Skip to main content
SpringerLink
Log in

Hydrothermal Synthesis and Crystal Structure of a Novel 2-Fold Interpenetrated Framework Based on Tetranuclear Homometallic Cluster

  • Published:
Journal of Inorganic and Organometallic Polymers and Materials Aims and scope Submit manuscript

Abstract

A novel 2-fold parallel interpenetrated polymer, Zn2(OH)(pheno)(p-BDC)1.5 · H2O (1) (pheno = phenanthrene-9,10-dione; p-BDC = 1,4-benzenedicarboxylate) was prepared by hydrothermal synthesis and characterized by IR spectra, elemental analysis and single crystal X-ray diffraction. Complex 1 crystallizes in the orthorhombic space group Pbca and affords a three-dimensional (3D) six-connected α-Po network.

Graphical Abstract

Hydrothermal Synthesis and Crystal Structure of a Novel 2-Fold Interpenetrated Framework Based on Tetranuclear Homometallic Cluster

Rong-Yi Huang, Xue-Jun Kong and Guang-Xiang Liu

A intriguing feature of complex 1 is a pair of identical 3D single nets is interlocked with each other, thus directly leading to the formation of a 2-fold interpenetrated 3D → 3D architecture.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Scheme 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. (a) P.J. Hagrman, D. Hagrman, J. Zubieta, Angew. Chem. Int. Ed. 38, 2638 (1998); (b) S. Leininger, B. Olenyuk, P.J. Stang, Chem. Rev. 100, 853 (2000); (c) A. Erxleben, Coord. Chem. Rev. 246, 203 (2003); (d) K. Biradha, Y. Hongo, M. Fujita, Angew. Chem. Int. Ed. 39, 3843 (2000); (e) P.D. Harey, H.B. Gray, J. Am. Chem. Soc. 110, 2145 (1988); (f) D. Cave, J.M. Gascon, A.D. Bond, S.J. Teat, P.T. Wood, Chem. Commun. 1050 (2002); (g) F.A. Almeida Paz, J. Klinowski, Inorg. Chem. 43, 3882 (2004); (h) K. Biradha, Y. Hongo, M. Fujita, Angew. Chem. Int. Ed. 39, 3843 (2000); (i) M. Eddaoudi, J. Kim, N. Rosi, D. Vodak, J. Wachter, M. O’Keegge, O.M. Yaghi, Science 295, 469 (2002); (j) S.Q. Zhang, R.J. Tao, Q.L. Wang, N.H. Hu, Y.X. Cheng, H.L. Niu, W. Lin, J. Am. Chem. Soc. 123, 10395 (2001); (k) L. Carlucci, G. Ciani, D.M. Proserpio, Cryst. Growth Design 5, 37 (2005)

  2. (a) M. Eddaoudi, D.B. Moler, H. Li, B. Chen, T.M. Reineke, M. O’Keeffe, O.M. Yaghi, Acc. Chem. Res. 34, 319 (2001); (b) P.J. Hagrman, D. Hagrman, J. Zubieta, Angew. Chem. Int. Ed. 38, 2638 (1999); (c) O.R. Evans, W. Lin, Acc. Chem. Res. 35, 511 (2002); (d) S. Kitagawa, R. Kitaura, S. Noro, Angew. Chem. Int. Ed. 43, 2334 (2004); (e) S.L. James, Chem. Soc. Rev. 32, 276 (2003); (f) L. Pan, H. Liu, X. Lei, X. Huang, D.H. Olson, N. J. Turro, J. Li, Angew. Chem. Int. Ed. 42, 542 (2003)

  3. (a) G. Ferey, C. Mellot-Draznieks, C. Serre, F. Millange, Acc. Chem. Res. 38, 217 (2005); (b) M. Eddaoudi, J. Kim, J.B. Wachter, H.K. Chae, M. O’Keeffe, O.M. Yaghi, J. Am. Chem. Soc. 123, 4368 (2001); (c) M. Eddaoudi, J. Kim, M. O’Keeffe, O.M. Yaghi, J. Am. Chem. Soc. 124, 376 (2002); (d) A. Thirumurugan, S. Natarajan, Cryst. Growth Design 6, 983 (2006); (e) R. Murugavel, M.G. Walawalkar, M. Dan, H.W. Roesky, C.N.R. Rao, Acc. Chem. Res. 37, 763 (2004)

  4. (a) J. Kim, B. Chen, T.M. Reineke, H. Li, M. Eddaoudi, D. B. Moler, M. O’Keeffe, O.M. Yaghi, J. Am. Chem. Soc. 123, 8239 (2001); (b) J.J. Lu, A. Mondal, B. Moulton, M. Zaworotko, Angew. Chem. Int. Ed. 40, 2113 (2001)

  5. (a) Q.R. Fang, X. Shi, G. Wu, G. Tain, G.S. Zhu, R.W. Wang, S.L. Qiu, J. Solid State Chem. 176, 1 (2003); (b) H. Li, C.E. Davis, T.L. Groy, D.G. Kelley, O.M. Yaghi, J. Am. Chem. Soc. 120, 2186 (1998)

