Abstract
Crude palm oil contains about 1% of minor components including carotenoids, tocopherols, sterols, triterpene alcohols, phospholipids, glycolipids and terpenic and paraffinic hydrocarbons. The nutritionally important components such as carotenes and tocopherols also improve stability of the oil. Although a highly valued product, carotene unfortunately is bleached or destroyed in refining because suitable recovery technology is not available. Thermal degradation of carotene, previously suspected of giving rise to undesirable chemicals, now is known to furnish mainly harmless hydrocarbons, most of which are removed by the deodorization step in refining. Tocopherols, being natural antioxidants, need to be carefully preserved during milling, refining, fractionation and modification of palm oils. The accumulation of tocopherols in the palm fatty acid distillate promises to provide a new source for the recovery of this valuable substance. The role played by phospholipids is frequently misunderstood because they can act in two ways, i.e. as an antioxidant synergist and a surface active agent to disperse impurities in oil. In crude palm oil the phospholipid content is small, because most of it is removed during milling; the phosphorus content is due mainly to inorganic phosphorus. Among the sterols, cholesterol constitutes too small a percentage to be of much concern. Sterols, triterpenoids and terpenoid hydrocarbons are also potentially useful side products should recovery technology become available. Other newly characterized minor and trace components also are discussed.
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References
Jacobsberg, B., Proceedings of First MARDI Workshop on Oil Palm Technology, Kuala Lumpur (1974).
Ames, G.R., W.D. Raymond and J.B. Ward, J. Sci. Food Agric. 11:194 (1960).
Siew, W.L., and K.G. Berger, “Malaysian Palm Kernel Oil, Chemical and Physical Characteristics,” PORIM Technology Series No. 6 (1981), PORIM, Kuala Lumpur, Malaysia.
Loncin, M., Oleagineaeux 30:77 (1975).
Buxton, L.D., U.S. Patent 2,318,747 (1943); Chem. Abst. 37:6095.
Jorand, J., Oleagineaux 10:99, 192, 269 (1955).
Ong, S.H., British Patent 1499333 (1978).
Lin, K.L., T.B. Ng, P.Y. Tan and S.F. Tan, J. Singapore Natl. Acad. Sci. 5:54 (1976); Chem. Abst. 86:104609x (1977).
Yoshioka, H., Y. Ohta and H. Watanabe, Chem. Abst. 87:172362g (1977).
Boldingh, J., Dutch Patent 74,349 (1954); Chem. Abst. 48:14132f (1954).
Chan, K.C., S.H. Goh, W.I. Tan, T.S. Tang and H.T. Toh, British Patent 1,545,238 (1976).
Ong, S.H., British Patent 1562794 (1975).
Davis, J.B., J.M. Robinson, N.K. Silva and A. Barranco, J. Fd. Technol. 14:253 (1979).
Rost, H.E., Chemy. Ind. 612 (1976).
Wong, K.C., in “Int. Dev. Palm Oil, Proc. Malays, Int. Symp. Palm Oil Process Mark. 1976,” D.A. Earp and W. Newall, eds., Kuala Lumpur, Malaysia (1977) p. 187.
Dirinck, P., L. Schreyen, L. DeSchoenmacker, F. Wychuyse and N. Schamp, J. Food Science 42:645 (1977).
Weir, G.S.D., Ph.D. Thesis, Reading (1975).
Tan, B.K., and C.H. Oh, “Malaysian Palm Oil Chemical and Physical Characteristics,” PORIM Technology No. 3 (1981), PORIM, Kuala Lumpur, Malaysia.
Gapor, A., and K.G. Berger, in “Palm Oil in the Eighties” (1982) PORIM, Kuala Lumpur, Malaysia.
Burton, G., and K.U. Ingold, J. Amer. Chem. Soc. 103:6472 (1981).
Thompson, J.N., and G. Hatina, J. Liquid Chromatogr. 2:327 (1979).
Mordret, F., and A.M. Laurent, Rev. Fre. des Corps. Gras. 25:245 (1978).
Siew, W.L. (PORIM, Kuala Lumpur, Malaysia), Private Communication, 1982.
Rossell, J.B., B. King and M.J. Downes, JAOCS 60:333 (1983).
Itoh, T., T. Tamura and T. Matsumoto, JAOCS 50:122 (1973).
Itoh, T., T. Tamura and T. Matsumoto, JAOCS 50:300 (1973).
Huyghebaert, A., and A. Hendrickx, Actes Congr. Mond.-Soc. Int. Etude Corps Gras, 13th 1976 Sect. B 1-9; Chem. Abstracts 87:199246j (1977).
Kochhar, S.P., Prog. Lipid Res. 22:161 (1983).
Welzel, P., K. Hobert, A. Ponty and T. Mikova, Tetrahedron Lett. 24:3199 (1983).
Prestwich, G.D., and S. Phirwa, Ibid. 24:2461 (1983).
Goh, S.H., and P.T. Gee, PRIOCHEM Asia Conference, Kuala Lumpur, April 1984, Malaysian Institute of Chemistry, Kuala Lumpur, Malaysia.
Gee, P.T., Ph.D. Thesis, University of Malaysia, Kuala Lumpur, Malaysia, 1984.
Tan, Barrie, University of Massachusetts, Amherst, USA, 1984.
Khor, H.T., S.H. Goh and W.I. Tan, Oil Palm News 24:12 (1980).
Goh, S.H., H.T. Khor and P.T. Gee, JAOCS 59:296 (1982).
Jacobsberg, B., “Quality of Palm Oil,” PORIM Occasional Paper, PORIM, Kuala Lumpur, Malaysia (1983).
Maclellan, M., JAOCS 60:368 (1983).
Goh, S.H., S.L. Tong and P.T. Gee, JAOCS, in press.
Kwon, T.-W., H.E. Snyder and H.G. Brown, in AOCS Conference, Dallas, April 1984.
Yeoh, G.H., in Int. Dev. Palm Oil, Proc. Malays. Int. Sym. Palm Oil Process. Mark., D.A. Earp and W. Newall, eds., Inc. Soc. Plant. Kuala Lumpur, Malaysia, p 27 (1976).
Swoboda, P., British Patent 8317543 (1983).
Segers, J.C., JAOCS 58:926 (1983).
Audley, B.G. (PORIM, Brickendonbury, UK), Private Communication, 1984.
Fraser, M.S., and G. Frankl, JAOCS 58:926 (1981).
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Goh, S.H., Choo, Y.M. & Ong, S.H. Minor constituents of palm oil. J Am Oil Chem Soc 62, 237–240 (1985). https://doi.org/10.1007/BF02541384
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DOI: https://doi.org/10.1007/BF02541384