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Handbook of Sol-Gel Science and Technology pp 1375–1397Cite as

Structural Characterization of Hybrid Organic–Inorganic Materials

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Abstract

Organic–inorganic sol-gel hybrid materials (OIHM) possess a high variability in configurations and arrangements of the organic and inorganic components, whose interaction can be mainly regulated through different weak or strong iono-covalent bonds. They can be prepared employing organically modified alkoxides which contain one or more covalent bonds, not cleaved during the sol-gel process and whose organic groups modify the inorganic network or undergo polymerization. Also, organic–inorganic mesostructured and mesoporous hybrid materials are synthesized by cooperative self-assembly in the presence of amphiphilic molecules acting as a supramolecular template. As these materials can have a broad possible structural configuration, the combined use of different analytical techniques is essential to given a quite deep understanding of their structure: solid state NMR spectroscopy and the vibrational spectroscopies will be considered hereafter, whose complementary use provided has been demonstrated highly significant to describe HOIM structure.

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Author information

Authors and Affiliations

  1. Laboratory of Materials Science and Nanotechnology, LMNT – D.A.D.U., University of Sassari and CR-INSTM, Palazzo Pou Salit, Piazza Duomo 6, 07041, Alghero, Sassari, Italy

    Plinio Innocenzi

  2. Department of Industrial Engineering, University of Padova, Via Marzolo 9, 35131, Padova, Italy

    Giovanna Brusatin

  3. Dipartimento di Ingegneria Industriale, Università di Padova, Padova, Italy

    Massimo Guglielmi

  4. l’Institut des Matériaux de Paris-Centre, Paris, France

    Florence Babonneau

Authors
  1. Plinio Innocenzi
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  2. Giovanna Brusatin
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  3. Massimo Guglielmi
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  4. Florence Babonneau
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Corresponding author

Correspondence to Plinio Innocenzi .

Editor information

Editors and Affiliations

  1. Materials Science and Engineering, Rutgers University, Piscataway, NJ, USA

    Lisa Klein

  2. Instituto de Cerámica y Vidrio, Consejo Superior de Investigaciones Científicas (CSIC), Madrid, Spain

    Mario Aparicio

  3. Department of Chemistry, Lehman College, The City University of New York, Bronx, NY, USA

    Andrei Jitianu

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Innocenzi, P., Brusatin, G., Guglielmi, M., Babonneau, F. (2018). Structural Characterization of Hybrid Organic–Inorganic Materials. In: Klein, L., Aparicio, M., Jitianu, A. (eds) Handbook of Sol-Gel Science and Technology. Springer, Cham. https://doi.org/10.1007/978-3-319-32101-1_36

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