Atomic symbol: Zr
Atomic number: 40
Atomic weight: 91.224
Isotopes and abundances: 90Zr, 51.45% 91Zr,
11.22%, 92Zr, 17.15%, 94Zr, 17.38%, 96Zr, 2.80%
1 Atm melting point: 1855 °C
1 Atm boiling point: 4371 °C
Common valences: 4+
Ionic radii: sixfold: 72 pm
Pauling electronegativity: 1.33
First ionization potential: 640 kJ/mol
Chondritic (CI) abundance: 3.63 ppm
Silicate Earth abundance: 10.3 ppm
Crustal abundance: 132 ppm
Seawater abundance: 9–300 pmol/kg
Core abundance: n/a
Properties
Zirconium is a transition metal of low toxicity with the atomic number of 41. Zirconium has five stable isotopes (90, 91, 92, 94, 96) with an atomic mass of 91.224(2) (CIAAW, 2015). The isotope 92Zr is the decay product of the now extinct 92Nb with a half-life of 34.7 Ma (e.g., Münker et al., 2000; Schönbächler et al., 2002; Iizuka et al., 2016). In some chondrites and CAIs , the neutron-rich isotope 96Zr is slightly enriched relative to other Zr isotopes, reflecting variable...
References
Akram, W., Schönbächler, M., Bisterzo, S., and Gallino, M., 2015. Zirconium isotope evidence for the heterogeneous distribution of s-process materials in the solar system. Geochimica et Cosmochimica Acta, 165, 484–500.
Barth, M. G., McDonough, W. F., and Rudnick, R. L., 2000. Tracking the budget of Nb and Ta in the continental crust. Chemical Geology, 165, 197–213.
Bau, M., 1996. Controls on the fractionation of isovalent trace elements in magmatic and aqueous systems: evidence from Y/Ho, Zr/Hf, and lanthanide tetrad effect. Contributions to Mineralogy and Petrology, 123, 323–333.
Bruland, K. W., Middag, R., and Lohan, M. C., 2014. Controls of trace metals in seawater. In Mottl, M. J., and Elderfield, H. (eds.), The Oceans and Marine Geochemistry. Amsterdam NL: Elsevier. Treatise on geochemistry, Vol. 8, pp. 19–51.
CIAAW (2015). Commission on Isotopic Abundances and Atomic Weights. http://ciaaw.org/atomic-weights.htm
David, K., Schiano, P., and Allègre, C. J., 2000. Assessment of the Zr/Hf fractionation in oceanic basalts and continental materials during petrogenetic processes. Earth and Planetary Science Letters, 178, 285–301.
Firdaus, M. L., Minami, T., Norisuye, K., and Sohrin, Y., 2011. Strong elemental fractionation of Zr-Hf and Nb-Ta across the Pacific Ocean. Nature Geoscience, 4, 227–230.
Foley, S., Tiepolo, M., and Vannucci, R., 2002. Growth of early continental crust controlled by melting of amphibolite in subduction zones. Nature, 417, 837–840.
Godfrey, L. V., White, W. M., and Salters, V. J. M., 1996. Dissolved zirconium and hafnium distributions across a shelf break in the northeastern Atlantic Ocean. Geochimica et Cosmochimica Acta, 60(21), 3995–4006.
Hermann, J., and Rubatto, D., 2009. Accessory phase control on the trace element signature of sediment melts in subduction zones. Chemical Geology, 265, 512–526.
Iizuka, T., Lai, Y. J., Akram, W., Amelin, Y., and Schönbächler, M., 2016. The initial abundance and distribution of 92Nb in the Solar System. Earth and Planetary Science Letters, 439, 172–181.
Klemme, S., Blundy, J. D., and Wood, B. J., 2002. Experimental constraints on major and trace element partitioning during partial melting of eclogite. Geochimica et Cosmochimica Acta, 66(17), 3109–3123.
Lodders, K., 2003. Solar system abundances and condensation temperatures of the elements. Astrophysical Journal, 591, 1220–1247.
McDade, P., Blundy, J. D., and Wood, B. J., 2003. Trace element partitioning on the Tinaquillo Lherzolite solidus at 1.5 GPa. Physics of the Earth and Planetary Interiors, 139, 129–147.
Münker, C., Weyer, S., Mezger, K., Rehkämper, M., Wombacher, F., and Bischoff, A., 2000. 92Nb-92Zr and the early differentiation history of planetary bodies. Science, 289, 1538–1542.
Münker, C., Pfänder, J. A., Weyer, S., Büchl, A., Kleine, T., and Mezger, K., 2003. Evolution of planetary cores and the Earth – moon system from Nb/Ta systematics. Science, 301, 84–87.
Palme, H., and O’Neill, H. St. C, 2014. Cosmochemical estimates of mantle composition. In Carlson, R. W. (ed.), The Mantle and Core. Amsterdam NL: Elsevier. Treatise on Geochemistry, Vol. 3, pp. 1–39.
Pearce, J. W., and Peate, D. W., 1995. Tectonic implications of the composition of volcanic arc magmas. Annual Review of Earth and Planetary Sciences, 23, 251–285.
Pfänder, J. A., Münker, C., Stracke, A., and Mezger, K., 2007. Nb/Ta and Zr/Hf in ocean island basalts - implications for crust-mantle differentiation and the fate of Niobium. Earth and Planetary Science Letters, 254(1-2), 158–172.
Pfänder, J. A., Jung, S., Münker, C., Stracke, A., and Mezger, K., 2012. A possible high Nb/Ta reservoir in the continental lithospheric mantle and consequences on the global Nb budget – evidence from continental basalts from Central Germany. Geochimica et Cosmochimica Acta, 77, 232–251.
Rudnick, R. L. and Gao, S., 2014. Composition of the continental crust. The Crust. Amsterdam NL: Elsevier. Treatise on Geochemistry, Vol. 4, pp. 1–51.
Schmidt, K., Bau, M., Hein, J. R., and Koschinsky, A., 2014. Fractionation of the geochemical twins Zr–Hf and Nb–Ta during scavenging from seawater by hydrogenetic ferromanganese crusts. Geochimica et Cosmochimica Acta, 140, 468–487.
Schönbächler, M., Rehkämper, M., Halliday, A. N., Lee, D. C., Bourot-Denise, M., Zanda, B., Hattendorf, B., and Günther, D., 2002. Niobium-zirconium chronometry and early solar sytem development. Science, 295, 1705–1708.
Shannon, R. D., 1976. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallographica, A32, 751–767.
USGS, (2014). http://minerals.usgs.gov/minerals/pubs/commodity/zirconium/mcs-2014-zirco.pdf
Zack, T., Kronz, A., Foley, S. F., and Rivers, T., 2002. Trace element abundances in rutiles from eclogites and associated garnet mica schists. Chemical Geology, 184, 97–122.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2016 Springer International Publishing AG
About this entry
Cite this entry
Münker, C. (2016). Zirconium. In: White, W. (eds) Encyclopedia of Geochemistry. Encyclopedia of Earth Sciences Series. Springer, Cham. https://doi.org/10.1007/978-3-319-39193-9_264-1
Download citation
DOI: https://doi.org/10.1007/978-3-319-39193-9_264-1
Received:
Accepted:
Published:
Publisher Name: Springer, Cham
Online ISBN: 978-3-319-39193-9
eBook Packages: Springer Reference Earth and Environm. ScienceReference Module Physical and Materials ScienceReference Module Earth and Environmental Sciences