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Gallium

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Encyclopedia of Geochemistry

Part of the book series: Encyclopedia of Earth Sciences Series ((EESS))

FormalPara Element Data

Atomic Symbol: Ga

Atomic Number: 31

Atomic Weight: 69.723 ± 1 g/mol

Isotopes and Abundances: 69Ga 60.1%;71Ga 39.9%

1 Atm Melting Point: 29.8 °C

1 Atm Boiling Point: ~2,400 °C

Common Valences: +3

Ionic Radii Values: 47 pm (fourfold); 62 pm (sixfold)

Pauling Electronegativity: 1.81

First Ionization Energy: 174.6 kJ/mol

Chondritic (CI) Abundance: 9.5 ± 0.3 μg/g

Silicate Earth Abundance: 4.0 μg/g

Crustal Abundance: 17.5 μg/g

Seawater Abundance: ~1.2 pg/g

Core Abundance: <1 μg/g

Properties

Gallium does not occur as a native metal and forms very few minerals like gallite (CuGaS2), but widely occurs in nature as a trace constituent substituted for Al. Gallium metal is prepared as a by-product of aluminum production from bauxite ore and from Zn ores (e.g., sphalerite). Synthetically prepared metallic Ga is a soft, silvery white metal and has a melting point below human body temperature so it can be readily melted in one’s hand. Liquid gallium is one of a few substances...

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References

  • Benezeth P, Diakonov II, Pokrovski GS, Dandurand J-L, Schott J, Khodakovsky IL (1997) Gallium speciation in aqueous solution. Experimental study and modeling: part 2. Solubility of α-GaOOH in acidic solutions from 150 to 250°C and hydrolysis constants of gallium (III) to 300°C. Geochim Cosmochim Acta 61:1345–1357

    Article  Google Scholar 

  • Bennett R, Czechowski F (1980) Gallium porphyrins in bituminous coal. Nature 283:465–467

    Article  Google Scholar 

  • Blanchard I, Badro J, Siebert J, Ryerson FJ (2015) Composition of the core from gallium metal-silicate partitioning experiments. Earth Planet Sci Lett 427:191–201

    Article  Google Scholar 

  • Bowen HJM (1982) Chapter 12, Boron, aluminum, gallium, indium thallium. In: Environmental chemistry, vol 2. Royal Society of Chemistry, London, pp 159–161

    Chapter  Google Scholar 

  • Campbell AJ, Humayun M (2005) Compositions of group IVB iron meteorites and their parent melt. Geochim Cosmochim Acta 69:4733–4744

    Article  Google Scholar 

  • Chabot NL, Wollack EA, Humayun M, Shank EM (2015) The effect of oxygen as a light element in metallic liquids on partitioning behavior. Meteorit Planet Sci 50:530–546

    Article  Google Scholar 

  • Chitamber CR (2010) Medical applications and toxicities of gallium compounds. Int J Environ Res Public Health 7:2337–2361

    Article  Google Scholar 

  • Clayton DD (2003) Handbook of isotopes in the Cosmos: hydrogen to gallium. Cambridge University Press, Cambridge, UK. 326 pp

    Book  Google Scholar 

  • Davis FA, Humayun M, Hirschmann MM, Cooper RS (2013) Experimentally determined mineral/melt partitioning of first-row transition elements (FRTE) during partial melting of peridotite at 3 GPa. Geochim Cosmochim Acta 104:232–260

    Article  Google Scholar 

  • Diakonov II, Pokrovski GS, Benezeth P, Schott J, Dandurand J-L, Escalier J (1997) Gallium speciation in aqueous solution. Experimental study and modeling: part 1. Thermodynamic properties of Ga(OH)4− to 300°C. Geochim Cosmochim Acta 61:1333–1343

    Article  Google Scholar 

  • Dupre B, Viers J, Dandurand J-L, Polve M, Benezeth P, Vervier P, Braun J-J (1999) Major and trace elements associated with colloids in organic-rich river waters: ultrafiltration of natural and spiked solutions. Chem Geol 160:63–80

