Definition
The polymer-based composite materials in which silicate layers of clay minerals are dispersed at nano level.
Introduction
In 1985, nylon 6 clay hybrid (NCH) was created by polymerizing caprolactam in the interlayer spacing of montmorillonite, a clay mineral. Transmission electron micrograph (TEM) and scanning electron micrograph (SEM) [1] observations (Fig.1) revealed that each silicate molecule of thickness of 1 nm was homogeneously dispersed in nylon 6 matrix. NCH is the first polymer nanocomposites where nylon 6 and clay silicates are dispersed on a molecular level. NCH containing only small amount of clay shows excellent properties when compared to pristine nylon 6 in terms of strength, modulus, heat resistance, gas barrier property, dimension stability, and appearance. Nylon 6 has been successfully reinforced by using conventional filler such as glass fiber or other inorganic materials. The size of those fillers...
References
Usuki A, Hasegawa N, Kadoura H, Okamoto T (2001) Three-dimensional observation of structure and morphology in nylon-6/clay nanocomposite. Nano Lett 1:271
Okada A, Usuki A (2006) Twenty years of polymer clay nanocomposites. Macromol Mater Eng 291:1449
Usuki A, Hasegawa N, Kato M (2005) Polymer-clay nanocomposites. Adv Polym Sci 179:135
Usuki A, Kojima Y, Kawasumi M, Okada A, Kurauchi T, Kamigaito O (1993) Swelling behavior of Montmorillonite cation-exchanged for ω-amino acids by ε-caprolactam. J Mater Res 8:1174
Usuki A, Kawasumi M, Kojima Y, Fukushima Y, Okada A, Kurauchi T, Kamigaito O (1993) Synthesis of nylon 6-clay hybrid. J Mater Res 8:1179
Kojima Y, Usuki A, Kawasumi M, Fukushima Y, Okada A, Kurauchi T, Kamigaito O (1993) Mechanical properties of nylon 6-clay hybrid. J Mater Res 8:1185
Messersmith PB, Giannelis EP (1995) Synthesis and barrier properties of poly(ε-caprolactone)- layered silicate nanocomposites. J Polym Sci A Polym Chem 33:1047
Lan T, Pinnavaia TJ (1994) Clay- reinforced epoxy nanocomposites. Chem Mater 6:2216
Usuki A, Okamoto K, Okada A, Kurauchi T (1995) Synthesis and properties of acrylic polymer-clay hybrid. Kobunshi Ronbunshu 52:728
Kojima Y, Fukumori K, Usuki A, Okada A, Kurauchi T (1993) Gas permeabilities in rubber clay hybrid. J Mater Sci Lett 12:889
Yano K, Usuki A, Okada A, Kurauchi T (1993) Synthesis and properties of polyimide-clay hybrid. J Polym Sci A Polym Chem 31:2493
Kawasumi M, Hasegawa N, Kato M, Usuki A, Okada A (1997) Preparation and mechanical properties of polypropylene-clay hybrids. Macromolecules 30:6333
Kato M, Okamoto H, Hasegawa N, Tsukigase A, Usuki A (2003) Preparation and properties of polyethylene-clay hybrids. Polym Eng Sci 43:1312
Hasegawa N, Okamoto H, Usuki A (2004) Preparation and properties of ethylene propylene rubber(EPR)-clay nanocomposites based on maleic anhydride-modified EPR and organophilic clay. J Appl Polym Sci 93:758
Usuki A, Tukigase A, Kato M (2002) Preparation and properties of EPDM-clay hybrids. Polymer 43:2185
Kato M, Tukigase A, Tanaka H, Usuki A, Inai I (2006) Preparation and properties of Isobutylene–Isoprene rubber–clay nanocomposites. J Polym Sci Part A Polym Chem 44:1182
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2014 Springer-Verlag Berlin Heidelberg
About this entry
Cite this entry
Nakano, M., Usuki, A. (2014). Clay Nanohybrid Materials. In: Kobayashi, S., Müllen, K. (eds) Encyclopedia of Polymeric Nanomaterials. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-36199-9_223-1
Download citation
DOI: https://doi.org/10.1007/978-3-642-36199-9_223-1
Received:
Accepted:
Published:
Publisher Name: Springer, Berlin, Heidelberg
Online ISBN: 978-3-642-36199-9
eBook Packages: Springer Reference Chemistry and Mat. ScienceReference Module Physical and Materials ScienceReference Module Chemistry, Materials and Physics