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Syntheses, structures, and magnetic properties of new rare earth coordination polymers constructed by 1,3,5-benzenetriacetic acid

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Abstract

Three new coordination polymers with formula [Gd(bta)(H2O)·1.39H2O] n (1), [Dy(bta)(H2O)·1.35H2O] n (2) and [Y(bta)(H2O)2·0.5H2O] n (3) were synthesized by using corresponding rare earth nitrates and 1,3,5-benzenetriacetic acid (H3bta) under hydrothermal/solvothermal reaction conditions, and characterized by single-crystal X-ray diffraction. In these complexes, the carboxylate groups of bta3− adopt different coordination modes, namely one carboxylate group adopts μ2-η1:η1-bridging and each of the other two carboxylate groups adopts μ2-η2:η1-bridging coordination modes in 1 and 2, and one carboxylate group adopts a μ2-η2:η1-bridging coordination mode and each of the other two carboxylate groups adopts a μ2-η1:η1-bridging mode for the major component and one carboxylate group adopts a μ2-η2:η1-bridging coordination mode, one has a μ2-η1:η1-bridging mode and the third has a monodentate mode for the minor component in 3. The magnetic properties of the complexes 1 and 2 were investigated in the temperature range of 1.8–300 K.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (Grant No. 20231020) and the National Science Fund for Distinguished Young Scholars (Grant No. 20425101).

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Authors and Affiliations

  1. Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, Jiangsu, P. R. China

    Zheng-Hua Zhang, Guang-Xiang Liu & Wei-Yin Sun

  2. Department of Macromolecular Science, Graduate School of Science, Osaka University, Toyonaka, Osaka, 560-0043, Japan

    Taka-aki Okamura & Norikazu Ueyama

Authors
  1. Zheng-Hua Zhang
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  2. Guang-Xiang Liu
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  3. Taka-aki Okamura
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  4. Wei-Yin Sun
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  5. Norikazu Ueyama
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Correspondence to Wei-Yin Sun.

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Zhang, ZH., Liu, GX., Okamura, Ta. et al. Syntheses, structures, and magnetic properties of new rare earth coordination polymers constructed by 1,3,5-benzenetriacetic acid. Struct Chem 17, 3–11 (2006). https://doi.org/10.1007/s11224-006-9014-4

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  • DOI: https://doi.org/10.1007/s11224-006-9014-4

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