Abstract
The methods compiled in this chapter are important in many areas of materials science and technology because various physical properties of materials (mechanical, thermal, electronic, optical, magnetic, dielectric, biological) depend on their geometric architecture, on scales ranging from the atomic or nanoscopic to the semimicroscopic. Some of the properties are governed only by an elementary atomic group in the structural hierarchy while others are brought about by cooperative functioning of multiple phases or microscopic structures in different dimensions. Corresponding to the vast variety of materials and their properties, a wide range of experimental techniques are available, so that the choice of which technique to employ on starting a study may not be clear. In this respect one should also bear in mind that some of the techniques presented in this chapter are based on physical principles, which are also relevant to the measurement methods compiled in Chapts. 4 and 6.
Abbreviations
- AES:
-
Auger electron spectroscopy
- AFM:
-
atomic force microscopy
- CE:
-
capillary electrophoresis
- CE:
-
counter electrode
- CL:
-
cathodoluminescence
- CT:
-
compact tension
- DLTS:
-
deep level transient spectroscopy
- EBIC:
-
electron beam induced currents
- EELS:
-
electron energy-loss spectroscopy
- EPMA:
-
electron probe microanalysis
- FID:
-
flame ionization detector
- FID:
-
free-induction decay
- FT:
-
Fourier transform
- GC:
-
gas chromatography
- IR:
-
infrared region
- LC:
-
liquid chromatography
- NMR:
-
nuclear magnetic resonance
- PAC:
-
perturbed angular correlations
- PCR:
-
polymerase chain reaction
- PEELS:
-
parallel electron energy loss spectroscopy
- PL:
-
photoluminescence
- RF:
-
radiofrequency
- SEM:
-
scanning electron microscope
- SNOM:
-
scanning near-field optical microscopy
- STEM:
-
scanning transmission electron microscope
- STM:
-
scanning tunneling microscopes
- TEM:
-
transmission electron microscope
- TOF:
-
time-of-flight
- XPS:
-
X-ray photoelectron spectroscopy
- bcc:
-
body-centered cubic
- fcc:
-
face-centered cubic
References
A. Briggs, W. Arnold: Advances in Acoustic Microscopy (Plenum, New York 1995)
K. Sakai, T. Ogawa: Fourier-transformed light scattering tomography for determination of scatterer shapes, Meas. Sci. Technol. 8, 1090 (1997)
S. V. Gupta: Practical Density Measurement and Hydrometry (IOP, Bristol 2002)
Z. Alfassi: Activation Analysis, Vol. I & II (CRC, Boca Raton 1990)
A. Tonomura: Electron Holography (Springer, Berlin, Heidelberg 1999)
J. Shah: Ultrafast Spectroscopy of Semiconductors and Semiconductor Nanostructures (Springer, Berlin, Heidelberg 1996)
T. Wimbauer, K. Ito, Y. Mochizuki, M. Horikawa, T. Kitano, M. S. Brandt, M. Stutzmann: Defects in planar Si pn junctions studied with electrically detected magnetic resonance, Appl. Phys. Lett. 76, 2280 (2000)
L. V. Azároff: Elements of X-ray Crystallography (McGraw–Hill, New York 1968)
J. M. Cowley: Diffraction Physics (North-Holland, Amsterdam 1975)
B. D. Cullity: Elements of X-ray Diffraction (Addison–Wesley, Reading 1977)
A. Guinier: X-ray Diffraction in Crystals and Imperfect Crystals, Amorphous Bodies (Dover, New York 1994)
G. Rhodes: Crystallography Made Crystal Clear (Academic, San Diego 2000)
S. Bradbury: An Introduction to the Optical Microscope (Oxford Sci. Publ., Oxford 1989)
