ono K (1968) Mössbauer study of soluble Prussian blue, insoluble Prussian blue, and Turnbull’s blue. J Chem Phys 48:3597–3599. https://doi.org/10.1063/1.1669656
Iwanade A, Kasai N, Hoshina H, Ueki Y, Saiki S, Seko S (2012) Hybrid grafted ion exchanger for decontamination of radioactive cesium in Fukushima Prefecture and other contaminated areas. J Radioanal Nucl Chem 293:703–709. https://doi.org/10.1007/s10967-012-1721-2
Jiao S, Tuo J, Xie H, Cai Z, Wang S, Zhu Y (2017) The electrochemical performance of Cu3[Fe(CN)6]2 as a cathode material for sodium-ion batteries. Mater Res Bull 86:194–200. https://doi.org/10.1016/j.materresbull.2016.10.019
Karyakin AA (2001) Prussian blue and its analogues: electrochemistry and analytical applications. Electroanalysis 13:813–819. https://doi.org/10.1002/1521-4109(200106)13:10%3c813:AID-ELAN813%3e3.0.CO;2-Z
Keggin JF, Miles FD (1936) Structures and formulæ of the Prussian blues and related compounds. Nature 137:577–578. https://doi.org/10.1038/137577a0
Kim YK, Kim Y, Kim S, Harbottle D, Lee W (2017) Solvent-assisted synthesis of potassium copper hexacyanoferrate embedded 3D-interconnected porous hydrogel for highly selective and rapid cesium ion removal. J Environ Chem Eng 5:975–986. https://doi.org/10.1016/j.jece.2017.01.026
Kravzov J, Rios C, Altagracia M, Monroy-Noyola A, López F (1993) Relationship between physicochemical properties of Prussian blue and its efficacy as antidote against thallium poisoning. J Appl Toxicol 13:213–216. https://doi.org/10.1002/jat.2550130313
Krishnan V, Xidis AL, Neff VD (1990) Prussian blue solid-state films and membranes as potassium ion-selective electrodes. Anal Chim Acta 239:7–12. https://doi.org/10.1016/S0003-2670(00)83828-3
Lee H, Kim YI, Park JK, Choi JW (2012) Sodium zinc hexacyanoferrate with a well-defined open framework as a positive electrode for sodium ion batteries. Chem Commun 48:8416–8418. https://doi.org/10.1039/C2CC33771A
Lee HW, Wang RY, Pasta M, Lee SW, Liu N, Cui Y (2014) Manganese hexacyanomanganate open framework as a high-capacity positive electrode material for sodium-ion batteries. Nat Commun 5:5280. https://doi.org/10.1038/ncomms6280
Li WJ, Chou SL, Wang JZ, Kang XM, Wang JL, Liu Y, Gu QF, Liu HK, Dou SX (2015) Facile method to synthesize Na-enriched Na1+xFeFe(CN)6 frameworks as cathode with superior electrochemical performance for sodium-ion batteries. Chem Mater 27:1997–2003. https://doi.org/10.1021/cm504091z
Lilga MA, Orth RJ, Sukamto JPH, Rassat SD, Genders JD, Gopal R (2001) Cesium separation using electrically switched ion exchange. Sep Purif Technol 24:451–466. https://doi.org/10.1016/s1383-5866(01)00145-9
Ling C, Chen J, Mizuno F (2013) First-principles study of alkali and alkaline earth ion intercalation in iron hexacyanoferrate: the important role of ionic radius. J Phys Chem C 117:21158–21165. https://doi.org/10.1021/jp4078689
LIU R, SUN B, LIU D, SUN A (1996) Flow injection gas-diffusion amperometric determination of trace amounts of ammonium ions with a cupric hexacyanoferrate. Talanta 43(7):1049–1054. https://doi.org/10.1016/0039-9140(96)01858-9
Liu S, Pan GL, Li GR, Gao XP (2014) Copper hexacyanoferrate nanoparticles as cathode material for aqueous Al-ion batteries. J Mater Chem A 3:959–962. https://doi.org/10.1039/C4TA04644G
Liu Y, Qiao Y, Zhang W, Li Z, Ji X, Miao L, Yuan L, Hu X, Huang Y (2015a) Sodium storage in Na-rich NaxFeFe(CN)6 nanocubes. Nano Energy 12:386–393. https://doi.org/10.1016/j.nanoen.2015.01.012
