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Catalytic Properties of Single-Phase Intermetallic Compounds

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Abstract

Unsupported and silica-supported intermetallic compounds were prepared. Some characterizations revealed that they were composed of single-phase compounds having their specific surface. The catalytic activity of TiPt3 was higher than that of Pt for the H2–D2 equilibration and hydrogenation of ethylene. Ni3Sn gave higher selectivity than Ni for the partial hydrogenation of acetylene and the dehydrogenation of cyclohexane into benzene. RuTi/SiO2 and Pd3Bi/SiO2 gave much higher selectivity than their component pure metals in FT synthesis and the oxidative acetoxylation of toluene, respectively.

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Acknowledgements

A part of this work was supported by a Grant-in-Aid (No. 12650777, 14550759 and 17560680) from the Ministry of Education, Science, Sports and Culture, Japan, the Petroleum Energy Center, with the subsidy of the Ministry of Economy, Trade and Industry, Japan, and the Japan Petroleum Institute. We thank Professor Yashima for his continued encouragement and helpful discussions. We also thank Professor Mishima and Professor Takeyama for the preparation of the intermetallic compounds, and Professor Takenaka for the measurement and analysis of XAFS spectra. The X-ray absorption experiment was performed under the approval of the Photon Factory Program Advisory Committee (Proposal No. 2000G075).

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  1. Ayumu Onda

    Present address: Research Laboratory of Hydrothermal Chemistry, Faculty of Science, Kochi University, Akebono-cho 2-5-1, Kochi, 780-8520, Japan

Authors and Affiliations

  1. Department of Chemistry, Tokyo Institute of Technology, 2-12-1-E1-10 Ookayama, Meguro-ku, Tokyo, 152-8550, Japan

    Takayuki Komatsu & Ayumu Onda

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  1. Takayuki Komatsu
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  2. Ayumu Onda
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Correspondence to Takayuki Komatsu.

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Komatsu, T., Onda, A. Catalytic Properties of Single-Phase Intermetallic Compounds. Catal Surv Asia 12, 6–15 (2008). https://doi.org/10.1007/s10563-007-9031-3

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