Skip to main content
SpringerLink
Log in

Preparation and reactivity of metal-containing monomers. 8. Polymerization of transition metal acrylates

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The valence state and coordination of transition metals do not change during polymerization of their acrylates.

  2. 2.

    On the example of polymerization of cobalt acrylate, it was shown that it takes place according to the traditional radical mechanism; the general polymerization equation isW n=K[M]∼1 [I]∼0.5.

  3. 3.

    The synthesized metal-containing polymers with Mη of 18,800–33,600 exhibit elevated (up to 400°C) thermal stability and a predominantly syndiotactic structure.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. M. V. Klyuev, L. V. Tereshko, G. I. Dzhardimalieva, and A. D. Pomogailo, Izv. Akad. Nauk SSSR, Ser. Khim., 2531 (1986).

  2. A. Gronowski and Z. Wojtczak, Abstrs. IUPAC. Macro ′83, Sec.1, Bucharest (1983), p. 39.

  3. R. A. Sheldon and J. K. Kochi, Metal-Catalyzed Oxidations of Organic Compounds, Academic Press, New York (1981), p. 39.

    Google Scholar 

  4. Kh. S. Bogdasar'yan, Theory of Radical Polymerization [in Russian], Nauka, Moscow (1966).

    Google Scholar 

  5. G. I. Dzhardimalieva, A. O. Tonoyan, A. D. Pomogailo, and S. P. Davtyan, Izv. Akad. Nauk SSSR, Ser. Khim., 1744 (1987).

  6. A. B. P. Lever, Inorganic Electronic Spectroscopy, Elsevier, Amsterdam (1968).

    Google Scholar 

  7. G. I. Dzhardimalieva, A. D. Pomogailo, V. I. Ponomarev, et al., Izv. Akad. Nauk SSSR, Ser. Khim., 1525 (1988).

  8. V. A. Kargin, V. A. Kabanov, and V. P. Zubov, Vysokomol. Soedin.,2, 765 (1960).

    Google Scholar 

  9. A. Chapiro, D. Goedfeeld-Freilich, and J. Perichon, Europ. Polim. J.,11, 515 (1975).

    Google Scholar 

  10. P. Monjol and G. Chempetier, Bull. Soc. Chim. France, 1302 (1972).

  11. Encyclopedia of Polymers [in Russian], Vol.1, Sov. Entsiklopediya, Moscow (1972), p. 38.

Download references

Author information

Authors and Affiliations

  1. Chernogolovka Branch, Institute of Chemical Physics, Academy of Sciences of the USSR, USSR

    G. I. Dzhardimalieva, A. D. Pomogailo, S. P. Davtyan & V. I. Ponomarev

Authors
  1. G. I. Dzhardimalieva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. D. Pomogailo
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. P. Davtyan
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. I. Ponomarev
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1531–1536, July, 1988.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Dzhardimalieva, G.I., Pomogailo, A.D., Davtyan, S.P. et al. Preparation and reactivity of metal-containing monomers. 8. Polymerization of transition metal acrylates. Russ Chem Bull 37, 1352–1357 (1988). https://doi.org/10.1007/BF00962738

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00962738

Keywords

Search

Navigation