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Green Synthesis of Metal Oxide Nanomaterials and Photocatalytic Degradation of Toxic Dyes

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Handbook of Green and Sustainable Nanotechnology

Abstract

In the recent years, nanomaterials are widely used in various fields, such as environmental remediation processes, energy production, industries, and medicines, but the synthesis of nanomaterials using the conventional chemical methods has various adverse effects such as high energy consumption, environmental pollution, and health problems. To address these challenges, green synthetic methods can be applied in which plant extracts are used rather than the toxic chemical substances. Compared to the traditional chemical methods, green synthesis is more beneficial as it is environment-friendly, cost-effective, and biologically safe. In this review, we have discussed about the adverse effect of chemical synthetic methods on the environment. To protect the environment from the harsh chemicals, green synthetic methods can be applied for the synthesis of metal oxide nanoparticles. Here, we have mainly emphasized on the green synthesis of some metal oxide nanoparticles such as SnO2, ZnO, and CuO. In this procedure, extracts of various plant parts (such as fruits, leaf, root), microbes, and ionic liquids can be used as precursors. These “green” metal oxide nanoparticles exhibit high biocompatibility and low toxicity, which enables them for their wide applications in various fields such as environmental remediation processes and removal of various organic pollutants. This chapter also discussed the applications of green synthesized metal oxide nanoparticles in the photocatalytic degradation of various toxic dyes from water bodies. In the end, we have also discussed about the future perspective of green synthetic methods and photocatalytic applications of metal oxide nanoparticles.

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References

  • Abdelkader E, Nadija L, Rose-Noelle V (2016) Adsorption of Congo red azo dye on nanosized SnO2 derived from sol-gel method. Int J Ind Chem 7:53–70

    Google Scholar 

  • Abdullah N, Ismail NM, Nuruzzaman DM (2018) Characterization of tin oxide (SnO2) nano structures prepared by thermal oxidation. In AIP Conference Proceedings, AIP Publishing LLC 2035(1):070009

    Google Scholar 

  • Alhalili Z (2022) Green synthesis of copper oxide nanoparticles CuO NPs from Eucalyptus Globoulus leaf extract: adsorption and design of experiments. Arab J Chem 15:103739

    Article  CAS  Google Scholar 

  • Alharthi MN, Salam MA (2021) Green synthesis of zinc oxide nanoparticles by Ziziphus jujuba leaves extract: environmental application, kinetic and thermodynamic studies. J Phys Chem Solids 158:110237

    Article  CAS  Google Scholar 

  • Altuwirqi RM, Albakri AS, Jawhari H, Ganash EA (2020) Green synthesis of copper oxide nanoparticles by pulsed laser ablation in spinach leaves extract. Optik 219:165280

    Article  CAS  Google Scholar 

  • Amade M, Tan ZQ, Liu R, Liu JF (2015) Nanofluid of zinc oxide nanoparticles in ionic liquid for single drop liquid microextraction of fungicides in environmental waters prior to high performance liquid chromatographic analysis. J Chromatogr A 1395:7–15

    Google Scholar 

  • Archana P, Janarthanan B, Bhuvana S, Rajiv P, Sharmila S (2022) Concert of zinc oxide nanoparticles synthesized using Cucumis melo by green synthesis and the antibacterial activity on pathogenic bacteria. Inorg Chem Commun 137:109255

    Article  Google Scholar 

  • Asha S, Bessy TC, Joe Sherin JF, Vani CV, Kumar CV, Bindhu MR, Shanmugam SK, Al-Khattaf FS, Hatamleh AA (2022) Efficient photocatalytic degradation of industrial contaminants by Piper longum mediated ZnO nanoparticles. Environ Res 20815:112686

    Article  Google Scholar 

  • Avirdi E, Hooshmand SE, Sepahvand H, Vishwanathan V, Bahadur I, Katata-Seru LM, Varma RS (2022) Ionic liquids-assisted greener preparation of silver nanoparticles. Curr Opin Green Sustain Chem 33:100581

    Article  CAS  Google Scholar 

  • Badri A, Slimi S, Guergueb M, Kahri H, Mateos X (2021) Green synthesis of copper oxide nanoparticles using prickly pear peel fruit extract: characterization and catalytic activity. Inorg Chem Commun 134:109027

    Article  CAS  Google Scholar 

  • Begum S, Ahmaruzzaman M (2018a) Green synthesis of SnO2 quantum dots using Parkia speciosa Hassk pods extract for the evaluation of anti-oxidant and photocatalytic properties. J Photochem Photobiol B Biol 184:44–53

    Article  CAS  Google Scholar 

  • Begum S, Ahmaruzzaman M (2018b) Green synthesis of SnO2 nanoparticles loaded on activated carbon and its application as photocatalyst in the degradation of Alizarin Red S dye. Mater Today Proc 5:2314–2320

    Article  CAS  Google Scholar 

  • Begum S, Ahmaruzzaman M, Adhikari PP (2018) Ecofriendly bio-synthetic route to synthesize ZnO nanoparticles using Eryngium foetidum L. and their activity against pathogenic bacteria. Mater Lett 228:37–41

    Google Scholar 

  • Bhattacharjee A, Ahmaruzzaman M (2015a) A novel and green process for the production of tin oxide quantum dots and its application as a photocatalyst for the degradation of dyes from aqueous phase. J Colloid Interface Sci 448:130–139

    Article  CAS  Google Scholar 

  • Bhattacharjee A, Ahmaruzzaman M (2015b) A green and novel approach for the synthesis of SnO2 nanoparticles and its exploitation as a catalyst in the degradation of methylene blue under solar irradiation. Mater Lett 145:74–78

    Article  CAS  Google Scholar 

  • Bhattacharjee A, Ahmaruzzaman M (2018) Microwave assisted facile and green route for synthesis of CuO nanoleaves and their efficacy as a catalyst for reduction and degradation of hazardous organic compounds. J Photochem Photobiol A Chem 353:215–228

    Article  CAS  Google Scholar 

  • Buniyamin I, Akhir RM, Asli NA, Khusaimi Z, Rusop M (2022) Green synthesis of tin oxide nanoparticles by using leaves extract of Chromolaena Odorata: the effect of different thermal calcination temperature to the energy band gap. Mater Today Proc 48:1805–1809

    Google Scholar 

  • Cao G (2004) Nanostructures and nanomaterials: synthesis, properties and applications. J Am Chem Soc 126(44):14679

    Google Scholar 

  • Chakravarty R, Chakraborty S, Shukla R, Bahadur J, Ram R, Mazumder S, Dev Sarma H, Tyagi AK, Dash A (2016) Mechanochemical synthesis of mesoporous tin oxide: a new generation nanosorbent for 68 Ge/68 Ga generator technology. Dalton Trans 45(34):13361–13372

    Google Scholar 

  • Das SK, Dickinson C, Lafir F, Brougham DF, Marsili E (2012) Synthesis, characterization and catalytic activity of gold nanoparticles biosynthesized with Rhizopus oryzae protein extract. Green Chem 14:1322–1334

    Google Scholar 

  • Devi TB, Ahmaruzzaman M (2016) Bio-inspired sustainable and green synthesis of plasmonic Ag/AgCl nanoparticles for enhanced degradation of organic compound from aqueous phase. Environ Sci Pollut Res Int 23(17):17702–17714

    Article  CAS  Google Scholar 

  • Diallo AE, Rajendran MV, Maaza M (2016) Physical & enhanced photocatalytic properties of green synthesized SnO2 nanoparticles via Aspalathus linearis. J Alloys Compd 681:561–570

    Article  CAS  Google Scholar 

  • Ebrahimian J, Mohsennia M, Khayatkashani M (2020) Photocatalytic-degradation of organic dye and removal of heavy metal ions using synthesized SnO2 nanoparticles by Vitex agnus-castus fruit via a green route. Mater Lett 263:127255

    Article  CAS  Google Scholar 

  • Elango G, Roopan SM (2016) Efficacy of SnO2 nanoparticles toward photocatalytic degradation of methylene blue dye. J Photochem Photobiol B Biol 155:34–38

    Article  CAS  Google Scholar 

  • Elango G, Kumaran SM, Kumar SS, Muthuraja S, Roopan SM (2015) Green synthesis of SnO2 nanoparticles and its photocatalytic activity of phenolsulfonphthalein dye. Spectrochim Acta A Mol Biomol Spectrosc 145:176–180

    Article  CAS  Google Scholar 

  • Fabre E, Murshed SMS (2021) A review of the thermophysical properties and potential of ionic liquids for thermal applications. J Mater Chem A 9:15861–15879

    Google Scholar 

  • Fu L, Zheng Y, Ren Q, Wang A, Deng B (2015) Green biosynthesis of SnO2 nanoparticles by plectranthus amboinicus leaf extract their photocatalytic activity toward rhodamine B degradation. J Ovonic Res 11:21–26

    CAS  Google Scholar 

  • Garrafa-Galvez HE, Nava O, Soto-Robles CA, Vilchis-Nestor AR, Castro-Beltrán A, Luque PA (2019) Green synthesis of SnO2 nanoparticle using Lycopersicon esculentum peel extract. J Mol Struct 1197:354–360

    Article  CAS  Google Scholar 

  • Ghorbani HR, Mehr FP, Poor AK (2015) Extracellular synthesis of copper nanoparticles using culture supernatants of Salmonella typhimurium. Orient J Chem 31:527–529

    Article  Google Scholar 

  • Goharshadi EK, Abareshi M, Mehrkhah R, Samiee S, Moosavi M, Youssefi A, Nancarrow P (2011) Preparation, structural characterization, semiconductor and photoluminescent properties of zinc oxide nanoparticles in a phosphonium-based ionic liquid. Mater Sci Semicond Process 14(1):69–72

    Article  CAS  Google Scholar 

  • Gomathi E, Jayapriya M, Arulmozhi M (2021) Environmental benign synthesis of tin oxide (SnO2) nanoparticles using Actinidia deliciosa (Kiwi) peel extract with enhanced catalytic properties. Inorg Chem Commun 130:108670

    Article  CAS  Google Scholar 

  • Gur T, Meydan I, Seckin H, Bekmezci M, Sen F (2022) Green synthesis, characterization and bioactivity of biogenic zinc oxide nanoparticles. Environ Res 204:111897

    Google Scholar 

  • Honarmand M, Golmohammadi M, Naeimi A (2019) Biosynthesis of tin oxide (SnO2) nanoparticles using jujube fruit for photocatalytic degradation of organic dyes. Adv Powder Technol 30(8):1551–1557

    Article  CAS  Google Scholar 

  • Haritha E, Roopan SM, Madhavi G, Elango G, Abdullah N, Al-Dhabi AMV (2016) Green chemical approach towards the synthesis of SnO2 NPs in argument with photocatalytic degradation of diazo dye and its kinetic studies. J Photochem Photobiol B Biol 162:441–447

    Article  CAS  Google Scholar 

  • Imade EE, Ajiboye TO, Fadiji AE, Onwudiwe DC, Babalola O (2022) Green synthesis of zinc oxide nanoparticles using plantain peel extracts and the evaluation of their antibacterial activity. Scientific African 16:e01152

    Article  CAS  Google Scholar 

  • Jayachandran A, Aswathy TR, Nair AS (2021) Green synthesis and characterization of zinc oxide nanoparticles using Cayratia pedata leaf extract. Biochem Biophys Rep 26:100995

    CAS  Google Scholar 

  • Kaur H, Singh J, Rani P, Kaur N, Kumar S, Rawat M (2022) A novel and one-pot synthesis of Punica granatum mediated copper oxide having flower-like morphology as an efficient visible-light driven photocatalyst for degradation of textile dyes in waste water. J Mol Liq 1:118966

    Article  Google Scholar 

  • Kumar JA, Krithiga T, Manigandan S, Sathish S, Renita AA, Prakash P, Prasad BSN, Kumar TRP, Rajasimman M, Hosseini-Bandegharaei A, Prabu D, Crispin S (2021) A focus to green synthesis of metal/metal-based oxide nanoparticles: various mechanisms and applications towards ecological approach. J Clean Prod 324:129198

    Article  CAS  Google Scholar 

  • Kumar M, Mehta A, Mishra A, Singh J, Rawat M, Basu S (2018) Biosynthesis of tin oxide nanoparticles using Psidium Guajava leave extract for photocatalytic dye degradation under sunlight. Mater Lett 215:121–124

    Google Scholar 

  • Li X, Xu H, Chen ZS, Chen G (2011) Biosynthesis of nanoparticles by microorganisms and their applications. J Nanomater 2011:270974

    Google Scholar 

  • Luque PA, Garrafa-Galvez HE, Nava O, Olivas A, Martinez-Rosas ME, Vilchis-Nestor AR, Villegas-Fuentes A, Chinchillas-Chinchillas MJ (2021) Efficient sunlight and UV photocatalytic degradation of Methyl Orange, Methylene Blue and Rhodamine B, using Citrus paradisi synthesized SnO2 semiconductor nanoparticles. Ceram Int 47:23861–23874

    Google Scholar 

  • Mohanta D, Ahmaruzzaman M (2020) Addressing nanotoxicity: green nanotechnology for a sustainable future. The ELSI handbook of nanotechnology: risk, safety, ELSI and commercialization, Scrivener Publishing LLC, pp 103–112

    Google Scholar 

  • Manasa DJ, Chandrashekar KR, Madhu Kumar DJ, Niranjana M, Navada KM (2021) Mussaenda frondosa L. mediated facile green synthesis of copper oxide nanoparticles – characterization, photocatalytic and their biological investigations. Arab J Chem 14(6):103184

    Article  CAS  Google Scholar 

  • Mishra SR, Ahmaruzzaman M (2022) Tin oxide based nanostructured materials: synthesis and potential applications. Nanoscale 14:1566–1605

    Google Scholar 

  • Mishra S, Singh BR, Naqvi AH, Singh HB (2017) Potential of biosynthesized silver nanoparticles using Stenotrophomonas sp. BHU-S7 (MTCC 5978) for management of soil-borne and foliar phytopathogens. Sci Rep 7(1):1–15

    Article  Google Scholar 

  • Moisescu C, Steeve B, Dominique T, