Abstract
Phenolics are an important class of natural products that have received immense interest for their remarkable biological activities. These are widely distributed in the plant kingdom. Nowadays, increasing attention is paid on rapid identification and characterization of phenolic acids from natural sources. This chapter particularly emphasizes on the diverse mass spectrometric application for the detection of phenolic acids, and several aspects related to fragmentation behavior of phenolic acids are discussed.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Abbreviations
- ESI:
-
Electro spray ionization
- GC:
-
Gas chromatography
- HPLC:
-
High-performance liquid chromatography
- MALDI:
-
Matrix-assisted laser desorption/ionization
- MS:
-
Mass spectrometry
References
Carl-Ove A (1958) Mass spectrometric studies on amino acid and peptide derivatives. Acta Chem Scand 12:1353
The Nobel Prize in Chemistry 2002 Information for the Public (2007) The Nobel Foundation. Retrieved 29 Aug 2007
David SO (2000) Mass spectrometry desk reference. Global View Publishing, Pittsburgh. ISBN 0-9660813-2-3
Ashcroft AE (1997) Ionization methods in organic mass spectrometry. The Royal Society of Chemistry, Cambridge, UK
Sleno L, Volmer DA (2004) Ion activation methods for tandem mass spectrometry. J Mass Spectrom 39:1091–1112
Bate-Smith EC, Swain T (1962) Flavonoid compounds. In: Mason HS, Florkin AM (eds) Comparative biochemistry, vol III. Academic Press, New York, pp 755–809
Harborne JB, Simmonds NW (1964) Biochemistry of phenolic compounds. Academic, London, p 101
Ribéreau-Gayon P (1972) Plant phenolics. Oliver and Boyd, Edinburgh, p 254
Schmitz-Hoerner R, Weissenbock G (2003) Contribution of phenolic compounds to the UV-B screening capacity of developing barley primary leaves in relation to DNA damage and repair under elevated UV-B levels. Phytochemistry 64:243–255
Clé C, Hill LM, Niggeweg R, Martin CR, Guisez Y, Prinsen E, Jansen MAK (2008) Modulation of chlorogenic acid biosynthesis in Solanum lycopersicum; consequences for phenolic accumulation and UV-tolerance. Phytochemistry 69:2149–2156
Chakraborty D, Sircar D, Mitra A (2008) Phenylalanine ammonia-lyase-mediated biosynthesis of 2-hydroxy-4-methoxybenzaldehyde in roots of Hemidesmus indicus. J Plant Physiol 165:1033–1040
Kefeli VI, Kalevitch MV, Borsari B (2003) Phenolic cycle in plants and environment. J Cell Mol Biol 2:13–18
Dixon RA, Paiva NL (1995) Stress induced phenylpropanoid metabolism. Plant Cell 7:1085–1097
Balasundram N, Sundram K, Samman S (2006) Phenolic compounds in plants and agri-industrial by-products: antioxidant activity, occurrence, and potential use. Food Chem 99:191–203
Mandal SM, Chakraborty D, Dey S (2010) Phenolic acids are the signaling molecule in plant-microbe symbioses. Plant Signal Behav 5:359–368
Chakraborty D, Mandal SM (2008) Fractional changes in phenolic acids composition in root nodules of Arachis hypogaea L. Plant Growth Regul 55:159–163
Chakraborty D, Mandal SM, Chakraborty J, Bhattacharyaa PK, Bandyopadhyay A, Mitra A, Gupta K (2007) Antimicrobial activity of leaf extracts of Basilicum polystachyon (L) Moench. Indian J Exp Biol 45:744–748.
Saleem M, Nazir M, Shaiq Ali M, Hussain H, Sup Lee Y, Riaz N, Jabbar A (2010) Antimicrobial natural products: an update on future antibiotic drug candidates. Nat Prod Rep 27:238–254
Fenselau C (1983) Fast atom bombardment (review). In: Benninghoven A (ed) Ion formation from organic solids: proceedings of the Second International Conference, vol 25, Springer series in chemical physics. Springer, New York, p 90
Sundqvist B, Macfarlane RD (1985) 252Cf-plasma desorption mass spectrometry. Mass Spectrom Rev 4:421–460
Cole RB (2000) Some tenets pertaining to electrospray ionization mass spectrometry. J Mass Spectrom 35:763–772
Hartley RD (1971) Improved methods for the estimation of gas-liquid chromatography of lignin degradation products from plants. J Chromatogr 54:335–344
Van de Casteele K, De Pooter H, Van Sumere CF (1976) Gas chromatographic separation and analysis of trimethylsilyl dervatives of some naturally occurring nonvolative phenolic compounds and related substances. J Chromatogr 121:49–63
Schulz JM, Herrmann K (1980) Analysis of hydroxybenzoic and hydroxycinnamic acids in plant material. I. Sample preparation and thin-layer chromatography. J Chromatogr 195:85–94
Christov R, Bankova V (1992) Gas chromatographic analysis of underivatized phenolic constituents from propolis using an electron-capture detector. J Chromatogr A 623:182–185
Zuo Y, Wang C, Zhan J (2002) Separation, characterization, and quantitation of benzoic and phenolic antioxidants in American cranberry fruit by GC-MS. J Agric Food Chem 50:3789–3794
Karas M, Bachmann D, Bahr U, Hillenkamp F (1987) Matrix-assisted ultraviolet laser desorption of non-volatile compounds. Int J Mass Spectrom Ion Processes 78:53–68.
Karas M (1996) Matrix-assisted laser desorption ionization MS: a progress report. Biochem Mass Spectrom 24:897–900
Wang J, Sporns P (2000) MALDI-ToF MS analysis of food flavonol glycosides. J Agric Food Chem 48:1657–1662
Reed JD, Krueger CG, Vestling MM (2005) MALDI-TOF mass spectrometry of oligomeric food polyphenols. Phytochemistry 66:2248–2263
Mandal SM, Dey S (2008) LC-MALDI-TOF MS-based rapid identification of phenolic acids. J Biomol Tech 19:116–121
Takahata Y, Ohnishi-Kameyama M, Furuta S, Takahashi M, Suda, I (2001) Highly polymerized procyanidins in brown soybean seed coat with a high radical-scavenging activity. J Agric Food Chem 49:5843–5847
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2013 Springer-Verlag Berlin Heidelberg
About this entry
Cite this entry
Mandal, S.M., Chakraborty, D. (2013). Mass Spectrometric Detection of Phenolic Acids. In: Ramawat, K., Mérillon, JM. (eds) Natural Products. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-22144-6_90
Download citation
DOI: https://doi.org/10.1007/978-3-642-22144-6_90
Published:
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-22143-9
Online ISBN: 978-3-642-22144-6
eBook Packages: Chemistry and Materials ScienceReference Module Physical and Materials ScienceReference Module Chemistry, Materials and Physics