P. B. Hirsch, A. Howie, R. B. Nicholson, D. W. Pashley, M. J. Whelan: Electron Microscopy of Thin Crystals (Butterworths, London 1965)
D. B. Williams, C. B. Carter: Transmission Electron Microscopy (Plenum, New York 1996)
M. J. Whelan: Modern Diffraction and Imaging Techniques in Materials Science, ed. by S. Amelinckx, R. Gevers, G. Remaut, J. Van Landuyt (North-Holland, Amsterdam 1970) p. 35
C. E. Lyman, D. E. Newbury, J. I. Goldstein, D. B. Williams, A. D. Romig, Jr., J. T. Armstrong, P. Echlin, C. E. Fiori, D. C. Joy, E. Lifshin, K. Peters: Scanning Electron Microscopy, X-ray Microanalysis and Analytical Electron Microscopy (Plenum, New York 1990)
D. Bonnell (Ed.): Scanning Probe Microscopy and Spectroscopy (Wiley, Weinheim 2001)
B. Bhushan, H. Huchs, S. Hosaka (Eds.): Applied Scanning Probe Methods (Springer, Berlin, Heidelberg 2004)
K. S. Birdi: Scanning Probe Microscopes (CRC, Boca Raton 2003)
V. J. Morris, A. R. Kirby, A. P. Gunning: Atomic Force Microscopy for Biologists (Imperial College Press, London 1999)
S. Morita, R. Wiesendanger, E. Meyer: Noncontact Atomic Force Microscopy (Springer, Berlin, Heidelberg 2002)
M. Ohtsu: Near-Field Nano-Atom Optics and Technology (Plenum, New York 1999)
M. K. Miller, G. D. W. Smith: Atom Probe Microanalysis (Materials Research Society, Pittsburgh 1989)
S. Morita, N. Oyabu: Atom selective imaging and mechanical atom manipulation based on noncontact atomic force microscope method, e-J.Surf. Sci. Technology 1, 158 (2003)
D. Attwood: Soft X-rays and Extreme Ultraviolet Radiation (Cambridge Univ. Press, Cambridge 1999)
H. Kusmany: Solid State Spectroscopy (Springer, Berlin, Heidelberg 1998) p. 210
M. Fleischman, P. J. Hendra, A. J. McQuillan: Raman-spectra of pyridine adsorbed at a silver electrode, Chem. Phys. Lett. 26, 163 (1974)
D. L. Feldheim, C. A. Foss, Jr.: Metal Nanoparticles (Marcel Dekker, New York 2002)
G. Bricogne: Maximum-entropy and the foundations of direct methods, Acta Cryst. A 40, 410 (1984)
R. Kitaura, S. Kitagawa, Y. Kubota, T. C. Kobayashi: Formation of a one-dimensional array of oxygen in a microporous metal-organic solid, Science 298, 2358 (2002)
R. B. Von Dreele: Combined Rietveld and stereochemical restraint refinement of a protein crystal structure, J. Appl. Cryst. 32, 1084 (1999)
M. Ito, H. Narumi, T. Mizoguchi, T. Kawamura, H. Iwasaki, and, N. Shiotani: Structural change of amorphous Mg70Zn30 alloy under isothermal annealing, J. Phys. Soc. Jpn. 54, 1843 (1985)
S. R. P. Silva: Properties of Amorphous Carbon (INSPEC, London 2003)
P. Ehrhart, H. G. Haubold, W. Schilling: Festkörperprobleme XIV/ Advances in Solid State Physics, ed. by J. Queisser H. (Vieweg, Braunschweig 1974) p. 87
P. Ehrhart, H. G. Haubold, W. Schilling: Investigation of Point Defects and Their Agglomerates in Irradiated Metals by Diffuse X-ray Scattering. In: Festkörperprobleme XIV/Advances in Solid State Phys., ed. by H. J. Queisser (Vieweg, Braunschweig 1974)
A. Hida, Y. Mera, K. Maeda: Identification of arsenic antisite defects with EL2 by nanospectroscopic studies of individual centers, Physica B 308–310, 738 (2001)
P. M. Voyles, D. A. Muller, J. L. Grazul, P. H. Citrin, H.-J. L. Gossmann: Atomic-scale imaging of individual dopant atoms and clusters in highly n-type bulk Si, Nature 416, 826 (2002)
