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Metal Impurities and Gettering in Crystalline Silicon

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Handbook of Photovoltaic Silicon

Abstract

Solar-grade Si usually contains a considerable amount of metal impurities and extended defects. The detrimental effect of transition metals on solar cell performance is well documented. This necessitates a study of transition metal properties in Si and their interaction with point and extended defects. Such studies will form the basis for the development of procedures on suppressing the detrimental effects of transition metals. This chapter briefly describes the solubilities, diffusivities, and electrical properties of metal impurities that are most frequently detected in multicrystalline silicon. The diffusion length values necessary for highly efficient crystalline silicon solar cells, which set a limit on the electrically active metal concentration, are estimated. The effects of dislocations and grain boundaries on the effective diffusion length are evaluated. Finally, the efficiency of gettering and hydrogen passivation procedures used in silicon solar cell technology is considered.

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References

  • K. Adamczyk, R. SøndenÃ¥, C.C. You, G. Stokkan, J. Lindroos, M. Rinio, M. Di Sabatino, Phys. Status Solidi A 215, 1700493 (2018)

    Article  CAS  Google Scholar 

  • M. Al-Amin, J.D. Murphy, J. Appl. Phys. 119, 235704 (2016)

    Article  CAS  Google Scholar 

  • M. Al-Amin, N.E. Grant, J.D. Murphy, Phys. Status Solidi (RRL) 11, 1700268 (2017)

    Article  CAS  Google Scholar 

  • J. Chen, T. Sekiguchi, D. Yang, Phys. Status Solidi C 4, 2908 (2007)

    Article  CAS  Google Scholar 

  • B. Chen, J. Chen, T. Sekiguchi, M. Saito, K. Kimoto, J. Appl. Phys. 105, 113502 (2009)

    Article  CAS  Google Scholar 

  • S.C. Choo, Phys. Rev. B 1, 687 (1970)

    Article  Google Scholar 

  • C. Claeys, E. Simoen, Metal Impurities in Silicon and Germanium-Based Technologies. Origin, Characterization, Control, and Device Impact (Springer, Basel, 2018)

    Book  Google Scholar 

  • G. Coletti, P.C.P. Bronsveld, G. Hahn, W. Warta, D. Macdonald, B. Ceccaroli, K. Wambach, N. Le Quang, J.M. Fernandez, Adv. Funct. Mater. 21, 879 (2011)

    Article  CAS  Google Scholar 

  • C. Donolato, Appl. Phys. Lett. 46, 270 (1985)

    Article  Google Scholar 

  • C. Donolato, Semicond. Sci. Technol. 7, 37 (1992)

    Article  Google Scholar 

  • C. Donolato, J. Appl. Phys. 84, 2656 (1998a)

    Article  CAS  Google Scholar 

  • C. Donolato, Semicond. Sci. Technol. 13, 781 (1998b)

    Article  CAS  Google Scholar 

  • O.V. Feklisova, A.L. Parakhonsky, E.B. Yakimov, J. Weber, Mater. Sci. Eng. B 71, 268 (2000)

    Article  Google Scholar 

  • O.V. Feklisova, E.B. Yakimov, N.A. Yarykin, Semiconductors 36, 282 (2002)

    Article  CAS  Google Scholar 

  • O.V. Feklisova, X. Yu, D. Yang, E.B. Yakimov, Phys. Status Solidi C 9, 1942 (2012)

    Article  CAS  Google Scholar 

  • K. Graff, Metal Impurities in Silicon-Device Fabrication, 2nd edn. (Springer, Berlin/Heidelberg, 2000)

    Book  Google Scholar 

  • R.N. Hall, Phys. Rev. 87, 387 (1952)

    Article  CAS  Google Scholar 

  • F.D. Heinz, M. Breitwieser, P. Gundel, M. Konig, M. Horteis, W. Warta, M.C. Schubert, Sol. Energy Mater. Sol. Cells 131, 105 (2014)

    Article  CAS  Google Scholar 

  • T. Heiser, A. Mesli, Phys. Rev. Lett. 68, 978 (1992)

    Article  CAS  Google Scholar 

  • A.A. Istratov, T. Buonassisi, M.D. Pickett, M. Heuer, E.R. Weber, Mater. Sci. Eng. B 134, 282 (2006)

    Article  CAS  Google Scholar 

  • M. Kittler, J. Lärz, W. Seifert, M. Seibt, W. Schröter, Appl. Phys. Lett. 58, 911 (1991)

    Article  CAS  Google Scholar 

  • V.I. Kolkovsky, L. Scheffler, J. Weber, Physica B 439, 24 (2014)

    Article  CAS  Google Scholar 

  • S.V. Koveshnikov, E.B. Yakimov, N. Yarykin, V.A. Yunkin, Phys. Status Solidi A 111, 81 (1989)

    Article  CAS  Google Scholar 

  • S.H. Lee, M.F. Bhopal, D.W. Lee, S.H. Lee, Mater. Sci. Semicond. Process. 79, 66 (2018)

    Article  CAS  Google Scholar 

  • S. Leonard, V.P. Markevich, A.R. Peaker, B. Hamilton, J.D. Murphy, Appl. Phys. Lett. 107, 032103 (2015)

    Article  CAS  Google Scholar 

  • A.Y. Liu, D. Macdonald, Phys. Status Solidi (RRL) 12, 1700430 (2018)

    Article  CAS  Google Scholar 

  • A. Mesli, T. Heiser, E. Mulheim, Mater. Sci. Eng. B 25, 141 (1994)

