Abstract
Color plays a vital part in our lives, acting to warn (i.e., red is hot, blue is cold), to direct (i.e., red is stop, green is go), or to express (i.e., red is angry, blue is sad). As a powerful form of communication, color, and in particular a change in color, is irreplaceable. Textiles with the ability to change color provide the opportunity to act as a flexible communicative display. The display can be used to express emotions and opinions or can be used for identification and decoration or safety and camouflage purposes. In this chapter a range of pre-existing color-changing textiles that apply LED, optical fiber, and chromic (thermo-, photo-, halo-) technologies are considered. The possibilities of flexible communicative displays using electrochromic technologies are then explored in detail. The principals of electrochromism are discussed and electrochromic materials and their devices (ECDs) introduced. There is a great potential provided when electrochromism is applied to flexible textiles. A flexible color-changing display, visible in natural and ambient light, offers endless opportunities. A number of challenges for the optimization and commercialization of flexible electrochromic devices (F-ECDs) exist. However, with the persistent improvements, which are being made, the field as a whole will continue to see great success. A colorful future is ahead for flexible electrochromic devices.
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References
Tao X (2001) Smart fibres, fabrics and clothing: fundamentals and applications. Woodhead Publishing, Cambridge
Cochrane C, Meunier L, Kelly FM, Koncar V (2011) Flexible displays for smart clothing: part I—overview. Indian J Fibre Text Res 36:422–428
Flexmedia (08 Jan 2014) http://www.flexmedia.com/tWeb/images/pdf/FlexmediaOverview.pdf
Genz R, Rosella F (08 Jan 2014) http://cutecircuit.com/collections/t-shirt-os/
Genz R, Rosella F (08 Jan 2014) http://cutecircuit.com/collections/the-galaxy-dress/
Koncar V (2005) Optical fiber fabric displays - OFFD. Optics Photonics News 16:40–45
Deflin E, Koncar V, Weill A, Vinchon H (2001) Bright optical fiber fabric. GEMTEX Publication, Hong-Kong
Luminex (08 Jan 2014) http://www.luminex.it/
Mordon S, Cochrane C, Lesage JC, Koncar V (2011) Innovative engineering design of a textile light diffuser for photodynamic therapy. Photodiagnosis Photodyn Ther 8:142–143
Sudhakar P, Gobi N (10 Jan 2014) http://www.fibre2fashion.com/industry-article/technology-industry-article/chameleonic-textiles/chameleonic-textiles1.asp
Van Langenhove L (2007) Smart textiles for medicine and healthcare: materials, systems and applications. Woodhead Publishing, Cambridge
Radiate Athletics (10 Jan 2014) http://www.kickstarter.com/projects/radiate/radiate-athletics-the-future-of-sports-apparel?ref%E2=%E2popular and http://www.radiateathletics.com/
Chung K (10 Jan 2014) www.whodesignedit.net/design/heat-sensitive-paint-ideas-shi-yuan
Bamfield P (2010) Chromic phenomena: the technological applications of colour chemistry. The Royal Society of Chemistry, Cambridge
Winters R (11 Jan 2014) http://www.rainbowwinters.com/
Zhong W (2012) An introduction to healthcare and medical textiles. DEStech Publications, Pensylvania
Goudjil K (1996) Photochromic ultraviolet detector, US 5581090 A
Vikova M, Vik M (2011) Alternative UV sensors based on color-changeable pigments. Advance Chem Engineer Sci 1:224–230
Osti E (2008) Skin ph variations from the acute phase to re-epithelialization in burn patients treated with new materials (burnshield®, semipermeable adhesive film, dermasilk®, and hyalomatrix®). Non-invasive preliminary experimental clinical trial. Ann Burns Fire Disaster 21:73–77
Sun D (12 Jan 2014) http://www.sundahea.com/rain%20palette.html
Somania PR, Radhakrishnan S (2002) Electrochromic materials and devices: present and future. Mater Chem Phys 77:117–133
Mortimer RJ, Dyer AL, Reynolds JR (2006) Electrochromic organic and polymeric materials for display applications. Displays 27:2–18
Rosseinsky DR, Mortimer RJ (2001) Electrochromic systems and the prospects for devices. Adv Mater 13:783–793
Silver J (1989) Chemical chameleons for electronics
Bonsor K (12 Jan 2014) http://home.howstuffworks.com/home-improvement/construction/green/smart-window4.htm
Gordon N http://www.dwfcontract.com/Drapery--Window-Covering-Blog/bid/83137/Being-Green-with-Smart-Glass
Monk PMS, Mortimer RJ, Rosseinsky DR (1995) Electrochromism: fundamentals and applications. VCH, Weinheim
Hagenmuller P, Gool W (1978) Solid electrolytes. General principles, characterization, materials, applications. Academic, New York
Pratt C (2005) Chromism. homepage.ntlworld.com/colin.pratt/Chromism.pdf
Somani PR, Radhakrishnan S (2003) Electrochromic materials and devices: present and future. Mater Chem Phys 77:117–133
Monk P, Mortimer R, Rosseinsky D (2007) Electrochromism: fundamentals and applications. 504
