Skip to main content

Iridium

  • Living reference work entry
  • First Online:
Encyclopedia of Geochemistry

Part of the book series: Encyclopedia of Earth Sciences Series ((EESS))

  • 436 Accesses

FormalPara Element Data

Atomic Symbol: Ir

Atomic Number: 77

Atomic Weight: 192.217(3)

Isotopes and Abundances: 191Ir 37.3 ± 2 % and 193Ir 62.7 ± 2 %

Atm Melting Point: 2447 °C

1 Atm Boiling Point: 4428 °C

Common Valences: +3 and +4

Ionic Radii: 3+: 68 pm, 4+: 63 pm

Pauling Electronegativity: 2.20

First Ionization Energy: 880 kJ/mol

Chondritic (CI) Abundance: 462 μg/kg (Fischer-Gödde et al., 2010)

Silicate Earth Abundance: 3.5 μg/kg (Becker et al., 2006)

Crustal Abundance: 0.022 μg/kg (Park et al., 2012)

Seawater Abundance: 0.5 to 1 fmol/kg

Core Abundance: ~2.6 mg/kg (McDonough, 2014)

Properties

Iridium (77Ir) with the electron configuration [Xe] 4f 14 5d 7 6s 2 is a d-block transition element in the cobalt group (cobalt, rhodium, iridium, and meitnerium) and is one of the six platinum group elements (PGE) . The atomic radii of the Os, Ir, Pt subgroup, caused by the lanthanide contraction of the 4fgroup elements, are similar compared to the Ru, Rh, Pd subgroup of the PGE. The almost...

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Institutional subscriptions

References

  • Alvarez, L. W., Alvarez, W., Asaro, F., and Michel, H. V., 1980. Extraterrestrial cause for the Cretaceous-Tertiary extinction. Science, 208, 1095–1108.

    Article  Google Scholar 

  • Becker, H., Horan, M. F., Walker, R. J., Gao, S., Lorand, J. P., and Rudnick, R. L., 2006. Highly siderophile element composition of the Earth’s primitive upper mantle: constraints from new data on peridotite massifs and xenoliths. Geochimica et Cosmochimica Acta, 70, 4528–4550.

    Article  Google Scholar 

  • Bruland, K. W., and Lohan, M. C., 2003. Controls of trace metals in seawater. In Elderfield, H. (ed.), The Oceans and Marine Geochemistry. Amsterdam: Elsevier Pergamon, Vol. 6, pp. 23–47.

    Google Scholar 

  • Day, J. M. D., Brandon, A. D., and Walker, R. J 2016. Highly siderophile elements in earth, mars, the moon, and asteroids. In Day, J. M. D., and Harvey. J. (eds.), Highly Siderophile and Strongly Chalcophile Elements in High Temperature Geochemistry and Cosmochemistry. Chantilly/Virgina: Mineralogical Society of America, Vol. 81 pp. 161–238.

    Google Scholar 

  • Fischer-Gödde, M., Becker, H., and Wombacher, F., 2010. Rhodium, gold and other highly siderophile element abundances in chondritic meteorites. Geochimica et Cosmochimica Acta, 74, 356–379.

    Article  Google Scholar 

  • Fritsche, J., and Meisel, T., 2004. Determination of anthropogenic input of Ru, Rh, Pd, Re, Os, Ir and Pt in soils along Austrian motorways by isotope dilution ICP-MS. The Science of the Total Environment, 325, 145–154.

    Article  Google Scholar 

  • Holser, W. T., Schönlaub, H.-P., Attrep, M. J., et al., 1989. A unique geochemical record at the Permian/Triassic boundary. Nature, 337, 39–44.

    Article  Google Scholar 

  • Hunt LB (1987) History of iridium. Platinum Metals Review 31:32–41.

    Google Scholar 

  • McDonough, W. F., 2014. 3.16 – Compositional model for the Earth’s core A2. In Turekian, K. K., and Holland, H. D. (eds.), Treatise on Geochemistry, 2nd edn. Oxford: Elsevier, pp. 559–577.

    Chapter  Google Scholar 

  • Meisel, T., and Horan, M. F., 2016. Analytical methods for the HSE elements. In Day, J. M. D., and Harvey, J. (eds.), Highly Siderophile and Strongly Chalcophile Elements in High Temperature Geochemistry and Cosmochemistry. Chantilly/Virgina: Mineralogical Society of America, Vol. 81, pp. 89–106.

    Google Scholar 

  • O’Driscoll. B., and González-Jiménez, J. M., 2016. An inventory and overview of natural occurrences of the platinum-group minerals (PGM) in extraterrestrial and terrestrial rocks. In Day, J. M. D., and Harvey, J. (eds.), Highly Siderophile and Strongly Chalcophile Elements in High Temperature Geochemistry and Cosmochemistry. Chantilly/Virgina: Mineralogical Society of America, Vol. 81, pp. 489–578.

    Google Scholar 

  • Park, J.-W., Hu, Z., Gao, S., Campbell, I. H., and Gong, H., 2012. Platinum group element abundances in the upper continental crust revisited – new constraints from analyses of Chinese loess. Geochimica et Cosmochimica Acta, 93, 63–76.

    Article  Google Scholar 

  • Wang, K., Attrep, M. J., and Orth, C. J., 1993. Global iridium anomaly, mass extinction, and redox change at the Devonian-Carboniferous boundary. Geology, 21, 1071–1074.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Thomas C. Meisel .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2016 Springer International Publishing Switzerland

About this entry

Cite this entry

Meisel, T.C. (2016). Iridium. In: White, W. (eds) Encyclopedia of Geochemistry. Encyclopedia of Earth Sciences Series. Springer, Cham. https://doi.org/10.1007/978-3-319-39193-9_259-1

Download citation

  • DOI: https://doi.org/10.1007/978-3-319-39193-9_259-1

  • Received:

  • Accepted:

  • Published:

  • Publisher Name: Springer, Cham

  • Online ISBN: 978-3-319-39193-9

  • eBook Packages: Springer Reference Earth and Environm. ScienceReference Module Physical and Materials ScienceReference Module Earth and Environmental Sciences

Publish with us

Policies and ethics