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Process Intensification

  • Anna Lee Tonkovich
  • Eric Daymo
Living reference work entry

Abstract

Process intensification is a broad technology category with the objective to reduce size and/or improve efficiency of chemical or biotechnology processes. This objective can be achieved in many ways, including shrinking equipment size, combining unit operations, and changing the method of operation (e.g., energy sources, process control, reaction routes, solvents, etc.). Many process intensification approaches rely on heat transfer equipment, either as a unit operation with reduced size (e.g., compact heat exchanger) or as an integrated component of a multifunctional unit operation (e.g., microreactors and heat-integrated distillation). In this chapter, applications of heat transfer equipment in process intensification are surveyed, with the notable exception that compact heat exchangers are explicitly addressed in the chapter entitled “Compact Heat Exchangers.” Specifically, this chapter is an overview of process-intensified heat transfer equipment, including microchannel and other process-intensified heat exchangers, compact reactors, and heat-integrated separations. The discussion on applications is followed by a commercial outlook for heat transfer equipment in process-intensified systems.

References

  1. Application note (2016) Fast scale up of microreactor technology from lab scale to production, No. 1 The Paal-Knorr synthesis, 2016. http://www.access2flow.com/?Technology. Accessed on 4 Apr 2016
  2. Anuar S, Villegas C, Mugo SM, Curtis JM (2011) The development of flow-through bio-catalyst microreactors from silica micro structured fibers for lipid transformations. Lipids 46(6):545–555CrossRefGoogle Scholar
  3. Barad S, Makwana M (2014) Numerical investigation of single phase fluid flow and heat transfer in rectangular micro channel using nanofluids as a cooling liquid. Int J Eng Res App 4(8):133–137Google Scholar
  4. Bell I, Groll E (2011) Air-side particulate fouling of microchannel heat exchangers: experimental comparison of air-side pressure drop and heat transfer with plate-fin heat exchanger. App Ther Eng 31:742–749CrossRefGoogle Scholar
  5. Bergles A (1998) Techniques to enhance heat transfer. In: Rohsenow W, Hartnett J, Cho Y (eds) Handbook of heat transfer, 3rd edn. McGraw Hill, New York, pp 11.1–11.76Google Scholar
  6. Bianco V, Manca O, Nardini S, Vafai K (2015) Heat transfer enhancement with nanofluids. CRC Press, Boca RatonCrossRefGoogle Scholar
  7. Brandner JJ, Benzinger W, Schygulla U, Zimmermann S, Schubert K (2007) Metallic micro heat exchangers: properties, applications and long term stability. In: Müller-Steinhagen H, Malayeri MR, Watkinson AP (eds) Proceedings of 7th international conference on heat exchanger fouling and cleaning – challenges and opportunities, Tomar, 1–6 July 2007. ECI symposium series, vol RP5. Engineering conferences international, New YorkGoogle Scholar
  8. Brooks KP, Rassat SD, TeGrotenhuis WE (2005) Development of a microchannel in situ propellant production system, PNNL-15456. Pacific Northwest National Laboratory, RichlandGoogle Scholar
  9. Charpentier JC (2007) In the frame of globalization and sustainability, process intensification, a path to the future of chemical and process engineering (molecules into money). Chem Eng J 134:84–92CrossRefGoogle Scholar
  10. Chen J, Xu D (2015) Radical quenching of methane-air premixed flame in microreactors using detailed chemical kinetics. Sci Study Res 16(3):215–227Google Scholar
  11. Chughtai I, Iqbal W, Din G, Mehdi S, Khan I, Inayat M, Jin J (2013) Investigation of liquid phase axial dispersion in Taylor bubble flow by radiotracer residence time distribution analysis. EPJ Web Conf 50:01002-1–01002-4CrossRefGoogle Scholar
  12. de Rijke A (2007) Development of a concentric internally heat integrated distillation column (HIDiC) Dissertation, Technische Universiteit DelftGoogle Scholar
  13. Deutschmann O, Tischer S, Correa C, Chatterjee D, Kleditzsch S, Janardhanan VM, Mladenov N, Minh HD, Karadeniz H, Hettel M (2014) DETCHEM software package, 2.5 edn. www.detchem.com, Karlsruhe
  14. Ding YL, Chen HS, Wang L, Yang CY, He YR, Yang W, Lee WP, Zhang LL, Huo R (2007) Heat transfer intensification. Kona-Powder Part 25:23–28CrossRefGoogle Scholar
  15. Dizaji H, Jafarmadar S (2014) Heat transfer enhancement due to air bubble injection into a horizontal double pipe heat exchanger. Intl J Automot Eng 4:902–910Google Scholar
  16. Fanelli M, Arora R, Glass A, Litt R, Qiu D, Silva L, Tonkovich A, Weidert D (2007) Micro-scale distillation – I: simulation. WIT Trans Eng Sci 56:205–213CrossRefGoogle Scholar
  17. Glover WB (2004) Selecting evaporators for process applications. Chem Eng Progress Dec 2004:26–33Google Scholar
  18. Gourdon C, Elgue S, Prat L (2015) What are the needs for process intensification? Oil Gas Sci Technol 70(3):463–473CrossRefGoogle Scholar
  19. Guidat R, Vizza Abrial A (2015) Advanced flow reactor technology for continuous industrial production. Specialty Chemicals Magazine, Nov 2015, 30–32Google Scholar
  20. Gurav S (2013) Parametric comparison of heat transfer in helical and straight tube-in-tube heat exchanger. Intl J of Sci Res 4:990–993Google Scholar
  21. Gururatana S, Li X (2013) Heat transfer enhancement of small scale heat sinks using vibrating pin fin. Am J Appl Sci 10(8):801–809CrossRefGoogle Scholar
  22. Haenggi D, Meszaros I (1999) Vapour recompression: distillation without steam. Sulzer Technical Review 1 pp. 32–34Google Scholar
  23. Harmsen J (2010) Process intensification in the petrochemicals industry: drivers and hurdles for commercial implementation. Chem Eng Process 49:70–73CrossRefGoogle Scholar
  24. Hartman R, Jensen K (2009) Microchemical systems for continuous-flow synthesis. Lab Chip 9:2495–2507CrossRefGoogle Scholar
  25. Hettel M, Diehm C, Bonart H, Deutschmann O (2015) Numerical simulation of a structured catalytic methane reformer by DUO: the new computational interface for OpenFOAM and DETCHEM. Catal Today 258:230–240CrossRefGoogle Scholar
  26. Horval Rotary Heat Exchangers (2015) Handbook for design, installation and operation. http://www.hovalpartners.com. Accessed 3 May 2016
  27. Ill T, Knorr A, Fritzsche L (2016) Microreactors – a powerful tool to synthesize peroxycarboxylic esters. Molecules 21(1):5–21CrossRefGoogle Scholar
  28. Ismail F, Rashid A, Mahbub M (2011) CFD analysis for optimum thermal design of a carbon nanotube based micro-channel heatsink. Eng J 15(4):11–22CrossRefGoogle Scholar
  29. Ismail M, Fotowat S, Fartaj A (2016) Numerical simulation of Al2O3/automatic transmission fluid and Al2O3/water nanofluids in a compact heat exchanger. J Fluid Flow Heat Mass Transf 3:34–43Google Scholar