Liu H, Yonezawa A, Kumagai K, Sano M, Miyake T (2015b) Cs and Sr removal over highly effective adsorbents ETS-1 and ETS-2. J Mater Chem A 3:1562–1568. https://doi.org/10.1039/C4TA06170E
Matsuda T, Takachi M, Moritomo Y (2013) A sodium manganese ferrocyanide thin film for Na-ion batteries. Chem Commun 49:2750–2752. https://doi.org/10.1039/C3CC38839E
Martínez-García R, Knobel M, Balmaseda J, Yee-Madeira H, Reguera E (2007) Mixed valence states in cobalt iron cyanide. J Phys Chem Solids 68(2):290–298. https://doi.org/10.1016/j.jpcs.2006.11.008
Moritomo Y, Urase S, Shibata T (2016) Enhanced battery performance in manganese hexacyanoferrate by partial substitution. Electrochim Acta 210:963–969. https://doi.org/10.1016/j.electacta.2016.05.205
Mortimer RJ, Rosseinsky DR (1983) Electrochemical polychromicity in iron hexacyanoferrate films, and a new film form of ferric ferricyanide. J Electroanal Chem Interfacial Electrochem 151:133–147. https://doi.org/10.1016/S0022-0728(83)80429-X
Mullaliu A, Aquilanti G, Conti P, Plaisier JR, Fehse M, Stievano L, Giorgetti M (2018a) Copper electroactivity in Prussian blue based cathode disclosed by operando XAS. J Phys Chem C 122:15868–15877. https://doi.org/10.1021/acs.jpcc.8b03429
Mullaliu A, Conti P, Aquilanti G, Plaisier JR, Stievano L, Giorgetti M (2018b) Operando XAFS and XRD study of a Prussian blue analogue cathode material: iron hexacyanocobaltate. Condens Matter 3:36. https://doi.org/10.3390/condmat3040036
Mullaliu A, Aquilanti G, Stievano L, Conti P, Plaisier JR, Cristol S, Giorgetti M (2019) Beyond the oxygen redox strategy in designing cathode material for batteries: dynamics of a Prussian blue-like cathode revealed by operando X-ray diffraction and X-ray absorption fine structure and by a theoretical approach. J Phys Chem C 123:8588–8598. https://doi.org/10.1021/acs.jpcc.8b12116
Neff VD (1978) Electrochemical oxidation and reduction of thin films of Prussian blue. J Electrochem Soc 125:886–887. https://doi.org/10.1149/1.2131575
Parajuli D, Takahashi A, Noguchi H, Kitajima A, Tanaka H, Takasaki M, Yoshino K, Kawamoto T (2016) Comparative study of the factors associated with the application of metal hexacyanoferrates for environmental Cs decontamination. Chem Eng J 283:1322–1328. https://doi.org/10.1016/j.cej.2015.08.076
Park Y, Lee YC, Shin WK, Choi SJ (2010) Removal of cobalt, strontium and cesium from radioactive laundry wastewater by ammonium molybdophosphate–polyacrylonitrile (AMP–PAN). Chem Eng J 162:685–695. https://doi.org/10.1016/j.cej.2010.06.026
Qian J, Wu C, Cao Y, Ma Z, Huang Y, Ai X, Yang H (2018) Prussian blue cathode materials for sodium-ion batteries and other ion batteries. Adv Energy Mater 8:1702619. https://doi.org/10.1002/aenm.201702619
Ricci F, Palleschi G (2005) Sensor and biosensor preparation, optimisation and applications of Prussian blue modified electrodes. Biosens Bioelectron 21:389–407. https://doi.org/10.1016/j.bios.2004.12.001
Robin MB (1962) The color and electronic configurations of Prussian blue. Inorg Chem 1:337–342. https://doi.org/10.1021/ic50002a028
Rodríguez-Hernández J, Reguera E, Lima E, Balmaseda J, Martínez-García R, Yee-Madeira H (2007) An atypical coordination in hexacyanometallates: structure and properties of hexagonal zinc phases. J Phys Chem Solids 68:1630–1642. https://doi.org/10.1016/j.jpcs.2007.03.054
Sangvanich T, Sukwarotwat V, Wiacek RJ, Grudzien RM, Fryxell GE, Addleman RS, Timchalk C, Yantasee W (2010) Selective capture of cesium and thallium from natural waters and simulated wastes with copper ferrocyanide functionalized mesoporous silica. J Hazard Mater 182:225–231. https://doi.org/10.1016/j.jhazmat.2010.06.019