  6. (a) M. Eddaoudi, J. Kim, N. Rosi, D. Vodak, J. Wachter, M. O’Keeffe, O.M. Yaghi, Science 295, 469 (2002); (b) B. Kesanli, Y. Cui, M.R. Smith, E.W. Bittner, B.C. Bockrath, W.B. Lin, Angew. Chem. Int. Ed. 44, 72 (2005)

    Google Scholar 

  7. Q.R. Fang, G.S. Zhu, Z. Jin, M. Xue, X. Wei, D.J. Wang, S.L. Qiu, Cryst. Growth Design 7, 1035 (2007)

    Article  CAS  Google Scholar 

  8. C. Lei, J.G. Mao, Y.Q. Sun, H.Y. Zeng, A. Clearfield, Inorg. Chem. 42, 6157 (2003)

    Article  CAS  Google Scholar 

  9. J.R. Li, Y. Tao, Q. Yu, X.H. Bu, Chem. Commun. 1527 (2007)

  10. S.Y. Yang, L.S. Long, R.B. Huang, L.S. Zheng, Chem. Commun. 472 (2002)

  11. T.M. Reineke, M. Eddaoudi, D.M. Moler, M. O’Keeffe O.M. Yaghi, J. Am. Chem. Soc. 122, 4843 (2002)

    Article  Google Scholar 

  12. D.M. Proserpio, R. Hoffman, P. Preuss, J. Am. Chem. Soc. 116, 9634 (1994)

    Article  CAS  Google Scholar 

  13. (a) O. Ermer, Adv. Mater. 3, 608 (1991); (b) J. S. Miller, Adv. Mater. 13, 525 (2001)

  14. SAINT version 6.02a, Software Reference Manual (Bruker AXS Inc., Madison, W1, 2002)

  15. G.M. Sheldrick, SADABS: Program for Empirical Absorption Correction of Area Detector Data (University of Göttingen, 1996)

  16. G. M. Sheldrick, SHELXS-97: Program for Crystal Structure Solution (University of Göttingen, 1997)

  17. G. M. Sheldrick, SHELXL-97: Program for Crystal Structure Refinement (University of Göttingen, 1997)

  18. V.A. Blatov, L. Carlucci, G. Ciani, D.M. Proserpio, Cryst. Eng. Comm. 6, 377 (2004)

    CAS  Google Scholar 

  19. (a) B.F. Hoskins, R. Robson, N.V.Y. Scarlett, J. Chem. Soc. Chem. Commun. 2025 (1994); (b) E. Siebel, R.D. Fischer, Chem. Eur. J. 3, 1987 (1997); (c) B.F. Abrahams, B.F. Hoskins, R. Robson, D.A. Slizys, Cryst. Eng. Comm. 4, 478 (1997); (d) M.J. Plater, M.R. S.J. Foreman, J.M.S. Skakle, Cryst. Eng. 4, 293 (2001); (e) X.L. Wang, C. Qin, E.B. Wang, Z.M. Su, Chem. Eur. J. 12, 2680 (2006)

  20. B. Kesanli, Y. Cui, R. Smith, E. Bittner, B.C. Bockrath, W. Lin, Angew. Chem. Int. Ed. 117, 74 (2005)

    Article  Google Scholar 

  21. (a) H.L. Gao, L. Yi, B. Ding, H.S. Wang, P. Cheng, D.Z. Liao, S.P. Yan, Inorg. Chem. 45, 481 (2006); (b) Y.H. Wen, J. Zhang, X.Q. Wang, Y.L. Feng, J.K. Cheng, Z.J. Li, Y.G. Yao, New J. Chem. 29, 995 (2005); (c) H.L. Sun, B.Q. Ma, S. Gao, S.R. Batten, Cryst. Growth Design 5, 1331 (2005); (d) J. Yang, J.F. Ma, Y.Y. Liu, S.L. Li, G.L. Zheng, Eur. J. Inorg. Chem. 2174 (2005)

Download references

Acknowledgments

This work was supported by the National Natural Science Foundation of China (20731004) and the Natural Science Foundation of the Education Committee of Anhui Province, China (KJ2008B004).

Author information

Authors and Affiliations

  1. Anhui Key Laboratory of Functional Coordination Compounds, College of Chemistry and Chemical Engineering, Anqing Normal University, Anqing, 246003, P.R. China

    Rong-Yi Huang, Xue-Jun Kong & Guang-Xiang Liu

Authors
  1. Rong-Yi Huang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Xue-Jun Kong
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Guang-Xiang Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Guang-Xiang Liu.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Huang, RY., Kong, XJ. & Liu, GX. Hydrothermal Synthesis and Crystal Structure of a Novel 2-Fold Interpenetrated Framework Based on Tetranuclear Homometallic Cluster. J Inorg Organomet Polym 18, 304–308 (2008). https://doi.org/10.1007/s10904-008-9199-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10904-008-9199-7

Keywords

Search

Navigation