  30. Iwakabe K, Nakaiwa M, Huang K, Matsuda K, Nakashini T, Ohmori T, Endo A, Yamamoto T (2006) An internally heat-integrated distillation column (HIDiC) in Japan. In: Distillation and absorption, Symposium series, vol 152. IChemE, RugbyGoogle Scholar
  31. Jahnisch K, Baerns M, Hessel V, Ehrfeld W, Haverkamp V, Lowe H, Wille C, Guber A (2000) Direct fluorination of toluene using elemental fluorine in gas/liquid microreactors. J Fluor Chem 105:117–128CrossRefGoogle Scholar
  32. Johnston A, Levy W (2006) Chemical reactor. US Patent 7,033,553 B2 filed Jan 25, 2001, issued Apr 25, 2006. Meggitt (UK) Limited (assignee)Google Scholar
  33. Kakaç S, Bergles A, Mayinger F, Yuncu H (1999) Heat transfer enhancements of heat exchangers. Kluwer Academic Publishers, DordrechtCrossRefGoogle Scholar
  34. Kakaç S, Liu H, Pramuanjaroenkij A (2012) Heat exchangers: selection, rating, and thermal design. CRC Press, Boca RatonMATHGoogle Scholar
  35. Kandlikar S, Garimella S, Li D, Colin S, King M (2014) Heat transfer and fluid flow in minichannels and microchannels. Butterworth-Heinemann, OxfordGoogle Scholar
  36. Kansha Y, Kishimoto A, Aziz M, Tsutsumi A (2012) Self-heat recuperation: theory and applications. In: Dr. Jovan Mitrovic (ed) Heat exchangers – basics design applications. InTech. ISBN:978–953–51-0278-6. Available from: http://www.intechopen.com/books/heat-exchangers-basics-design-applications/self-heat-recuperation-theory-and-applications
  37. Kazazi V, Ressegotti D (2015) Optimization of multiregion simulations of catalytic reactors: an application to the CH4 partial oxidation on Rh. MS thesis, Politenco di MilanoGoogle Scholar
  38. Kim T (2009) Micro power generation from micro fuel cell combined with micro methanol reformer. In: Takahata K (ed) Micro electronic and mechanical systems. Intech, RijekaGoogle Scholar
  39. Kirubadurai B, Rahman FS, Velmurugan P, Kumar S (2017) Effectiveness analysis of double pipe heat exchanger with curls band in various angles. J Appl Mech Eng 6(2):1–6Google Scholar
  40. Kiss A (2016) Process intensification: industrial applications. In: Segovia-Hernandez J, Bonilla-Petriciolet A (eds) Process intensification in chemical engineering: design optimization and control. Springer, ChamGoogle Scholar
  41. Kiss A, Olujic Z (2014) A review on process intensification in internally heat-integrated distillation columns. Chem Eng Proc: Process Intensification 86:125–144CrossRefGoogle Scholar
  42. Kiwi-Minsker L, Renken A (2005) Microstructured reactors for catalytic reactions. Catal Today 110:2–14CrossRefGoogle Scholar
  43. Kockmann N (2008) Transport phenomena in micro process engineering. Springer, BerlinGoogle Scholar
  44. Kumar S, Suresh S, Rajiv K (2012) Heat transfer enhancement by nano structured carbon nanotube coating. Intl J Sci Eng Res 3:1–5Google Scholar
  45. LaMont M, Tonkovich AY, Fitzgerald S, Neagle P (2006) Microchannel fouling mitigation: flow distribution and wall shear effects. In: Presentation at the 2006 Spring Meeting & 2nd Global Congress on Process Safety, OrlandoGoogle Scholar
  46. Lavric E (2008) Thermal performance of corning glass microstructures. In: ECI international conference and fluid flow in microscale, WhistlerGoogle Scholar
  47. Lee J, Gharagozloo P, Kolade B, Eaton J, Goodson K (2010) Nanofluid convection in microtubes. J Heat Transf 132:092401-1–092401-5Google Scholar
