Atomic Symbol: Ir
Atomic Number: 77
Atomic Weight: 192.217(3)
Isotopes and Abundances: 191Ir 37.3 ± 2 % and 193Ir 62.7 ± 2 %
Atm Melting Point: 2447 °C
1 Atm Boiling Point: 4428 °C
Common Valences: +3 and +4
Ionic Radii: 3+: 68 pm, 4+: 63 pm
Pauling Electronegativity: 2.20
First Ionization Energy: 880 kJ/mol
Chondritic (CI) Abundance: 462 μg/kg (Fischer-Gödde et al., 2010)
Silicate Earth Abundance: 3.5 μg/kg (Becker et al., 2006)
Crustal Abundance: 0.022 μg/kg (Park et al., 2012)
Seawater Abundance: 0.5 to 1 fmol/kg
Core Abundance: ~2.6 mg/kg (McDonough, 2014)
Properties
Iridium (77Ir) with the electron configuration [Xe] 4f 14 5d 7 6s 2 is a d-block transition element in the cobalt group (cobalt, rhodium, iridium, and meitnerium) and is one of the six platinum group elements (PGE) . The atomic radii of the Os, Ir, Pt subgroup, caused by the lanthanide contraction of the 4fgroup elements, are similar compared to the Ru, Rh, Pd subgroup of the PGE. The almost...
References
Alvarez, L. W., Alvarez, W., Asaro, F., and Michel, H. V., 1980. Extraterrestrial cause for the Cretaceous-Tertiary extinction. Science, 208, 1095–1108.
Becker, H., Horan, M. F., Walker, R. J., Gao, S., Lorand, J. P., and Rudnick, R. L., 2006. Highly siderophile element composition of the Earth’s primitive upper mantle: constraints from new data on peridotite massifs and xenoliths. Geochimica et Cosmochimica Acta, 70, 4528–4550.
Bruland, K. W., and Lohan, M. C., 2003. Controls of trace metals in seawater. In Elderfield, H. (ed.), The Oceans and Marine Geochemistry. Amsterdam: Elsevier Pergamon, Vol. 6, pp. 23–47.
Day, J. M. D., Brandon, A. D., and Walker, R. J 2016. Highly siderophile elements in earth, mars, the moon, and asteroids. In Day, J. M. D., and Harvey. J. (eds.), Highly Siderophile and Strongly Chalcophile Elements in High Temperature Geochemistry and Cosmochemistry. Chantilly/Virgina: Mineralogical Society of America, Vol. 81 pp. 161–238.
Fischer-Gödde, M., Becker, H., and Wombacher, F., 2010. Rhodium, gold and other highly siderophile element abundances in chondritic meteorites. Geochimica et Cosmochimica Acta, 74, 356–379.
Fritsche, J., and Meisel, T., 2004. Determination of anthropogenic input of Ru, Rh, Pd, Re, Os, Ir and Pt in soils along Austrian motorways by isotope dilution ICP-MS. The Science of the Total Environment, 325, 145–154.
Holser, W. T., Schönlaub, H.-P., Attrep, M. J., et al., 1989. A unique geochemical record at the Permian/Triassic boundary. Nature, 337, 39–44.
Hunt LB (1987) History of iridium. Platinum Metals Review 31:32–41.
McDonough, W. F., 2014. 3.16 – Compositional model for the Earth’s core A2. In Turekian, K. K., and Holland, H. D. (eds.), Treatise on Geochemistry, 2nd edn. Oxford: Elsevier, pp. 559–577.
Meisel, T., and Horan, M. F., 2016. Analytical methods for the HSE elements. In Day, J. M. D., and Harvey, J. (eds.), Highly Siderophile and Strongly Chalcophile Elements in High Temperature Geochemistry and Cosmochemistry. Chantilly/Virgina: Mineralogical Society of America, Vol. 81, pp. 89–106.
O’Driscoll. B., and González-Jiménez, J. M., 2016. An inventory and overview of natural occurrences of the platinum-group minerals (PGM) in extraterrestrial and terrestrial rocks. In Day, J. M. D., and Harvey, J. (eds.), Highly Siderophile and Strongly Chalcophile Elements in High Temperature Geochemistry and Cosmochemistry. Chantilly/Virgina: Mineralogical Society of America, Vol. 81, pp. 489–578.
Park, J.-W., Hu, Z., Gao, S., Campbell, I. H., and Gong, H., 2012. Platinum group element abundances in the upper continental crust revisited – new constraints from analyses of Chinese loess. Geochimica et Cosmochimica Acta, 93, 63–76.
Wang, K., Attrep, M. J., and Orth, C. J., 1993. Global iridium anomaly, mass extinction, and redox change at the Devonian-Carboniferous boundary. Geology, 21, 1071–1074.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2016 Springer International Publishing Switzerland
About this entry
Cite this entry
Meisel, T.C. (2016). Iridium. In: White, W. (eds) Encyclopedia of Geochemistry. Encyclopedia of Earth Sciences Series. Springer, Cham. https://doi.org/10.1007/978-3-319-39193-9_259-1
Download citation
DOI: https://doi.org/10.1007/978-3-319-39193-9_259-1
Received:
Accepted:
Published:
Publisher Name: Springer, Cham
Online ISBN: 978-3-319-39193-9
eBook Packages: Springer Reference Earth and Environm. ScienceReference Module Physical and Materials ScienceReference Module Earth and Environmental Sciences