D. A. Muller, N. Nakagawa, A. Ohtomo, J. Grazul, H. Y. Hwang: Atomic-scale imaging of nanoengineered oxygen vacancy profiles in SrTiO3, Nature 430, 657 (2004)
F. Lüty: Physics of Color Centers, ed. by W. B. Fowler (Academic Press, New York 1968) p. 181
A. van der Ziel: Noise in Solid State Devices and Circuits (Wiley, New York 1986)
N. B. Lukyanchikova: Noise Research in Semiconductor Physics (Gordon Breach, Amsterdam 1996)
N. Fukata, T. Ohori, M. Suezawa, H. Takahashi: Hydrogen-defect complexes formed by neutron irradiation of hydrogenated silicon observed by optical absorption measurement, J. Appl. Phys. 91, 5831 (2002)
A. Hida: unpublished
J. P. Buisson, S. Lefrant, A. Sadoc, L. Taureland M. Billardon: Raman-scattering by KI containing F-centers, Phys. Stat. Sol. B 78, 779 (1976)
T. Sekiguchi, Y. Sakuma, Y. Awano, N. Yokoyama: Cathodoluminescence study of InGaAs/GaAs quantum dot structures formed on the tetrahedral-shaped recesses on GaAs (111)B substrates, J. Appl. Phys. 83, 4944 (1998)
G. D. Watkins: Radiation Damage in Semiconductors (Dunod, Paris 1964) p. 97
B. Henderson: Defects in Crystalline Solids (E Arnold, London 1972)
L. F. Mollenauer, S. Pan: Dynamics of the optical-pumping cycle of F centers in alkali halides-theory and application to detection of electron-spin and electron-nuclear-double-spin resonance in the relaxed-excited state, Phys. Rev. B 6, 772 (1972)
S. E. Barrett, R. Tycko, L. N. Pfeiffer, K. W. West: Directly detected Nuclear-Magnetic-Resonance of optically pumped GaAs quantum-wells, Phys. Rev. Lett. 72, 1368 (1994)
K. Morigaki: Spin-dependent radiative and nonradiative recombinations in hydrogenated amorphous silicon: Optically detected magnetic resonance, J. Phys. Soc. Jpn. 50, 2279 (1981)
A. Möslang, H. Graf, G. Balzer, E. Recknagel, A. Weidinger, T. Wichert, R. I. Grynszpan: Muon trapping at monovacancies in iron, Phys. Rev. B 27, 2674 (1983)
C. P. Slichter, D. Ailion: Low-field relaxation and the study of ultraslow atomic motions by magnetic resonance, Phys. Rev. 135, A1099 (1964)
P. Hautojärvi: Positrons in Solids (Springer, Berlin, Heidelberg 1979)
R. Krause-Rehberg, H. S. Leipner: Positron Annihilation in Semiconductors (Springer, Berlin, Heidelberg 1999)
M. J. Puska, C. Corbel: Positron states in Si and GaAs, Phys. Rev. B 38, 9874 (1988)
M. Hakala, M. J. Puska, R. M. Nieminen: Momentum distributions of electron-positron pairs annihilating at vacancy clusters in Si, Phys. Rev. B 57, 7621 (1998)
M. Hasegawa: private communication
M. Saito, A. Oshiyama: Lifetimes of positrons trapped at Si vacancies, Phys. Rev. B 53, 7810 (1996)
Z. Tang, M. Saito, M. Hasegawa: unpublished
H. Ohkubo, Z. Tang, Y. Nagai, M. Hasegawa, T. Tawara, M. Kiritani: Positron annihilation study of vacancy-type defects in high-speed deformed Ni, Cu and Fe, Mater. Sci. Eng. A 350, 95 (2003)
W. Triftshäuser, J. D. McGervey: Monovacancy formation energy in copper, silver, and gold by positron-annihilation, Appl. Phys. 6, 177 (1975)
R. O. Simmons, R. W. Balluffi: Measurements of equilibrium vacancy concentrations in aluminum, Phys. Rev. 117, 52 (1960)
M. Hasegawa, Z. Tang, Y. Nagai, T. Nonaka, K. Nakamura: Positron lifetime and coincidence Doppler broadening study of vacancy-oxygen complexes in Si: experiments and first-principles calculations, Appl. Surf. Sci. 194, 76 (2002)
S. Mantl, W. Triftshäuser: Defect annealing studies on metals by positron-annihilation and electrical-resistivity measurement, Phys. Rev. B 17, 1645 (1978)
