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Nonsymmetrical iron bis(carborane) complexes (η-1-ButNH-1,7,9-C3B8H10)Fe(η-9-L-7,8-C2B9H10) (L = SMe2, NMe3)

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Abstract

Visible light irradiation of the benzene complex [(η-1-ButNH-1,7,9-C3B8H10)Fe(η-C6H6)]+ in the presence of the charge-compensated carborane anions [9-L-7,8-C2B9H10]− (L = SMe2, NMe3) affords ferracarboranes (η-1-ButNH-1,7,9-C3B8H10)Fe(η-9-L-7,8-C2B9H10). Their structures were established by X-ray diffraction analysis.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    M. M. Vinogradov, D. A. Loginov, Z. A. Starikova, P. V. Petrovskii & A. R. Kudinov

  2. Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic (Research Centre for New Inorganic Compounds and Advanced Materials, University of Pardubice), 250 68, Řež, Czech Republic

    J. Holub

Authors
  1. M. M. Vinogradov
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  2. D. A. Loginov
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  3. Z. A. Starikova
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  4. P. V. Petrovskii
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  5. J. Holub
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  6. A. R. Kudinov
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Correspondence to A. R. Kudinov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2089–2096, November, 2010.

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Vinogradov, M.M., Loginov, D.A., Starikova, Z.A. et al. Nonsymmetrical iron bis(carborane) complexes (η-1-ButNH-1,7,9-C3B8H10)Fe(η-9-L-7,8-C2B9H10) (L = SMe2, NMe3). Russ Chem Bull 59, 2143–2146 (2010). https://doi.org/10.1007/s11172-010-0370-2

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  • DOI: https://doi.org/10.1007/s11172-010-0370-2

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