Skip to main content
SpringerLink
Log in

Nitric acid adduct formation during crystallization of barium and strontium nitrates and their co-precipitation from nitric acid media

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

The molar solubilities of Ba, Sr and Pb nitrates in nitric acid as a function of total nitrate concentration is presented and described by the mass action law, indicating on formation of the adducts with nitric acid. Precipitates of Ba(NO3)2 and Sr(NO3)2 crystallized from nitric acid were studied by ISP OES and IR spectroscopy. The data obtained confirmed formation of metastable adducts with nitric acid. IR and X-ray diffraction studies of the mixed salt systems indicated conversion of the mixed salts into (Ba,Sr)(NO3)2 solid solution of discrete structure in range of total nitrate ion concentration ~6 mol/L.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. Koyama T, Washiya T, Nakabayashi H, Funasaka H (2009) Proceedings of GLOBAL 2009, paper 9100

  2. Torihara H, Tamura T, Watanabe K, Itagaki T (2011) Proceedings of GLOBAL 2011, paper 448646

  3. Mishina NE, Akhmatov AA, Zilberman BYa et al (2010) Radiochemistry 52(5):523–529

    Article  CAS  Google Scholar 

  4. Mishina NE, Zilberman BYa, Lumpov AA et al (2014) Radiochemistry 56(3):252–261

    Article  CAS  Google Scholar 

  5. Leithe W (1964) Z Anal Chem 202(1):102

    Article  Google Scholar 

  6. Procenko P.I., Razumovskaya O.N., Brykova N.A. (1971) Spravochnik po rastvorimosti v nitritnykh i nitratnykh sistemakh (Handbook on solubility in nitrite and nitrate salt systems), L. Khimiya

  7. Devi SS, Aruna BL, Reddy SN, Chary AS (2012) Pelagia research library. Der Chemica Sinica 3(6):1337–1342

    Google Scholar 

  8. Bon AM, Benoit C, Bernard O (1976) Phys Stat Sol b 78(1):67–78

    Article  CAS  Google Scholar 

  9. Markowitz MM, Ricci JE, Winternitz PF (1955) J Am Chem Soc 77(13):3482–3484

    Article  CAS  Google Scholar 

  10. Zilberman BYa, Makarychev-Mikhailov MN, Ryabkov DV et al (2011) Theor Found Chem Eng 45(4):530–536

    Article  CAS  Google Scholar 

  11. Ryabkov DV, Andreeva EV, Mishina NE et al (2011) Chem Technol (Rus) 9:556–563

    Google Scholar 

  12. Gavrilov PM, Kudryavtsev EG, Revenko YuA et al. (2011) Proceedings of GLOBAL 2011, paper 390993

Download references

Author information

Authors and Affiliations

  1. Khlopin Radium Institute, 2nd Murinsky Av., 28, 194021, Saint-Petersburg, Russia

    N. E. Mishina, B. Ya. Zilberman, A. A. Lumpov, T. I. Koltsova, E. A. Puzikov & D. V. Ryabkov

Authors
  1. N. E. Mishina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. B. Ya. Zilberman
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. A. Lumpov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. T. I. Koltsova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. E. A. Puzikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. D. V. Ryabkov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to N. E. Mishina.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Mishina, N.E., Zilberman, B.Y., Lumpov, A.A. et al. Nitric acid adduct formation during crystallization of barium and strontium nitrates and their co-precipitation from nitric acid media. J Radioanal Nucl Chem 304, 387–393 (2015). https://doi.org/10.1007/s10967-014-3691-z

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10967-014-3691-z

Keywords

Search

Navigation