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Agrochemical Formulations

  • Reference work entry

Synonyms

Colloid aspects of agrochemical formulations

Keywords

Agrochemicals; Controlled release; Emulsions; Interaction forces; Microemulsions; Microencapsulation; Surfactants; Suspensions; Suspoemulsions

Definition

Agrochemicals are formulated as emulsions, suspensions, microemulsions, and various controlled-release systems. Control of the interaction forces between the droplets or particles is essential in achieving the long-term physical stability of the formulation as well as optimum application. Various interaction forces must be considered: attractive van der Waals, repulsive electrostatic, or steric forces. Combination of these interaction forces results in various energy-distance curves that determine the state of the system on storage. It is necessary to control the various processes such as creaming or sedimentation, flocculation, Ostwald ripening, coalescence, and phase inversions. This requires the use of effective emulsifiers and dispersants. Methods must be designed to...

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References

  • Abeles F (1964) In: Passaglia E, Stromberg RR, Kruger J (eds) Ellipsometry in the measurement of surfaces and thin films. Nat Bur Stand Misc Publ 256

    Google Scholar 

  • Adam NK (1925) J Phys Chem 29:87

    CAS  Google Scholar 

  • Asakura A, Oosawa F (1954) J Chem Phys 22:1235; J Polymer Sci 93:183 (1958)

    Google Scholar 

  • Bahadir M, Pfister G (1990) Controlled release formulations of pesticides. In: Bowers WS, Ebing W, Martin D (eds) Controlled release, biochemical effects of pesticides and inhibition of plant pathogenic fungi. Springer, Berlin, pp 1–64

    Google Scholar 

  • Barnett KG, Cosgrove T, Vincent B, Burgess A, Crowley TL, Kims J, Turner JD, Tadros THF (1981) Disc Faraday Soc 22:283

    Google Scholar 

  • Batchelor GK (1972) J Fluid Mech 52:245

    Google Scholar 

  • Becher P (1987) In: Schick MJ (ed) Nonionic surfactants, vol 1, Surfactant science series. Marcel Dekker, New york

    Google Scholar 

  • Beetsman GB (1999) In: Scher HB (ed) Controlled-release delivery systems for pesticides. Marcel Dekker, New York

    Google Scholar 

  • Bijesterbosch BH (1987) Stability of solid/liquid dispersions. In: Tadros THF (ed) Solid/liquid dispersions. Academic, London

    Google Scholar 

  • Buestein BR, Hiliton CL (1982) Amphoteric surfactants. Marcel Dekker, NewYork

    Google Scholar 

  • Buscall R, Goodwin JW, Ottewill RH, Tadros TF (1982) J Colloid Interface Sci 85:78

    CAS  Google Scholar 

  • Clunie JS, Ingram BT (1983) In: Parfitt GD, Rochester CH (eds) Adsorption from solution at the solid/liquid interface. Academic, London, p 105

    Google Scholar 

  • Cohen-Staurt MA, Fleer GJ, Bijesterbosch J (1982) Colloid Interface Sci 90:321

    Google Scholar 

  • Cohen-Stuart MA, Mulder JW (1985) Colloids and Surfaces 15:49

    Google Scholar 

  • Conner P, Ottewill RH (1971) J Colloid Interface Sci 37:642

    Google Scholar 

  • Cosgrove T, Crowley TL, Ryan T (1987) Macromolecules 20:2879

    CAS  Google Scholar 

  • Danielsson I, Lindman B (1983) Colloids Surf 3:391

    Google Scholar 

  • Davies JT (1959) Proc Int Congr Surf Act 1:426; Davies JT, Rideal (1961) Interfacial phenomena. Academic, NewYork

    Google Scholar 

  • Davies JT, Rideal EK (1969) Interfacial phenomena. Academic, New York

    Google Scholar 

  • Day RE, Greenwood FG, Parfitt GD 4th (1967) Int Congr Surface Active Subst 18:1005

    Google Scholar 

  • Debye P, Anaker EW (1951) J Phs Colloid Chem 55:644

    CAS  Google Scholar 

  • Deryaguin BV, Landau L (1941) Acta Physico Chem 14(633)

    Google Scholar 

  • Deryaguin BV, Scherbaker RL (1961) Kolloid Zh 23:33

    Google Scholar 

  • Dukhin SS, Kretzscmar G, Miller R (1995) Dynamics of adsorption at liquid interfaces. Elsevier, Amsterdam

    Google Scholar 

  • Elworthy PH, Florence AT, Macfarlane CB (1968) Solubilization by surface active agents. Cahpman and Hall, London

    Google Scholar 

  • Fischer EW (1958) Kolloid Z 160:120

    Google Scholar 

  • Fleer GJ, Cohen-Stuart MA, Scheutjens JMHM, Cosgrove T, Vincent B (1993) Polymers at interfaces. Chapman and Hall, London