Sato O, Iyoda T, Fujishima A, Hashimoto K (1996) Photoinduced magnetization of a cobalt-iron cyanide. Science 272:704–705. https://doi.org/10.1126/science.272.5262.704
Shankaran RD, Narayanan SS (1999) Characterization and application of an electrode modified by mechanically immobilized copper hexacyanoferrate. Fresenius J Anal Chem 364:686–689. https://doi.org/10.1007/s002160051414
Shi C, Fernandez-Jimenez A (2006) Stabilization/solidification of hazardous and radioactive wastes with alkali-activated cements. J Hazard Mater 137:1656–1663. https://doi.org/10.1016/j.jhazmat.2006.05.008
Shiga T, Kondo H, Kato Y, Inoue M (2015) Insertion of calcium ion into Prussian blue analogue in nonaqueous solutions and its application to a rechargeable battery with dual carriers. J Phys Chem C 119:27946–27953. https://doi.org/10.1021/acs.jpcc.5b10245
Song J, Wang L, Lu Y, Liu J, Guo B, Xiao P, Lee J-J, Yang X-Q, Henkelman G, Goodenough JB (2015) Removal of interstitial H2O in hexacyanometallates for a superior cathode of a sodium-ion battery. J Am Chem Soc 137:2658–2664. https://doi.org/10.1021/ja512383b
Tani Y, Eun H, Umezawa Y (1998) A cation selective electrode based on copper(II) and nickel(II) hexacyanoferrates: dual response mechanisms, selective uptake or adsorption of analyte cations. Electrochim Acta 43:3431–3441. https://doi.org/10.1016/S0013-4686(98)00089-9
Thomsen KN, Baldwin RP (1989) Amperometric detection of nonelectroactive cations in flow systems at a cupric hexacyanoferrate electrode. Anal Chem 61:2594–2598. https://doi.org/10.1021/ac00198a002
Thomsen KN, Baldwin RP (1990) Evaluation of electrodes coated with metal hexacyanoferrate as amperometric sensors for nonelectroactive cations in flow systems. Electroanalysis 2:263–271. https://doi.org/10.1002/elan.1140020402
Tokoro H, Ohkoshi SI (2011) Novel magnetic functionalities of Prussian blue analogs. Dalton Trans 40:6825–6833. https://doi.org/10.1039/C0DT01829E
Ventura M, Mullaiu A, Ciurduc DE, Zappoli S, Giuli G, Tonti D, Enciso E, Giorgetti M (2018) Thin layer films of copper hexacyanoferrate: structure identification and analytical applications. J Electroanal Chem 827:10–20. https://doi.org/10.1016/j.jelechem.2018.08.044
Vincent T, Vincent C, Guibal E (2015) Immobilization of metal hexacyanoferrate ion-exchangers for the synthesis of metal ion Sorbents-A mini-review. Molecules 20:20582–20613. https://doi.org/10.3390/molecules201119718
Wang L, Song J, Qiao R, Wray LA, Hossain MA, Chuang YD, Yang W, Lu Y, Evans D, Lee JJ, Vail S, Zhao X, Nishijima M, Kakimoto S, Goodenough JB (2015) Rhombohedral Prussian white as cathode for rechargeable sodium-ion batteries. J Am Chem Soc 137:2548–2554. https://doi.org/10.1021/ja510347s
Ware M (2008) Prussian blue: artists’ pigment and chemists’ sponge. J Chem Educ 85:612–620. https://doi.org/10.1021/ed085p612
Wessells CD, Hugings RA, Cui Y (2011) Copper hexacyanoferrate battery electrodes with long cycle life and high power. Nat Commun 2:550. https://doi.org/10.1038/ncomms1563
Wessells CD, Peddada SV, McDowell MT, Huggins RA, Cui Y (2012) The effect of insertion species on nanostructured open framework hexacyanoferrate battery electrodes. J Electrochem Soc 159:A98. https://doi.org/10.1149/2.060202jes
Wills AS (2005) Magnetism. Annu Rep Prog Chem Sect A Inorg Chem 101:472–488. https://doi.org/10.1039/B408369P