    Article  Google Scholar 

  • Goldstein JI, Scott ERD, Chabot NL (2009) Iron meteorites: crystallization, thermal history, parent bodies, and origin. Chem Erde 69:293–325

    Article  Google Scholar 

  • Gross JL, Thoennessen M (2012) Discovery of gallium, germanium, lutetium, and hafnium isotopes. At Data Nucl Data Tables 98:983–1002

    Article  Google Scholar 

  • Humayun M (2012) Chondrule cooling rates inferred from diffusive profiles in metal lumps from the Acfer 097 CR2 chondrite. Meteorit Planet Sci 47:1191–1208

    Article  Google Scholar 

  • Jenner FE, O’Neill HSC (2012) Analysis of 60 elements in 616 ocean floor basaltic glasses. Geochem Geophys Geosyst 13:Q02005. https://doi.org/10.1029/2011GC004009

    Article  Google Scholar 

  • Johnson K (2016) Periodic table of elements in the ocean. Monterey Bay Aquarium Research Institute. Available at http://www.mbari.org/science/upper-ocean-systems/chemical-sensor-group/periodic-table-of-elements-in-the-ocean. Accessed 18 Jan 2016

  • Kato C, Foriel J, Moynier F (2014) Isotopic study of gallium in terrestrial and meteoritic samples. In: 77th annual meeting of the Meteoritical Society, Abstract #5209

    Google Scholar 

  • Lodders K (2003) Solar system abundances and condensation temperatures of the elements. Astrophys J 591:1220–1247

    Article  Google Scholar 

  • McDonough WF, Sun S-S (1995) The composition of the Earth. Chem Geol 120:223–253

    Article  Google Scholar 

  • Mittlefehldt DW, McCoy TJ, Goodrich CA, Kracher A (1998) Non-chondritic meteorites from asteroidal bodies. In: Papike JJ (ed) Planetary materials, Reviews in mineralogy, vol 36. 195 pp

    Google Scholar 

  • Orians KJ, Bruland KW (1988) The marine geochemistry of dissolved gallium: a comparison with dissolved aluminum. Geochim Cosmochim Acta 52:2955–2962

    Article  Google Scholar 

  • Righter K, Campbell AJ, Humayun M (2005) Diffusion of trace elements in FeNi metal: applications to zoned metal grains in chondrites. Geochim Cosmochim Acta 69:3145–3158

    Article  Google Scholar 

  • Schulte RF, Foley NK (2013) Compilation of gallium resource data for bauxite deposits. US Geol Surv 004Fpen File Rep 2013–1272. https://pubs.usgs.gov/of/2013/1272/pdf/ofr2013-1272.pdf

  • Shiller AM, Frilot DM (1996) The geochemistry of gallium relative to aluminum in California streams. Geochim Cosmochim Acta 60:1323–1328

    Article  Google Scholar 

  • Wänke H, Palme H, Kruse H, Baddenhausen H, Cendales M, Dreibus G, Hofmeister H, Jagoutz E, Palme C, Spettel B, Thacker R (1976) Chemistry of lunar highland rocks: a refined evaluation of the composition of primary matter. Proc Lunar Sci Conf 7:3479–3499

    Google Scholar 

  • Wasson JT, Kallemeyn GW (1988) Compositions of chondrites. Philos Trans R Soc Lond A 325:535–544

    Article  Google Scholar 

  • Wasson JT, Huber H, Malvin DJ (2007) Formation of IIAB iron meteorites. Geochim Cosmochim Acta 71:760–781

    Article  Google Scholar 

  • Yang S, Humayun M, Righter K, Jefferson G, Fields D, Irving AJ (2015) Siderophile and chalcophile element abundances in shergottites: implications for Martian core formation. Meteorit Planet Sci 50:691–714

    Article  Google Scholar 

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Correspondence to Munir Humayun .

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Humayun, M. (2018). Gallium. In: White, W.M. (eds) Encyclopedia of Geochemistry. Encyclopedia of Earth Sciences Series. Springer, Cham. https://doi.org/10.1007/978-3-319-39312-4_246

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