  48. Legay M, Gondrexon N, Le Person S, Boldo P, Bontemps A (2011) Enhancement of heat transfer by ultrasound: review and recent advances. Intl J Chem Eng., Article ID:670108Google Scholar
  49. Lam K, Sorensen E, Gavriilidis A (2013) Review on gas-liquid separations in microchannel devices. Chem Eng Res Des 91(10):1941–1953CrossRefGoogle Scholar
  50. Lerou JJ, Tonkovich AL, Silva L, Perry S, McDaniel J (2010) Microchannel reactor architecture enables greener processes. Chem Eng Sci 65:380–385CrossRefGoogle Scholar
  51. Luo L (2013) Intensification of adsorption process in porous media. In: Luo L (ed) Heat and mass transfer intensification and shape optimization. Springer, London, pp 19–44CrossRefGoogle Scholar
  52. Maranzana G, Perry I, Maillet D (2004) Mini- and micro-channels: influence of axial conduction in the walls. Int J Heat Mass Transf 47:3993–4004CrossRefMATHGoogle Scholar
  53. Marschewski J, Brechbühler R, Jung S, Ruch P, Michel B (2016) Significant heat transfer with herringbone-inspired microstructures. Int J Heat Mass Transf 95:755–764CrossRefGoogle Scholar
  54. Marshall J, Renjitham S (2014) Simulation of particulate fouling at a microchannel entrance region. Microfluid Nanofluid 18:253–265CrossRefGoogle Scholar
  55. Mathew J, Lai F (1995) Enhanced heat transfer in a horizontal channel with double electrodes. In: Industry applications conference. IEEE, PiscatawayGoogle Scholar
  56. Maxwell J (1873) A treatise on electricity and magnetism. Clarendon Press, OxfordMATHGoogle Scholar
  57. Meszaros I, Meili A (2002) Optimize distillation operations with ejectors. Hydrocarb Process 03:51–56Google Scholar
  58. Meili A, Meszaros I (1998) Successful application of heat pump assisted distillation. In: New thinking in distillation column hardware, 25 Mar 1998. IChemE Fluid Separation-Process Group, Aston UniversityGoogle Scholar
  59. Minkowycz W, Sparrow E, Abraham J (2013) Nanoparticle heat transfer and fluid flow, Advances in heat transfer, vol IV. CRC Press, Boca RatonGoogle Scholar
  60. Moreau M, Di Miceli RN, Le Sauze N, Cabassud M, Gourdon C (2015) Pressure drop and axial dispersion in industrial millistructured heat exchange reactors. Chem Eng Process 95:54–62CrossRefGoogle Scholar
  61. Muthuraman S (2013) Investigation of brazed plate heat exchangers with variable chevron angles. Amer J Eng Res 2(8):90–107Google Scholar
  62. Muscatello A, Santiago-Maldonado E, Gibson T, Devor R, Captain R (2011) Evaluation of Mars CO2 capture and gas separation technologies. http://ntrs.nasa.gov/archive/nasa/casi.ntrs.nasa.gov/20110015862.pdf. Accessed 19 May 2016
  63. Olujic Z, Fakhri F, de Rijke A, de Graauw J, Jansens P (2003) Internal heat integration – the key to an energy conserving distillation column. J Chem Technol Biotechnol 78:241–248CrossRefGoogle Scholar
  64. Ottewell S (2014) Reactive distillation: will a sea change occur? Chemical Processing Com, 28 Oct 2014Google Scholar
  65. Perry J, Kandlikar S (2008) Fouling and its mitigation in silicon microchannels used for IC chip cooling. Microfluid Nanofluid 5:357–371CrossRefGoogle Scholar
  66. Pfeifer P (2012) Application of catalysts to metal microreactor systems. In: Patel V (ed) Chemical kinetics. InTech. http://www.intechopen.com/books/chemical-kinetics/application-of-catalysts-to-metal-microreactor-systems. Accessed 24 May 2016