    Google Scholar 

  • Flory PJ, Krigbaum WR (1950) J Chem Phys 18:1086

    CAS  Google Scholar 

  • Fontana BJ, Thomas JR (1961) J Phys Chem 65:480

    CAS  Google Scholar 

  • Friberg S, Jansson PO, Cederberg E (1976) J Colloid Interface Sci 55:614

    CAS  Google Scholar 

  • Fuerestenau DW (1971) In Hair ML (ed) The chemistry of biosurfaces. Marcel Dekker, New York, p 91

    Google Scholar 

  • Fuerstenau DW, Healy TW (1972) In: Lemlich R (ed) Adsorptive bubble seperation techniques. Academic, London, p 91

    Google Scholar 

  • Garvey MJ, Tadros THF, Vincent B (1974) J Colloid Interface Sci 49:57

    CAS  Google Scholar 

  • Garvey MJ, Tadros TF, Vincent B (1976) J Colloid Interface Sci 55:440

    CAS  Google Scholar 

  • Gaudin AM, Fuertsenau DW (1955) Trans AIME 202:958

    Google Scholar 

  • Gibbs JW (1928) Collected works, 1. Longman, New York, p 219

    Google Scholar 

  • Goodwin JW, Hughes R (2000) Rheology for chemsits. Royal Society of Chemistry Publication, Cambridge

    Google Scholar 

  • Greenwood FG, Parfitt GD, Picton NH, Wharton DG (1968) Adv Chem Ser No. 79:135

    CAS  Google Scholar 

  • Griffin WC (1949) J Cosmet Chemists 1:311; 5:249 (1954)

    Google Scholar 

  • Hamaker HC (1937) Physica 4:1058

    CAS  Google Scholar 

  • Harkins WD, Mattoon WD, Corrin ML (1946) J Am Chem Soc 68: 220; J Colloid Sci 1:105

    CAS  Google Scholar 

  • Hartley GS (1936) Aqueous solutions of paraffin chain salts. Hermann and Cie, Paris

    Google Scholar 

  • Healy TW (1974) J Macromol Sci Chem 118:603

    Google Scholar 

  • Hesselink FT, Vrij A, Overbeek JTG (1971) J Phys Chem 75:2094

    CAS  Google Scholar 

  • Higuchi WI, Misra J (1962) J Pharm Sci 51:459

    CAS  Google Scholar 

  • Hirst EL, McGilvary DI, Percival EG (1950) J Chem Soc:1297

    Google Scholar 

  • Hoar TP, Schulman JH (1943) Nature (London) 152:102

    CAS  Google Scholar 

  • Hoeve CA (1970) J Polym Sci 30: 361; (1971) 34:1

    Google Scholar 

  • Holmberg K, Jonsson B, Kronberg B, Lindman B (2003) Surfactants and polymers in solution, 2nd edn. Wiley, Chichester

    Google Scholar 

  • Hough DB, Randall HM (1983) In: Parfitt GD, Rochester CH (1983) Adsorption from solution at the solid/liquid interface. Academic, London, p 247

    Google Scholar 

  • Hunter RJ (1981) Zeta potential in colloid science; principles and applications. Academic, London

    Google Scholar 

  • Istraelachvili J (1985) Intermolecular and surface forces, with special applications to colloidal and biological systems. Academic, London, p 251

    Google Scholar 

  • Jungerman E (1970) Cationic surfactants. Marcel Dekker, NewYork

    Google Scholar 

  • Kabalanov AS, Shchukin ED (1992) Adv Colloid Interface Sci 38:69; Kabalanov AS (1994) Langmuir 10:680

    Google Scholar 

  • Killmann E, Eisenlauer E, Korn MJ (1977) Polymer Sci Polymer Symp 61:413

    CAS  Google Scholar 

  • Kloubek J, Friml K, Krejci F (1976) Check Chem Commun 41:1845

    CAS  Google Scholar 

  • Kondo A (1979) Microcapsule processing and technology. Marcel Dekker, NewYork

    Google Scholar 

  • Lifshitz IM, Slesov VV (1959) Sov Phys JETP 35:331

    Google Scholar 

  • Lindman B (1984) In: Tadros THF (ed) Surfactants. Academic, London. Holmberg K, Jonsson B, Kronberg B, Lindman B (2003) Surfactants and polymers in aqueous solution, 2nd edn. Wiley, New York

    Google Scholar 

  • Linfield WM (ed) (1967) Anionic surfactants. Marcel Dekker, New York

    Google Scholar 

  • Lucasses-Reynders EH (1994) Collids Sur A91:79

    Google Scholar 

  • Lucasssen-Reynders EH (1981) Anionic surfactants–- physical chemistry of surfactant action. Marcel Dekker, New York

