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Synthesis of Inorganic, Polymer and Hybrid Nanoparticles Using Ultrasound

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Abstract

In this chapter, an attempt has been made to explain the role of ultrasonication in the synthesis of pure nanoparticles and nanoparticle-loaded polymers (i.e., hybrid). Ultrasound acts as an opportune method to synthesize metal, metal oxide nanoparticles, and hybrids with unique properties which are highly desirable for many applications. Extraordinary conditions such as temperature, pressure, heating, and cooling rates during the acoustic cavitation provide access to the range of chemical reaction conditions. These conditions generate the nanoparticles/hybrids with extremely large surface-to-volume ratio and specific surface area due to non-equilibrium conditions of cavitation interface. In this present chapter, new developments in ultrasound-assisted synthesis of inorganic nanomaterials and polymer-based hybrids had been discussed. In this chapter, the use of ultrasound atomization process for the production of the nanomaterials which are used in solar cells and electronics application was also discussed. The chapter also reports about the formation of the pigment dispersion which was an energy-intensive process when compared to planetary ball milling. Finally, the comparison of the acoustic cavitation and hydrodynamic cavitation was reported for nano-calcite production.

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References

  1. Chen D, Sharma SK, Mudhoo A (2012) Handbook on applications of ultrasound: sonochemistry for sustainability. CRC Press, Boca Raton

    Google Scholar 

  2. Cheeke JDN (2002) Fundamentals and applications of ultrasonic waves. CRC Press, Boca Raton

    Google Scholar 

  3. Sanghi R, Singh V, Cann MC, Connelly ME (2000) Real-world cases in green chemistry. ACS, Washington, DC

    Google Scholar 

  4. Manickam S, Ashokkumar M (2014) Cavitation: a novel energy-efficient technique for the generation of nanomaterials. CRC Press, Boca Raton

    Book  Google Scholar 

  5. Bang JH, Suslick KS (2010) Applications of ultrasound to the synthesis of nanostructured materials. Adv Mater 22:1039–1059

    Article  CAS  Google Scholar 

  6. Suslick KS, Gawienowski JW, Suhubert PF, Wag HH (1983) Alkane sonochemistry. J Phys Chem 87:2299–2301

    Article  CAS  Google Scholar 

  7. Suslick KS (2001) Sonoluminescence and sonochemistry. In: Meyers RA (ed) Enyclopedia of physical science and technology. Academic, San Diego

    Google Scholar 

  8. Mason TJ, Cordemans de Meulenaer E (1998) Synthetic organic sonochemistry. Plenum Press, New York

    Google Scholar 

  9. Pal U, Kim C, Jadhav N, Kang Y (2009) Ultrasound-assisted synthesis of mesoporous ZnO nanostructures of different porosities. J Phys Chem C 113:14676–14680

    Article  CAS  Google Scholar 

  10. Forcada J, Ramos J (2010) Encapsulation of inorganic by miniemulsion ploymerization. In: Mittal V (ed) Miniemulsion polymerization technology. Wiley Scrivener, Salem

    Google Scholar 

  11. Teo BM, Prescott SW, Ashokkumar M, Grieser F (2008) Ultrasound initiated miniemulsion polymerization of methacrylate monomers. Ultrasound Sonochem 15:89–94

    Article  CAS  Google Scholar 

  12. Kobayashi D, Matsumato H, Kuroda C (2008) Improvement of indirect ultrasonic irradiation method for intensification of emulsion polymerization process. Chem Eng J 135:43–48

    Article  CAS  Google Scholar 

  13. Teo BM, Ashokkumar M, Grieser F (2011) Sonochemical polymerization of miniemulsions in organic liquids/water mixtures. Phys Chem Chem Phys 13:4095–4102

    Article  CAS  Google Scholar 

  14. Xia H, Wang Q, Liao Y, Xu X, Baxter SM, Slone RV, Wu S, Swift G, Westmoreland DG (2002) Polymerization rate and mechanism of ultrasonically initiated emulsion polymerization of n-butyl acrylate. Ultrason Sonochem 9:151–158