Wu X, Deng W, Qian J, Cao Y, Ai X, Yang H (2013) Single-crystal FeFe(CN)6 nanoparticles: a high capacity and high rate cathode for Na-ion batteries. J Mater Chem 1:10130. https://doi.org/10.1039/c3ta12036h
Yang HM, Hwang KS, Park CW, Lee KW (2017) Sodium-copper hexacyanoferrate-functionalized magnetic nanoclusters for the highly efficient magnetic removal of radioactive caesium from seawater. Water Res 125:81–90. https://doi.org/10.1016/j.watres.2017.08.037
Yasunari TY, Stohl A, Hayano RS, Burkhart JF, Eckhardt S, Yasunari T (2011) Cesium-137 deposition and contamination of Japanese soils due to the Fukushima nuclear accident. Proc Natl Acad Sci U S A 108:19530–19534. https://doi.org/10.1073/pnas.1112058108
You Y, Wu XL, Yin YX, Guo XG (2013) A zero-strain insertion cathode material of nickel ferricyanide for sodium-ion batteries. J Mater Chem A 1:14061–14065. https://doi.org/10.1039/C3TA13223D
You Y, Wu XL, Yin YX, Guo YG (2014) High-quality Prussian blue crystals as superior cathode materials for room-temperature sodium-ion batteries. Energy Environ Sci 7:1643–1647. https://doi.org/10.1039/C3EE44004D
Yue Y, Binder AJ, Guo B, Zhang Z, Qiao ZA, Tian C, Dai S (2014) Mesoporous Prussian blue analogues: template-free synthesis and sodium-ion battery applications. Angew Chem 53:3134–3137. https://doi.org/10.1002/anie.201310679
Zadronecki M, Linek IA, Stroka J, Wrona PK, Galus Z (2001) High affinity of thallium ions to copper hexacyanoferrate films. J Electrochem Soc 148:E348. https://doi.org/10.1149/1.1381074
Zamponi S, Berrettoni M, Kulesza PJ, Miecznikowski K, Malik MA, Makowski O, Marassi R (2003) Influence of experimental conditions on electrochemical behavior of Prussian blue type nickel hexacyanoferrate film. Electrochim Acta 48:4261–4269. https://doi.org/10.1016/j.electacta.2003.08.001
Zen JM, Chen PY, Kumar AS (2003) Flow injection analysis of an ultratrace amount of arsenite using a prussian blue-modified screen-printed electrode. Anal Chem 75:6017–6022. https://doi.org/10.1021/ac0301649
Zheng Y, Qiao J, Yuan J, Shen J, Wang A-j, Niu L (2017) Electrochemical removal of radioactive cesium from nuclear waste using the dendritic copper Hexacyanoferrate/carbon nanotube hybrids. Electrochim Acta 257:172–180. https://doi.org/10.1016/j.electacta.2017.09.179
Zhiqiang G, Xingyao Z, Guangqing W, Peibiao L, Zaofan Z (1991) Potassium ion-selective electrode based on a cobalt(II)-hexacyanoferrate film-modified electrode. Anal Chim Acta 244:39–48. https://doi.org/10.1016/S0003-2670(00)82476-9
Zhou D-M, Ju H-X, Chen H-Y (1996) Catalytic oxidation of dopamine at a microdisk platinum electrode modified by electrodeposition of nickel hexacyanoferrate and Nafion®. J Electroanal Chem 408:219–223. https://doi.org/10.1016/0022-0728(95)04522-8
Zong Y, Zhang Y, Lin X, Ye D, Qiao D, Zeng S (2017) Facile synthesis of potassium copper ferrocyanide composite particles for selective cesium removal from wastewater in the batch and continuous processes. RSC Adv 7:31352–31364. https://doi.org/10.1039/c7ra03111d
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Berrettoni, M., Mullaliu, A., Giorgetti, M. (2021). Metal Hexacyanoferrate Absorbents for Heavy Metal Removal. In: Inamuddin, Ahamed, M., Lichtfouse, E., Asiri, A. (eds) Green Adsorbents to Remove Metals, Dyes and Boron from Polluted Water. Environmental Chemistry for a Sustainable World, vol 49. Springer, Cham. https://doi.org/10.1007/978-3-030-47400-3_7
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