Abstract
In this chapter a mechanical method of porous silicon formation is described. By applying high-energy ball milling to polycrystalline silicon powder or single crystalline silicon wafers, highly dispersed and nanocrystalline silicon powders are produced. Pressing and sintering then lead to a porous matrix. The macroporous structures made in this way can then be permeated by meso- and micropores. The sinters have isotropic character of the pore distribution and morphology; this method is not limited by the wafer dimensions, and it is possible to make large-scale porous bodies, which is an advantage in comparison to lithographic methods.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Barraclough KG, Loni A, Caffull E, Canham LT (2007) Cold compaction of silicon powders without a binding agent. Mater Lett 61:485–487
Benjamin JS (1970) Dispersion strengthened superalloys by mechanical alloying. Metal Trans 1:2943–2951
Bollero A, Gutfleisch O, Kubis M, Müller K-H, Schultz L (2000) Hydrogen disproportionation by reactive milling and recombination of Nd2(Fe1-xCox)14B alloys. Acta Mater 48:4929–4934
Bychto L, Balaguer M, Pastor E, Chirvony V, Matveeva E (2008) Influence of preparation and storage conditions on photoluminescence of porous silicon powder with embedded Si nanocrystals. J Nanopart Res 10:1241–1249
Chakravarty D, Sarada BV, Chandrasekhar SB, Saravanan K, Rao TN (2011) A novel method of fabricating porous silicon. Mater Sci Eng A 528:7831–7834
Christophersen M, Merz P, Quenzer J, Carstensen J, Föll H (2001) Deep electrochemical trench etching with organic hydrofluoric electrolytes. Sens Actuator A 88:241–246
Coblenz WS (1990) The physics and chemistry of the sintering of silicon. J Mater Sci 25:2754–2764
De Castro CL, Mitchell BS (2002) Nanoparticles from mechanical attrition. In: Baraton M-I (ed) Synthesis, functionalization and surface treatment of nanoparticles. American Scientific Publisher, Stevenson Ranch
Diaz-Guerra C, Montone A, Piqueras J, Cardellini F (2002) Structural and cathodoluminescence study of mechanically milled silicon. Semicond Sci Technol 17:77–82
Gaffet E, Harmelin M (1990) Crystal-amorphous phase transition induced by ball-milling in silicon. J Less Common Met 157:201–222
Huang JY, Yasuda H, Mori H (1999) Deformation-induced amorphization in ball-milled silicon. Philos Mag Lett 79:305–314
Jakubowicz J, Jungblut H, Lewerenz HJ (2003) Initial surface topography changes during divalent dissolution of silicon electrodes. Electrochim Acta 49:137–146
Jakubowicz J, Smardz K, Smardz L (2007) Characterization of porous silicon prepared by powder technology. Physica E 38:139–143
Lang W, Steiner P, Sandmaier H (1995) Porous silicon: a novel material for microsystems. Sens Actuator A 51:31–36
Möller H-J, Welsch G (1985) Sintering of ultrafine silicon powder. J Am Ceram Soc 68(6):320–325
Odo EA, Britton DT, Gonfa GG, Harting M (2012) Structure and characterization of silicon nanoparticles produced using a vibratory disc mill. Afr Rev Phys 7:45–56
Parkhutik V (1999) Porous silicon – mechanism of growth and applications. Sol State Electron 43:1121–1141
Pawlak BJ, Gregorkiewicz T, Ammerlaan CAJ, Takkenberg W, Tichelaar FD, Alkemade PFA (2001) Experimental investigation of band structure modification in silicon nanocrystals. Phys Rev B 64:115308
Russo L, Colangelo F, Cioffi R, Rea I, De Stefano L (2011) A mechanochemical approach to porous silicon nanoparticles fabrication. Material 4:1023–1033
Saffie R, Barraclough KG, Lau Ch-H, Torabi-Pour N, Canham LT, Loni A (2005) Silicon structure. International Patent no WO2005/113467
Sailor MJ (2011) Porous silicon in practice, preparation, characterization and applications. Wiley, Weinheim
Santanav CJ, Jones KS (1996) The effects of processing conditions on the density and microstructure of hot-pressed silicon powder. J Mater Sci 31:4985–4990
Shen TD, Koch CC, McCormick TL, Nemanich RJ, Huang JY, Huang JG (1995) The structure and property characteristics of amorphous/nanocrystalline silicon produced by ball milling. J Mater Res 10:139–148
Stevulova N, Sepelak V, Tkacova K (1997) Mechanically induced transformation in silicon. Acta Montan Slovaca 3:261–265
Svrcek V, Rehspringeb J-L, Gaffec E, Slaoua A, Muller J-C (2005) Unaggregated silicon nanocrystals obtained by ball milling. J Cryst Growth 275:589–597
Unifantowicz P, Vaucher S, Lewandowska M, Kurzydlowski KJ (2008) Structural changes of silicon upon high-energy milling investigated by Raman spectroscopy. J Phys Condens Matter 20:025205
van Buuren T, Tiedje T, Patitsas SN (1994) Effect of thermal annealing on the conduction- and valence-band quantum shifts in porous silicon. Phys Rev B50:2719–2722
Yadav TP, Yadav RM, Singh DP (2012) Mechanical milling: a top down approach for the synthesis of nanomaterials and nanocomposites. Nanosci Nanotechnol 2(3):22–48
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2018 Springer International Publishing AG, part of Springer Nature
About this entry
Cite this entry
Jakubowicz, J. (2018). Porous Silicon Formation by Mechanical Means. In: Canham, L. (eds) Handbook of Porous Silicon. Springer, Cham. https://doi.org/10.1007/978-3-319-71381-6_9
Download citation
DOI: https://doi.org/10.1007/978-3-319-71381-6_9
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-71379-3
Online ISBN: 978-3-319-71381-6
eBook Packages: Chemistry and Materials ScienceReference Module Physical and Materials ScienceReference Module Chemistry, Materials and Physics