    Article  CAS  Google Scholar 

  • V.I. Orlov, E.B. Yakimov, E.P. Magomedbekov, A.B.. Danilin, Adv. Condens. Matter Phys. 2017, 1946490 (2017)

    Google Scholar 

  • O. Palais, E. Yakimov, S. Martinuzzi, Mater. Sci. Eng. B 91–92, 216 (2002)

    Article  Google Scholar 

  • S.M. Peshcherova, E.B. Yakimov, A.I. Nepomnyashchikh, L.A. Pavlova, O.V. Feklisova, Semiconductors 49, 724 (2015)

    Article  CAS  Google Scholar 

  • S. Pizzini, Advanced Silicon Materials for Photovoltaic Applications (Wiley, Chichester, 2012)

    Book  Google Scholar 

  • I.E. Reis, S. Riepe, W. Koch, J. Bauer, S. Beljakowa, O. Breitenstein, H. Habenicht, D. Kreßner-Kiel, G. Pensl, J. Schon, W. Seifert, in Proceedings of the 24th European Photovoltaic Solar Energy Conference and Exhibition, Hamburg, 2009, p. 2144

    Google Scholar 

  • T. Sadoh, M. Watanabe, H. Nakashima, T. Tsurushima, J. Appl. Phys. 75, 3978 (1994)

    Article  CAS  Google Scholar 

  • L. Scheffler, V. Kolkovsky, J. Weber, AIP Conf. Ser. 1583, 85 (2014a)

    CAS  Google Scholar 

  • L. Scheffler, V. Kolkovsky, J. Weber, J. Appl. Phys. 116, 173704 (2014b)

    Article  CAS  Google Scholar 

  • J. Schmidt, B. Lim, D. Walter, K. Bothe, S. Gatz, T. Dullweber, P.P. Altermatt, IEEE J. Photovoltaics 3, 114 (2013)

    Article  Google Scholar 

  • M. Seibt, V. Kveder, in Advanced Silicon Materials for Photovoltaic Applications, ed. by b. S. Pizzini, (Wiley, Chichester, 2012), p. 127

    Chapter  Google Scholar 

  • Y.L. Shabel’nikova, E.B. Yakimov, J. Surf. Investig. 6, 894 (2012)

    Article  CAS  Google Scholar 

  • W. Shockley, W.T. Read, Phys. Rev. 87, 835 (1952)

    Article  CAS  Google Scholar 

  • G. Stokkan, D.S. Marisa, R. SøndenÃ¥, M. Juel, A. Autruffe, K. Adamczyk, H.V. Skarstad, K.E. Ekstrøm, M.S. Wiig, C.C. You, H. Haug, M. M‘Hamdi, Phys. Status Solidi A 214, 1700319 (2017)

    Article  CAS  Google Scholar 

  • T. Tachibana, T. Sameshima, T. Kojima, K. Arafune, K. Kakimoto, Y. Miyamura, H. Harada, T. Sekiguchi, Y. Ohshita, A. Ogura, J. Appl. Phys. 111, 074505 (2012)

    Article  CAS  Google Scholar 

  • H. Takahashi, M. Suezawa, K. Sumino, Phys. Rev. B 46, 1882 (1992)

    Article  CAS  Google Scholar 

  • C.K. Tang, L. Vines, B.G. Svensson, E.V. Monakhov, Appl. Phys. Lett. 99, 052106 (2011)

    Article  CAS  Google Scholar 

  • E.B. Yakimov, J. Phys. Condens. Matter 14, 13069 (2002)

    Article  CAS  Google Scholar 

  • E. Yakimov, I. Périchaud, Appl. Phys. Lett. 67, 2054 (1995)

    Article  CAS  Google Scholar 

  • E. Yakimov, G. Mariani, B. Pichaud, J. Appl. Phys. 78, 1495 (1995)

    Article  CAS  Google Scholar 

  • N. Yarykin, J. Weber, Phys. Rev. B 88, 085205 (2013)

    Article  CAS  Google Scholar 

  • N. Yarykin, J. Weber, Appl. Phys. Lett. 105, 012109 (2014)

    Article  CAS  Google Scholar 

  • N. Yarykin, J. Weber, Appl. Phys. Lett. 109, 102101 (2016)

    Article  CAS  Google Scholar 

  • N. Yarykin, J.-U. Sachse, H. Lemke, J. Weber, Phys. Rev. B 59, 5551 (1999)

    Article  CAS  Google Scholar 

  • T. Zundel, J. Weber, B. Benson, P.O. Hahn, A. Schnegg, H. Prigge, Appl. Phys. Lett. 53, 1426 (1988)

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Microelectronics Technology, Russian Academy of Science, Chernogolovka, Russia

    Eugene B. Yakimov

  2. National University of Science and Technology, MISiS, Moscow, Russia

    Eugene B. Yakimov

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  1. Eugene B. Yakimov
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Correspondence to Eugene B. Yakimov .

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Editors and Affiliations

  1. State Key Laboratory of Silicon Materials and School of Materials Science and Engineering, Zhejiang University, Hangzhou, China

    Deren Yang

Section Editor information

  1. Faculty of Physics - IV. Physical Institute - Ropers group, Georg-August-University Goettingen, Goettingen, Germany

    Michael Seibt

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Yakimov, E.B. (2019). Metal Impurities and Gettering in Crystalline Silicon. In: Yang, D. (eds) Handbook of Photovoltaic Silicon. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-56472-1_23

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