    Article  CAS  Google Scholar 

  15. Kojima Y, Koda S, Nomura H (2001) Effect of ultrasonic frequency on polymerization of styrene under sonication. Ultrason Sonochem 8:75–79

    Article  CAS  Google Scholar 

  16. Wang R, Cheung HM (2005) Ultrasound assisted polymerization of MMA and styrene in near critical CO2. J Supercrit Fluids 33:269–274

    Article  Google Scholar 

  17. Chau HCJ, Stoffer JO (1999) Ultrasonically initiated free radical catalyzed emulsion polymerization of methyl methacrylate (I). J Appl Polym Sci 72:797–825

    Article  Google Scholar 

  18. Grieser F, Ashokkumar M (2004) Sonochemical synthesis of inorganic and organic colloids. In: Caruso F (ed) Colloids and colloid assemblies. Wiley-VCH GmbH & CoKga A, Weinheim, pp 120–149

    Google Scholar 

  19. Jing J, Feng C, Jinlong Z (2010) Carbon-deposited TiO2: synthesis, characterization, and visible photocatalytic performance. J Phys Chem C 114:933–939

    Article  Google Scholar 

  20. Shirsath SR, Pinjari DV, Gogate PR, Sonawane SH, Pandit AB (2013) Ultrasound assisted synthesis of doped TiO2 nanoparticles: characterization and comparison of effectiveness for photocatalytic oxidation of dyestuff effluent. Ultrason Sonochem 20:277–286

    Article  CAS  Google Scholar 

  21. Romuald B, Hamoudi S, Larachi F, Belkacemi K (2012) Synthesis of CaCO3 nanoparticles by controlled precipitation of saturated carbonate and calcium nitrate aqueous solutions. Can J Chem Eng 90:26–33

    Article  Google Scholar 

  22. Aboutaleb GJG, Mohammad I (2013) Characterization of CaCO3 nanoparticles synthesized by reverse microemulsion technique in different concentration of surfactants. Iran J Chem Eng 32:27–35

    Google Scholar 

  23. Sargheini J, Ataie A, Salili SM, Hoseinion AA (2012) One step facile synthesis of CaCO3 nanoparticles via mechano-chemical route. Powder Technol 219:72–77

    Article  CAS  Google Scholar 

  24. Shirsath SR, Sonawane SH, Saini DR, Pandit AB (2014) Continuous precipitation of calcium carbonate using sonochemical reactor. Ultrason Sonochem 24:132–139

    Article  Google Scholar 

  25. Gomez-Diaz D, Navaza JM, Sanjurjo B (2006) Analysis of mass transfer in the precipitation process of calcium carbonate using a gas/liquid reaction. Chem Eng J 116:203–209

    Article  CAS  Google Scholar 

  26. Wachi S, Jones AG (1991) Effect of gas–liquid mass transfer on crystal size distribution during the batch precipitation of calcium carbonate. Chem Eng Sci 46:3289–3293

    Article  CAS  Google Scholar 

  27. Silva P, Bucea L, Moorehead DR, Sirivivatnanon V (2006) Carbonate binders reaction kinetics strength and microstructure. Cement Concr Compos 28:613–620

    Article  Google Scholar 

  28. Sun Q, Deng Y (2004) Synthesis of micrometer to nanometer CaCO3 particles via mass restriction method in an emulsion liquid membrane process. J Colloid Interface Sci 278:376–382

    Article  CAS  Google Scholar 

  29. Sonawane SH, Shirsanth SR, Khanna PK, Pawar S, Mahajan CM, Paithankar V, Shinde V, Kapadnis CV (2008) An innovative method for effective micro-mixing of CO2 gas during synthesis of nano-calcite crystal using sonochemical carbonization. Chem Eng J 143:308–313