    Google Scholar 

  • Lyklema J (1987) Structure of the solid/liquid interface and the electrical double layer. In: Tadros THF (ed) Solid/liquid dispersions. Academic, London

    Google Scholar 

  • Mackor EL, van der Waals JH (1951) J Colloid Sci 7:535

    Google Scholar 

  • McBain JW (1913) Trans Faraday Soc 9:99

    Google Scholar 

  • McBain JW (1950) Colloid science. Heath, Boston

    Google Scholar 

  • McCutcheon. Detergents and emulsifiers. Allied, New Jersey, published annually

    Google Scholar 

  • Miller R, Hoffmann A, Hartmann R, Schano KH, Halbig A (1992) Adv Mater 4:370

    CAS  Google Scholar 

  • Morgan PW, Kvolek SL (1947) J Polym Sci 2:90

    Google Scholar 

  • Mukerjee P, Mysels KJ (1971) Critical Micelle concentrations of aqueous surfactant systems. National Bureau of Standards Publication, Washington, DC

    Google Scholar 

  • Napper DH (1981) Polymeric stabilisation of colloidal dispersions. Academic, London

    Google Scholar 

  • Norrish K (1954) Disc Faraday Soc 18:120

    CAS  Google Scholar 

  • Ottewill RH (1987) Properties of concentrated suspensions. In: Taddros THF (ed) Solid/liquid dispersions. Academic, London

    Google Scholar 

  • Parfitt GD (1977) Dispersion of powders in liquid. Applied Science, London

    Google Scholar 

  • Park DJ, Jackson WR, McKinnon IR, Marshall M (1999) In: Scher HB (ed) Controlled-release delivery systems for pesticides. Marcel Dekker, New York

    Google Scholar 

  • Piirma I (1992) Polymeric surfactants, Surfactant science series, No.42. Marcel Dekker, NewYork

    Google Scholar 

  • Porter MR (1994) Handbook of surfactants. Chapman and Hall, Blackie

    Google Scholar 

  • Prince LM (1977) Microemulsion theory and practice. Academic, New York

    Google Scholar 

  • Pusey PN (1973) In: Green JHS, Dietz R (eds) Industrial polymers : characterisation by molecular weights. Transcripta Books, London

    Google Scholar 

  • Reynders L (1996) In: Becher P (ed) Encyclopedia of emulsion technolog. Marcel Dekker, NewYork

    Google Scholar 

  • Rideal EK (1922) Phil Mag 44:1152

    CAS  Google Scholar 

  • Robb ID, Smith R (1974) Eur Polym J 10:1005

    CAS  Google Scholar 

  • Roe RJ (1974) J Chem Phys 60:4192

    CAS  Google Scholar 

  • Rubingh N, Holland PM (eds) (1991) Cationic surfactants – physical chemistry. Marcel Dekker, NewYork

    Google Scholar 

  • Saleeb FZ, Kitchener JA (1965) J Chem Soc 911

    Google Scholar 

  • Scher HB (1999) Controlled-release delivery systems for pesticides. Marcel Dekker, New York

    Google Scholar 

  • Scheutjens JMHM, Fleer GJ (1979) J Phys Chem 83:1919

    Google Scholar 

  • Scheutjens JMHM, Fleer GJ (1980) J Phys Chem 84:178

    CAS  Google Scholar 

  • Scheutjens JMHM, Fleer GJ (1982) Adv Colloid Interface Sci 16:341

    Google Scholar 

  • Schick MJ (ed) (1966) Nonionic surfactants. Marcel Dekker, NewYork

    Google Scholar 

  • Schick MJ (ed) (1987) Nonionic surfactants: physical chemistry. Marcel Dekker, NewYork

    Google Scholar 

  • Schonfeldt N (1970) Surface active ethylene oxide adducts. Pergamon, Elmsford

    Google Scholar 

  • Shinoda K (1967) J Colloid Interface Sci 25:396

    Google Scholar 

  • Shinoda K, Saito H (1969) J Colloid Interface Sci 30:258

    CAS  Google Scholar 

  • Shinoda K, Nagakawa T, Tamamushi BI, Isemura T (1963) Colloidal surfactants, some physicochemical properties. Academic, London

    Google Scholar 

  • Silberberg A (1968) J Chem Phys 48:2835

    CAS  Google Scholar 

  • Smolders CA (1960) Rec Trav Chim 80:650

    Google Scholar 

  • Somasundaran P, Goddard ED (1979) Modern Aspects Electrochem 13:207

    CAS  Google Scholar 

  • Somasundaran P, Hannah HS (1979) In: Shah DO, Schechter RS (eds) Improved oil recovery by surfactant and polymer flooding. Academic, London, p 205

