Skip to main content
SpringerLink
Log in

Carbon Dioxide-Based Polymers

  • Living reference work entry
  • First Online:
Encyclopedia of Polymeric Nanomaterials

  • 535 Accesses

Synonyms

Polymeric materials made from carbon dioxide

Definition

Carbon dioxide-based polymers are here defined as “a polymer of which carbon dioxide comprises the main chain.” The carbon dioxide incorporated into a polymer main chain forms carbonate/carbamate/urea (Fig. 1, left) or ester (Fig. 1, right) structures.

Fig. 1
figure 1

Possible structures of incorporated carbon dioxide and their retro-syntheses

Full size image

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution

Institutional subscriptions

References

  1. Sakakura T, Choi J-C, Yasuda H (2007) Transformation of carbon dioxide. Chem Rev 107:2365–2387. doi:10.1021/cr068357u

    Article  CAS  Google Scholar 

  2. Aresta M (2010) Carbon dioxide as chemical feedstock. Wiley-VCH, Weinheim

    Book  Google Scholar 

  3. Diem H, Mattias G, Wagner RA (2010) Amino resins. In: Elvers B. et al. (2011) Ullmann’s encyclopedia of industrial chemistry. 7th Ed. Wiley-VCH, Weinheim. doi:10.1002/14356007.a02_115.pub2

    Google Scholar 

  4. Coates GW, Moore DR (2004) Discrete metal-based catalysts for the copolymerization of CO2 and epoxides: discovery, reactivity, optimization, and mechanism. Angew Chem Int Ed 43:6618–6639. doi:10.1002/anie.200460442

    Article  CAS  Google Scholar 

  5. Sugimoto H, Inoue S (2004) Copolymerization of carbon dioxide and epoxide. J Polym Sci A Polym Chem 42:5561–5573. doi:10.1002/pola.20319

    Article  CAS  Google Scholar 

  6. Darensbourg DJ (2007) Making plastics from carbon dioxide: salen metal complexes as catalysts for the production of polycarbonates from epoxides and CO2. Chem Rev 107:2388–2410. doi:10.1021/cr068363q

    Article  CAS  Google Scholar 

  7. Kember MR, Buchard A, Williams CK (2010) Catalysts for CO2/epoxide copolymerisation. Chem Commun 47:141–163. doi:10.1039/C0CC02207A

    Article  Google Scholar 

  8. Lu X-B, Darensbourg DJ (2012) Cobalt catalysts for the coupling of CO2 and epoxides to provide polycarbonates and cyclic carbonates. Chem Soc Rev 41:1462–1484. doi:10.1039/C1CS15142H

    Article  CAS  Google Scholar 

  9. Wu G-P, Ren W-M, Luo Y, Li B, Zhang W-Z, Lu X-B (2012) Enhanced asymmetric induction for the copolymerization of CO2 and cyclohexene oxide with unsymmetric enantiopure salenCo(III) complexes: synthesis of crystalline CO2-based polycarbonate. J Am Chem Soc 134:5682–5688. doi:10.1021/ja300667y

    Article  CAS  Google Scholar 

  10. Wu G-P, Xu P-X, Lu X-B, Zu Y-P, Wei S-H, Ren W-M, Darensbourg DJ (2013) Crystalline CO2 copolymer from epichlorohydrin via Co(III)-complex-mediated stereospecific polymerization. Macromolecules 46:2128–2133. doi:10.1021/ma400252h

    Article  CAS  Google Scholar 

  11. Wu GP, Jiang SD, Lu XB, Ren WM, Yan SK (2012) Stereoregular poly(cyclohexene carbonate)s: unique crystallization behavior. Chin J Polym Sci 30:487–492. doi:10.1007/s10118-012-1171-x

    Article  CAS  Google Scholar 

  12. Nakano K, Kobayashi K, Ohkawara T, Imoto H, Nozaki K (2013) Copolymerization of epoxides with carbon dioxide catalyzed by iron–corrole complexes: synthesis of a crystalline copolymer. J Am Chem Soc 135:8456–8459. doi:10.1021/ja4028633

    Article  CAS  Google Scholar 

  13. Ren W-M, Liang M-W, Xu Y-C, Lu X-B (2013) Trivalent cobalt complex mediated formation of stereoregular CO2 copolymers from phenyl glycidyl ether. Polym Chem 4:4425–4433. doi:10.1039/C3PY00554B

    Article  CAS  Google Scholar 

  14. Price CJ, Reich BJE, Miller SA (2006) Thermodynamic and kinetic considerations in the copolymerization of ethylene and carbon dioxide. Macromolecules 39:2751–2756. doi:10.1021/ma052697kd

    Article  CAS  Google Scholar 

  15. Nakano R, Ito S, Nozaki K (2014) Copolymerization of carbon dioxide and butadiene via a lactone intermediate. Nat Chem 6:325–331. doi:10.1038/nchem.1882

    Article  CAS  Google Scholar 

  16. Soga K, Hosoda S, Ikeda S (1975) Copolymerization of carbon dioxide and some diene compounds. Die Makromol Chem 176:1907–1911. doi:10.1002/macp.1975.021760630

    Article  CAS  Google Scholar 

  17. Chiang W-Y (1978) Copolymerization of carbon dioxide and acrylonitrile. Proc Natl Sci Counc ROC 2:170–176

    CAS  Google Scholar 

  18. Terajima T, Koinuma H (2004) A cold plasma generator and its applications to combinatorial copolymerization of carbon dioxide with organic molecules. Macromol Rapid Commun 25:312–314. doi:10.1002/marc.200300203

    Article  CAS  Google Scholar 

  19. Behr A, Henze G (2011) Use of carbon dioxide in chemical syntheses via a lactone intermediate. Green Chem 13:25–39. doi:10.1039/C0GC00394H

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan

    Ryo Nakano & Kyoko Nozaki

Authors
  1. Ryo Nakano
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Kyoko Nozaki
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Kyoko Nozaki .

Editor information

Editors and Affiliations

  1. Kyoto Institute of Technology R & D Center for Bio-Based Materials, Kyoto, Japan

    Shiro Kobayashi

  2. Max-Planck-Institut für Polymerforschung, Mainz, Germany

    Klaus Müllen

Rights and permissions

Reprints and permissions

Copyright information

© 2014 Springer-Verlag Berlin Heidelberg

About this entry

Cite this entry

Nakano, R., Nozaki, K. (2014). Carbon Dioxide-Based Polymers. In: Kobayashi, S., Müllen, K. (eds) Encyclopedia of Polymeric Nanomaterials. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-36199-9_330-1

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-36199-9_330-1

  • Received:

  • Accepted:

  • Published:

  • Publisher Name: Springer, Berlin, Heidelberg

  • Online ISBN: 978-3-642-36199-9

  • eBook Packages: Springer Reference Chemistry and Mat. ScienceReference Module Physical and Materials ScienceReference Module Chemistry, Materials and Physics

Publish with us

Policies and ethics

Search

Navigation