M. Hasegawa, Z. Tang, Y. Nagai, T. Chiba, E. Kuramoto, M. Takenaka: Irradiation-induced vacancy and Cu aggregations in Fe-Cu model alloys of reactor pressure vessel steels: state-of-the-art positron annihilation spectroscopy, Philos. Mag. 85, 467 (2005)
T. Moriya, H. Ino, F. E. Fujita, Y. Maeda: Mössbauer effect in iron-carbon martensite structure, J. Phys. Soc. Jpn. 24, 60 (1968)
K. Nakagawa, K. Maeda, S. Takeuchi: Observation of dislocations in cadmium telluride by cathodoluminescence microscopy, Appl. Phys. Lett. 34, 574 (1979)
L. N. Pronina, S. Takeuchi, K. Suzuki, M. Ichihara: Dislocation-structures in rolled and annealed (001) [110] single-crystal molybdenum, Philos. Mag. A 45, 859 (1982)
M. J. Hÿtch, J. Putaux, J. Pénisson: Measurement of the displacement field of dislocations to 0.03 angstrom by electron microscopy, Nature 423, 270 (2003)
R. L. Snyder, J. Fiala, H. J. Bunge: Defect, Microstructure Analysis by Diffraction (Oxford Univ. Press, Oxford 1999)
G. Rhodes: Crystallography: A Guide for Users of Macromolecular Models, 2nd edn. (Academic, San Diego 2000)
Y. Akita: NMR in Proteins (Kyoritsu, Tokyo 1996)
K. Wüthrich: NMR of Proteins and Nucleic Acids (Wiley, New York 1986)
J. K. M. Sanders, B. K. Hunter: Modern NMR Spectroscopy (Oxford Univ. Press, Oxford 1993)
T. D. W. Claridge: High Resolution NMR Techniques in Organic Chemistry (Elsevier, Oxford 1999)
S. Weiss: Measuring conformational dynamics of biomolecules by single molecule fluorescence spectroscopy, Nature Struct. Biol. 7, 724 (2000)
V. Randle, O. Engler: Introduction to Texture Analysis (Taylor & Francis, London 2000)
D. C. Joy, D. E. Newbury, D. L. Davidson: Electron channeling patterns in the scanning electron-microscope, J. Appl. Phys. 53, R81 (1982)
K. Suenaga, T. Tence, C. Mori, C. Colliex, H: Kato, T. Okazaki, H.Shinohara, K. Hirahara, S. Bandow, S. Iijima: Element-selective single atom imaging, Science 290, 2280 (2000)
N. Hayazawa, A. Tarun, Y. Inouye, S. Kawata: Near-field enhanced Raman spectroscopy using side illumination optics, J. Appl. Phys. 92, 6983 (2002)
R. Snyder, J. Fiala, H. J. Bunge: Defect and Microstructure Analysis by Diffraction (Oxford Univ. Press, Oxford 1999)
B. D. Cullity: Elements of X-ray Diffraction, 2nd edn. (Addison–Wesley, Reading 1978)
M. E. Fitzpatrick, A. Lodini: Analysis of Residual Stress by Diffraction using Neutron and Synchrotron Radiation (CRC, Boca Raton 2004)
K. Hono: Nanoscale microstructural analysis of metallic materials by atom probe field ion microscopy, Prog. Mater. Sci. 47, 621 (2002)
H. Jinnai, Y. Nishikawa, T. Ikehara, T. Nishi: Emerging technologies for the 3D analysis of polymer structures, Adv. Polymer Sci. 170, 115 (2004)
A. Momose: Phase-contrast X-ray imaging based on interferometry, J. Synchrotron Rad. 9, 136 (2002)
A. Momose: Demonstration of phase-contrast X-ray computed tomography using an X-ray interferometer, Nucl. Instrum. Methods A 352, 622 (1995)
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Maeda, K., Mizubayashi, H. (2006). Nanoscopic Architecture and Microstructure. In: Czichos, H., Saito, T., Smith, L. (eds) Springer Handbook of Materials Measurement Methods. Springer Handbooks. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-30300-8_5
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