    Google Scholar 

  • Stevens CV, Meriggi A, Peristerpoulou M, Christov PP, Booten K, Levecke B, Vandamme A, Pittevils N, Tadros TF (2001) Biomacromolecules 2:1256

    CAS  Google Scholar 

  • Suzuki M (1993) In : Suzuki M, Chatterton NJ (eds) Science and technology of fructans. CRC Press, Boca Raton, p 21

    Google Scholar 

  • Tadros TF (1980) Adv Colloid Interface Sci 12:141

    CAS  Google Scholar 

  • Tadros ThF (1985) In: Buscall R, Corner T, Stageman JF (eds) Polymer colloids. Appl Sci London, Elsevier, p 105

    Google Scholar 

  • Tadros THF (1987) Solid/liquid dispersions. Academic, London

    Google Scholar 

  • Tadros TF (1994) Surfactants in agrochemicals. Marcel Dekker, New York

    Google Scholar 

  • Tadros TF (2005) Applied surfactants. Wiley-VCH, Germany

    Google Scholar 

  • Tadros T (2009) Colloids in agrochemicals. Wiley-VCH, Weinheim

    Google Scholar 

  • Tadros TH (2010) Rheology of dispersions. Wiley-VCH, Germany

    Google Scholar 

  • Tadros Th F (1973) In: Smith AL (ed) Particle growth in suspensions. Academic, London

    Google Scholar 

  • Tadros Th F (1983) In: Poehlein GW, Ottewill RH (eds) Science and technology of polymer colloids, vol II. Marinus Nish of Publishing, Boston

    Google Scholar 

  • Tadros Th F, Vincent B (1983) In: Becher P (ed) Encyclopedia of emulsion technology. Marcel Dekker, NewYork

    Google Scholar 

  • Tadros ThF, Booten K, Levecke B, Vandamme A to be published

    Google Scholar 

  • Tadros THF, Vincent B (1978) J Colloid Interface Sci 72:505

    Google Scholar 

  • Th.F. Tadros, "Polymer adsorption and Dispersion Stability", in "the Effect of Polymers on Dispersion Properties", Editor Th.F. Tadros, Academic Press, London (1981)

    Google Scholar 

  • Thompson (Lord Kelvin) W (1871) Phil Mag 42(448)

    Google Scholar 

  • van den Boomgaard T, King TA, Tadros THF, Tang H, Vincent B (1978) J Colloid Interface Sci 61:68

    Google Scholar 

  • van den Tempel M (1960) Proc Int Congr Surf Act 2:573

    Google Scholar 

  • van Olphen H (1963) Clay colloid chemistry. Wiley, New York

    Google Scholar 

  • van Os NM, Haak JR, Rupert LAM (1993) Physico-chemical properties of selected anionic, cationic and nonionic surfactants. Elsevier, Amsterdam

    Google Scholar 

  • Verwey EJW, Overbeek JTG (1948) Theory of stability of lyophobic colloids. Elsevier, Amsterdam

    Google Scholar 

  • von Smoluchowski (1914) Handbuch der Electricitat und des Magnetismus, vol II, Barth, Leipzig

    Google Scholar 

  • Wagner C (1961) Z Electrochem 35:581

    Google Scholar 

  • Wakamatsu T, Fuerstenau DW (1968) Adv Che Ser 71:161

    Google Scholar 

  • Walstra P (1983) In: Becher P (ed) Encyclopedia of emulsion technology, vol I. Marcel Dekker, New York

    Google Scholar 

  • Walstra P (1996) In: Becher P (ed) Encyclopedia of emulsion technology, vol 4. Marcel Dekker, NewYork

    Google Scholar 

  • Walstra P, Smolders PEA (1998) In: Binks BP (ed) Modern aspects of emulsions. The Royal Society of Chemistry, Cambridge

    Google Scholar 

  • Ward AFH, Tordai L (1946) J Phys Chem 14:453

    CAS  Google Scholar 

  • Washburn ED (1921) Phys Rev 17:273

    Google Scholar 

  • Whorlow RW (1980) Rheological techniques. Ellis Horwood, Chister

    Google Scholar 

  • Wilkins RM (ed) (1990) Controlled Delivery of Crop Protection Agents’. Taylor and Francis, London

    Google Scholar 

  • Woodford AR (1998) Dispersible granules. In: Van Valkenberg W, Sugavanan B, Khetan SK (eds) Pesticide formulation. UNIDO, Vienna, New Age International (P) Ltd., New Delhi, India, Chapter 9

    Google Scholar 

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Tadros, T. (2013). Agrochemical Formulations. In: Tadros, T. (eds) Encyclopedia of Colloid and Interface Science. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-20665-8_7

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