    Article  CAS  Google Scholar 

  30. Sonawane SH, Gumfekar SP, Meshram S, Deosarkar MP, Mahajan CM, Khanna P (2009) Combined effect of surfactant and ultrasound on nano calcium carbonate synthesized by crystallization process. Int J Chem React Eng 7:1–15

    Google Scholar 

  31. Li S, Toprak MS, Jo YS, Dobson J, Kim DK, Muhammed M (2007) Bulk synthesis of transparent and homogeneous polymeric hybrid materials with ZnO quantum dots and PMMA. Adv Mater 19:4347–4352

    Article  CAS  Google Scholar 

  32. Askari S, Halladj R (2013) Effects of ultrasound-related variables on sonochemically synthesized SAPO-34 nanoparticles. J Solid State Chem 201:85–92

    Article  CAS  Google Scholar 

  33. Barkade SS, Pinjari DV, Singh AK, Gogate PR, Naik JB, Sonawane SH, Pandit AB, Ashokkumar M (2013) Ultrasound assisted miniemulsion polymerization for preparation of polypyrrole zinc oxide (PPy/ZnO) functional latex for LPG sensing. Ind Eng Chem Res 52:7704–7712

    Article  CAS  Google Scholar 

  34. Barkade SS, Pinjari DV, Nakate UT, Singh AK, Gogate PR, Naik JB, Sonawane SH, Pandit AB (2013) Ultrasound assisted synthesis of polythiophene/SnO2 hybrid nanolatex particles for LPG sensing. Chem Eng Process 74:115–123

    Article  CAS  Google Scholar 

  35. Sonawane SH, Neppolian B, Teo BM, Grieser F, Ashokkumar M (2010) Ultrasound-assisted preparation of semiconductor/polymer photoanodes and their photoelectrochemical properties. J Phys Chem C 114:5148–5153

    Article  CAS  Google Scholar 

  36. Bhanvase BA, Sonawane SH (2010) New approach for simultaneous enhancement of anticorrosive and mechanical properties of coatings: application of water repellent nano CaCO3–PANI emulsion nanocomposite in alkyd resin. Chem Eng J 156:177–183

    Article  CAS  Google Scholar 

  37. Elik MC, Onal M (2007) Intercalated polyaniline/Na-montmorillonite nanocomposites via oxidative polymerization. J Polym Res 14:313–331

    Article  Google Scholar 

  38. Bhanvase BA, Kutbuddin Y, Borse RN, Selokar NR, Pinjari DV, Gogate PR, Sonawane SH, Pandit AB (2013) Ultrasound assisted synthesis of calcium zinc phosphate pigment and its application in nanocontainer for active anticorrosion coatings. Chem Eng J 231:345–354

    Article  CAS  Google Scholar 

  39. Kapole SA, Bhanvase BA, Pinjari DV, Kulkarni RD, Patil UD, Gogate PR, Sonawane SH, Pandit AB (2014) Intensification of corrosion resistance of 2 K epoxy coating by encapsulation of liquid inhibitor in nanocontainer core of sodium zinc molybdate and iron oxide. Compos Interfaces 21:469–486

    Article  CAS  Google Scholar 

  40. Prasad K, Sonawane SH, Zhou M, Muthupandian A (2013) Ultrasound assisted synthesis and characterization of poly(methyl methacrylate)/CaCO3 nanocomposites. Chem Eng J 219:254–261

    Article  CAS  Google Scholar 

  41. Maruthamuthu P (1980) Absolute rate constants for the reactions of sulfate, phosphate and hydroxyl radicals with monomers. Macromol Chem Rapid Commun 1:23–25

    Article  CAS  Google Scholar 

  42. Criquet J, Leitner NKV (2009) Degradation of acetic acid with sulfate radical generated by persulfate ions photolysis. Chemosphere 77:194–200

