Definition
The unified atomic mass unit , u, is defined as 1/12th of the rest mass of a neutral atom of 12C in its nuclear and electronic ground state. Avogadro’s constant, N A, is the number of atoms in a mole of substance, where mole, denoted mol, is defined as the amount of substance that contains as many elementary entities as there are atoms in 0.012 kg of carbon-12.
Unified Atomic Mass Unit
The nineteenth-century chemists had two different standards for atomic weight values: hydrogen = 1, as chosen and quoted by John Dalton (1805), and oxygen = 16, as suggested by Brauner (1889) and the German Atomic Weights’ Committee (Ostwald, 1903) because oxygen was a primary measurement standard. At the start of the twentieth century, chemists (Landolt et al., 1900) voted for oxygen =16. The physicist, Francis Aston, who was using a mass spectrometer to determine mass ratios of isotopes (nuclides), used the stable isotope 16O = 16 as a standard. With the discovery (Giaugue and Johnson, 1929a...
References
Avogadro, A., 1811. Essai d’une maniere de determiner les masses relatives des molecules elementaires des corps, et les proportions selon lesquelles elles entrent dans ces combinaisons. Journal de Physique, 73, 58–76.
Brauner, B., 1889. Die basis atomgewichte. Berichte Der Deutschen Chemischen Gesellschaft, 22, 1186–1892.
Dalton, J., 1805. On the absorption of gases by water and other liquids. Memories and Proceeding of the Manchester Literary and Philosophical Society, 1, 271–287.
Dole, M., 1935. The relative atomic weight of oxygen in water and in air. Journal of the American Chemical Society, 57, 2731.
Giaugue, W. F., and Johnson, H. L., 1929a. An atom of oxygen, mass 18. Nature, 123, 318.
Giaugue, W. F., and Johnson, H. L., 1929b. An isotope of oxygen of mass 17 in the earth’s atmosphere. Nature, 123, 831.
Holden, N. E., 1984. The International Commission on Atomic Weights – an early historical review. Chemistry International, 6(1), 5–12.
Landolt, H., Ostwald, W., and Seubert, K., 1900. Zweiter Bericht der Commission fur die Festsetzung der Atomgewichte. Berichte Der Deutschen Chemischen Gesellschaft, 33, 1847–1883.
Ostwald, W., 1903. Bemerkungen zu dem Berichte der internationalen Atomgewichtskommission. Zeitschrift für Anorganische Chemie, 34, 257–259.
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Holden, N.E. (2016). Unified Atomic Mass Unit, Avogadro Constant, and Mole. In: White, W. (eds) Encyclopedia of Geochemistry. Encyclopedia of Earth Sciences Series. Springer, Cham. https://doi.org/10.1007/978-3-319-39193-9_233-1
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