Sapp SA, Sotzing GA, Reynolds JR (1998) High contrast ratio and fast-switching dual polymer electrochromic devices. Chem Mater 10:2101–2108
Scarminio J, Urbano A, Gardes BJ, Gorenstein A (1991) Electrochromism in nickel oxide films obtained by thermal decomposition. J Mater Sci Let 11:562–563
Oh DH, Boxer SG (2002) Electrochromism in the near-infrared absorption spectra of bridged ruthenium mixed-valence complexes. J Am Chem Soc 112:8161–8162
Schoot CJ, Ponjee JJ, van Dam HT, van Doorn RA, Bolwijn PJ (1973) New electrochromic memory display. Appl Phys Lett 23:64–65
Eloi J, Chabanne L, Whittell G, Manners I (2008) Metallopolymers with emerging applications. Mater Today 11:28–36
Patil A, Heeger AJ, Wudl F (1988) Optical properties of conducting polymers. Chem Rev 88:183–200
Kelly FM (2005) Hybrid materials of cellulose and protein with conducting polymers. Victoria University of Wellington, Wellington
Kelly FM, Cochrane C, Koncar V (2013) Evaluation of solid or liquid phase conducting polymers within a flexible textile electrochromic device. J Display Tech 9:626–631
Gaupp CL, Reynolds JR (2003) Multichromic copolymers based on 3,6-bis(2-(3,4-ethylenedioxythiophene))-N-alkyl carbazole derivatives. Macromolecules 36:6305–6315
Kelly FM (2013) Figure: the colour of thiophene electrochromics may be tuned by functionalising the monomer unit before polymerisation
Hanlon M (15 Jan 2014) http://www.gizmag.com/go/4821/
Savastano D http://www.printedelectronicsnow.com/articles/2009/10/nteras-innovations-partnerships-are-leading-to-exc
Mortimer RJ (2002) Electrochromic polymers. Wiley
Schawaller D (2013) Flexible, switchable electrochromic textiles. Macromol Mater Eng. Article first published online: 19 July 2013
Beaupré S, Dumas J, Leclerc M (2006) Toward the development of new textile/plastic electrochromic cells using triphenylamine-based copolymers. Chem Mater 18:4011–4018
Zhang Q, Xin B, Lin L (2013) Preparation and characterisation of electrochromic fabrics based on polyaniline. Adv Mater Res 651:77–82
Kelly FM, Cochrane C, Koncar V (2013) Polyaniline: application as solid state electrochromic in a flexible textile display. Displays 34:1–7
Meunier L, Kelly FM, Cochrane C, Koncar V (2011) Flexible displays for smart clothing : part II – electrochromic displays. Indian J Fibre Text Res 36:429–435
Kelly FM (2012) Photo: ECD containing PProDOT-Me2 in its oxidised and neutral states
Kelly FM (2013) Photos: F-ECD containing PEDOT:PSS in its oxidised and neutral (reduced) states, and showing its flexibility
Ding Y, Invernale MA, Mamangun DMD, Kumar A, Sotzing GA (2011) A simple, low waste and versatile procedure to make polymer electrochromic devices. J Mater Chem
Invernale MA, Ding Y, Sotzing GA (2010) All-organic electrochromic spandex. ACS Appl Mater Interfaces 2:296–300
Sotzing GA, Invernale MA (2012) Flexible electrochromic devices, electrodes therefor, and methods of manufacture US 8107153 B2
Invernale MA, Ding Y, Sotzing GA (2011) The effects of coloured base fabric on electrochromic textile. Color Technol 127:167–172
Nike Inc (2013) Article of footwear with color change portion and method of changing color US 8474146 B2
Sotzing GA, Mather PT (2012) Conjugated polymer fiber, preparation and use thereof US 8178629 B2
Orth M, Berzowska JM (2003) US Patent 200322415
Xu C, Ma C, Taya M (2010) Flexible panel based on electrochromic polymers US 7826124 B2
Chameleon Optics (2008) Adhesive ion-conducting layer for flexible electrochromic devices US 7414771 B2
Chameleon Optics (2002) Flexible Electrochromic Devices US 6456418 B1
Shim GH, Han MG, Foulger SH (2010) Electrochromic inks including conducting polymer colloidal nanocomposites, devices including the electrochromic inks and methods of forming same US 7785496 B1
Chameleon Optics (2009) Metal ferrocyanide-polymer composite layer within a flexible electrochromic device US 7586665 B1
Rauh R (1999) Electrochromic windows: an overview. Electrochim Acta 44:3165–3176
Cho SI, Lee SB (2008) Fast electrochemistry of conductive polymer nanotubes: synthesis, mechanism and application. Acc Chem Res 41:699–707
Cho SI, Xiao R, Kim S-H, Lee SB (2007) Electrochemical synthesis of Poly(3,4-ethylenedioxythiophene) nanotubes toward fast window-type electrochromic device. Nanotechnology 18:405705
Mortimer RJ (2013) Switching colors with electricity. Am Sci 101:38–45
Doblhofer K, Rajeshwar K, Skotheim T, Elsenbaumer RL, Reynolds JR (1998) Handbook of conducting polymers. Marcel Dekker, New York
Fu Y-b, Ma X-h, Yang Q-h, Zong X-f (2003) The effect of fumed silica on the interfacial stability in the polymer gel electrolyte. Mater Lett 57:1759–1764
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Kelly, F.M., Cochrane, C. (2015). Color-Changing Textiles and Electrochromism. In: Tao, X. (eds) Handbook of Smart Textiles. Springer, Singapore. https://doi.org/10.1007/978-981-4451-45-1_16
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DOI: https://doi.org/10.1007/978-981-4451-45-1_16
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