    Article  CAS  Google Scholar 

  43. Karekar SE, Bhanvase BA, Sonawane SH, Deosarkar MP, Pinjari DV, Pandit AB (2015) Synthesis of zinc molybdate and zinc phosphomolybdate nanopigments by an ultrasound assisted route: advantage over conventional method. Chem Eng Process 87:51–59

    Article  CAS  Google Scholar 

  44. Gurav P, Naik S, Bhanvase BA, Pinjari DV, Sonawane SH, Ashokkumar M (2015) Heat transfer intensification using polyaniline based nanofluids: preparation and application. Chem Eng Process 95:195–201

    Article  CAS  Google Scholar 

  45. Badgujar NP, Bhoge YE, Deshpande TD, Bhanvase BA, Gogate PR, Sonawane SH, Kulkarni RD (2015) Ultrasound assisted organic pigment dispersion: advantages of ultrasound method over conventional method. Pigment Resin Technol 44:214–223

    Article  CAS  Google Scholar 

  46. Yasuda K, Bando Y, Yamaguchi S, Nakamura M, Oda A, Kawase Y (2005) Analysis of concentration characteristics in ultrasonic atomization by droplet diameter distribution. Ultrason Sonochem 12:37–41

    Article  CAS  Google Scholar 

  47. Wang WN, Purwanto A, Lenggoro IW, Okuyama K, Chang H, Jang HD (2008) Investigation on the correlations between droplet and particle size distribution in ultrasonic spray pyrolysis. Ind Eng Chem Res 47:1650–1659

    Article  CAS  Google Scholar 

  48. Ramisetty KA, Pandit AB, Gogate PR (2012) Investigations into ultrasound induced atomization. Ultrason Sonochem 20:254–264

    Article  Google Scholar 

  49. Liu R, Liu L, Liu J (2009) Massive production of nanoparticles via mist reaction. Physica E 41:1197–1200

    Article  CAS  Google Scholar 

  50. Bang JH, Didenko YT, Helmich RJ, Suslick KS (2012) Nanostructured materials through ultrasonic spray pyrolysis. Mater Matters 7:15–18

    CAS  Google Scholar 

  51. Sonawane SH, Chaudhari PL, Ghodke SA, Parande MG, Bhandari VM, Mishra S, Kulkarni RD (2009) Ultrasound assisted synthesis of polyacrylic acid–nanoclay nanocomposite and its application in sonosorption studies of malachite green dye. Ultrason Sonochem 16:351–355

    Article  CAS  Google Scholar 

  52. Sonawane SH, Chaudhari PL, Ghodke SA, Ambade SB, Gulig S, Mirikar A, Bane A (2008) Combined effect of ultrasound and nanoclay on adsorption of phenol. Ultrason Sonochem 15:1033–1037

    Article  CAS  Google Scholar 

  53. Sonawane SH, Gumfekar SP, Kate SH, Meshram SP, Kunte KJ, Ramjee L, Mahajan CM, Parande MG, Ashokkumar M (2010) Hydrodynamic cavitation-assisted synthesis of nanocalcite, Int J Chem Eng 10:1–8

    Google Scholar 

  54. Sonawane SH, Kapadnis CV, Meshram S, Gumfekar SP, Khanna PK (2010) Sonochemical formation of CaCO3 nanoparticles with controlled particle size distribution. Int J Green Nanotechnol PhysChem 2:69–79

    Article  Google Scholar 

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Shaik, S., Sonawane, S., Barkade, S., Bhanvase, B. (2015). Synthesis of Inorganic, Polymer and Hybrid Nanoparticles Using Ultrasound. In: Ashokkumar, M. (eds) Handbook of Ultrasonics and Sonochemistry. Springer, Singapore. https://doi.org/10.1007/978-981-287-470-2_17-1

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  • DOI: https://doi.org/10.1007/978-981-287-470-2_17-1

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  • Publisher Name: Springer, Singapore

  • Online ISBN: 978-981-287-470-2

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