  67. Ratner D, Murphy E, Jhunjhunwala M, Snyder D, Jensen K, Seeberger P (2005) Microreactor-based reaction optimization in organic chemistry – glycosylation as a challenge. Chem Commun:578–580Google Scholar
  68. Reay D, Ramshaw C, Harvey A (2013) Process intensification, second edition: engineering for efficiency, sustainability, and flexibility. Butterworth-Heinemann, OxfordGoogle Scholar
  69. Roberge D, Gottsponer M, Eyholzer M, Kockmann N (2009) Industrial design, scale-up, and use of microreactors. Chem Today 27(4):8–11Google Scholar
  70. Rock KL, Judzis A, Almering MJ (2008) Cost effective solutions for reduction of benzene in gasoline. AM-08-04. National Petroleum & Refiners Association, WashingtonGoogle Scholar
  71. Sadeghi E, Bahrami M, Djilali N (2010) Estimation of Nusselt number in microchannels of arbitrary cross section with constant axial heat flux. Heat Transf Eng 31:666–674CrossRefGoogle Scholar
  72. Sandia National Laboratory (2016) The Sandia Cooler: a fundamental breakthrough in heat transfer technology for microelectronics. http://ip.sandia.gov. Accessed 3 May 2016
  73. Schnider C, Roberge D (2012) Industrial design, scale-up and use of microreactors. Specialty Chemicals Magazine, Nov 2012, 16–18Google Scholar
  74. Schwiedernoch R, Tischer S, Correa C, Deutschmann O (2003) Experimental and numerical study on the transient behavior of partial oxidation of methane in a catalytic monolith. Chem Eng Sci 58:633–642CrossRefGoogle Scholar
  75. Shen C, Johnstone H (1955) Gas-solid contact in fluidized beds. AICHE J 1:349–354CrossRefGoogle Scholar
  76. Silvestri C, Riccio M, Poelma R, Morana B, Vollebregt S, Santagata F, Irace A, Zhang GQ, Sarro P (2016) Thermal characterization of carbon nanotube foam using MEMS microhotplates and thermographic analysis. Nanoscale 8:8266–8275Google Scholar
  77. Stankiewicz AI, Moulijn J (2000) Process intensification: transforming chemical engineering. Chem Eng Prog Jan 2000:22–34Google Scholar
  78. Stankiewicz AI, Moulijn J (2004) Re-engineering the chemical processing plant. Marcel Dekker, New YorkGoogle Scholar
  79. Stief T, Langer OU, Schuber K (1999) Numerische untersuchungen zur optimalen wärmeleitfähigkeit in mikrowärmeübertragerstrukturen. Chem Ing Tech 70:1539–1544CrossRefGoogle Scholar
  80. Su Y, Chen G, Yuan Q (2011) Influence of hydrodynamics on liquid mixing during Taylor flow in a microchannel. AICHE J 58:1660–1670CrossRefGoogle Scholar
  81. Tanthapanichakoon W, Matsuyama K, Aoki N, Mae K (2006) Design of microfluidic slug mixing based on the correlation between a dimensionless mixing rate and a modified Peclet number. Chem Eng Sci 61:7386–7392CrossRefGoogle Scholar
  82. Tegrotenhuis W, Humble P, Seeney J (2012) Simulation of a high efficiency multi-bed adsorption heat pump. App Ther Eng 37:176–182CrossRefGoogle Scholar
  83. Tian M, Cheng L, Lin Y, Zhang G (2004) Heat transfer enhancement by crossflow-induced vibration. Heat Transf Asian Res 33(4):211–218CrossRefGoogle Scholar
  84. Tonkovich AY, Daymo EA (2009) Microreaction systems for large-scale production. In: Dietrich T (ed) Microchemical engineering in practice. Wiley, HobokenGoogle Scholar
  85. Tonkovich AL, Lerou JJ (2010) Microstructures on macroscale: microchannel reactors for medium and large-size processes. In: Cybulski A, Moulijn J, Stankiewicz A (eds) Novel concepts in catalysis and chemical reactors: improving the efficiency of the future. Wiley, WeinheimGoogle Scholar
  86. Tonkovich AY, Perry S, Wang Y, Qiu D, LaPlante T, Rogers W (2004) Microchannel process technology for compact methane steam reforming. Chem Eng Sci 59:4819–4824CrossRefGoogle Scholar
  87. Tonkovich A, Kuhlmann D, Rogers WA, McDaniel J, Fitzgerald S, Arora R, Yuschak T (2005) Microchannel technology scale-up to commercial capacity. Trans IChemE Part A Chem Eng Res Des 83(A6):634–639CrossRefGoogle Scholar
  88. Tonkovich AL, Jarosch K, Arora R, Silva L, Perry S, McDaniel J, Daly F, Litt B (2008) Methanol production FPSO plant concept using multiple microchannel unit operations. Chem Eng J 135S:S2–S8CrossRefGoogle Scholar
  89. United States Department of Energy (2009) Heat integrated distillation through use of microchannel technology. Industrial Technologies Program brochure. http://energy.doe.gov. Accessed 4 May 2016
  90. Ventola L, Robotti F, Dailameh M, Calignano F, Manfredi D, Chiavazzo E, Asinari P (2014) Rough surfaces with enhanced heat transfer for electronics cooling by direct metal laser sintering. Int J Heat Mass Transf 75:58–74Google Scholar
  91. Wang M, Lawal A, Stephenson P, Sidders J, Ramshaw C, Yeung H (2011) Post-combustion CO2 capture with chemical absorption: a state-of-the-art review. Chem Eng Res Des 89(9):1609–1624CrossRefGoogle Scholar
  92. Werner TM, Schmitt SC, Daymo EA, Wegeng RS (1999) Microchannel gasoline vaporizer unit manufacturing cost study, PNNL-12226. Pacific Northwest National Laboratory, RichlandGoogle Scholar
  93. Westphalen D, Roth K, Brodrick J (2006) Heat transfer enhancement. ASHRAE J 48:68–71Google Scholar
  94. Wibulswas P (1966). Laminar flow heat transfer in non-circular ducts. Thesis, Department of Mechanical Engineering, University College LondonGoogle Scholar
  95. Yao Y, Zhang X, Guo Y (2010) Experimental study on enhancement of water-water shell-and-tube heat exchanger assisted by power ultrasonic. In: International refrigeration and air conditioning conference, Purdue, Paper 1110. http://docs.lib.purdue.edu/iracc/1110
  96. Yeong KK, Gavriilidis A, Zapf R, Hessel V (2004) Experimental studies of nitrobenzene hydrogenation in a microstructured falling film reactor. Chem Eng Sci 59:3491–3494CrossRefGoogle Scholar
  97. Yu W, France D, Singh D, Routbort J, Timofeeva E, Smith R (2008) Nanofluids for thermal control. United States Department of Energy. http://www1.eere.energy.gov. Accessed 3 May 2016
  98. Zhang H, Chen G, Yue J, Yuan Q (2009) Hydrodynamics and mass transfer of gas-liquid flow in a falling film microreactor. AICHE J 55(5):1110–1120CrossRefGoogle Scholar
  99. Zheng F, Stenkamp VS, Tegrotenhuis W, Huang X, King D (2006) Microchannel distillation of JP-8 jet fuel for sulfur content reduction. 2006 AIChE annual meeting, San FranciscoGoogle Scholar
  100. Zoeller J (2004) Eastman chemical Company’s chemicals from coal program: the first quarter century. Catal Today 140:118–126CrossRefGoogle Scholar
  101. Zuber L, Sander S (2015) Developing intensified separation processes for the industry. AIChE, spring meeting – reactive and intensified distillation, Austin, Apr 2015Google Scholar

Copyright information

© Springer International Publishing AG 2017

Authors and Affiliations

  1. 1.Tonkomo LLCGilbertUSA

Section editors and affiliations

  • Yaroslav Chudnovsky
    • 1
  1. 1.Division of Energy Delivery and UtilizationGas Technology InstituteDes PlainesUSA

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