Encyclopedia of Astrobiology

Living Edition
| Editors: Muriel Gargaud, William M. Irvine, Ricardo Amils, Henderson James Cleaves, Daniele Pinti, José Cernicharo Quintanilla, Michel Viso

Aldehyde

Living reference work entry
DOI: https://doi.org/10.1007/978-3-642-27833-4_46-6

Definition

Aldehydes are organic compounds containing the RCHO functional group where R can be hydrogen or another carbon-containing moiety. Aldehydes are named after the corresponding carboxylic acids by dropping the -ic or -oic suffix and adding -aldehyde or -al (e.g., acetic acid acetaldehyde, ethanoic acid → ethanal), or if derived from acyclic aliphatic hydrocarbons, by dropping the final e and adding -al (e.g., propane → propanal). Formyl derivatives of ring compounds may be called carbaldehydes as in cyclopentanecarbaldehyde. See the IUPAC rules for more complex cases.

Aldehydes can be reduced to alcohols or oxidized to carboxylic acids and undergo a variety of addition and condensation reactions, for example, addition of cyanide in the cyanohydrin synthesis, or condensation with another aldehyde in a benzoin reaction or condensation with the carbon adjacent to an aldehyde or ketone in the aldol reaction.

History

The name may be derived from the phrase “alcohol dehydrogenatum.”

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Keywords

Acetic Acid Organic Compound Carboxylic Acid Bioorganic Chemistry Condensation Reaction 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Copyright information

© Springer-Verlag Berlin Heidelberg 2014

Authors and Affiliations

  1. 1.Scripps Institute of Oceanography Geosciences Research DivisionUniversity of California, San DiegoLa JollaUSA