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Polyphenylcyclopentadienyl complexes of rare earth elements

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Abstract

Reaction of LnCl3(thf) x (Ln = Y, La, Yb, Lu) with NaCpPhn (CpPhn = 1,3-Ph2C5H3, 1,2,4-Ph3C5H2, Ph4C5H) leads to formation of monocyclopentadienyl dichloride complexes Yb(Ph2C5H3)Cl2(thf)3 (1), Ln(Ph3C5H2)Cl2(thf)3 (Ln = Y (2), Lu (3)), La(Ph4C5H)Cl2(thf)3 (4). Molecular structures of 1, 2 and the polynuclear complex [(Ph3C5H2)3Lu4(Cl)7(O)(thf)3] (5), which is a partial hydrolysis product of 3, have been established by the X-ray method.

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Authors and Affiliations

  1. L.Ya. Karpov Institute of Physical Chemistry, 6 buld., 3-1/12, per. Obukha, 105064, Moscow, Russian Federation

    D. M. Roitershtein, M. E. Minyaev & A. A. Mikhaylyuk

  2. N. D. Zelinsky Institute of Organic Chemistry of Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    D. M. Roitershtein & P. A. Belyakov

  3. A. N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    M. E. Minyaev, K. A. Lyssenko & I. V. Glukhov

  4. A. V. Topchiev Institute of Petrochemical Synthesis of Russian Academy of Sciences, 21 Leninsky prosp., 119991, Moscow, Russian Federation

    A. A. Mikhaylyuk

Authors
  1. D. M. Roitershtein
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  2. M. E. Minyaev
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  3. A. A. Mikhaylyuk
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  4. K. A. Lyssenko
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  5. I. V. Glukhov
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  6. P. A. Belyakov
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Correspondence to D. M. Roitershtein.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1710–1716, September, 2012.

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Roitershtein, D.M., Minyaev, M.E., Mikhaylyuk, A.A. et al. Polyphenylcyclopentadienyl complexes of rare earth elements. Russ Chem Bull 61, 1726–1732 (2012). https://doi.org/10.1007/s11172-012-0238-8

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  • DOI: https://doi.org/10.1007/s11172-012-0238-8

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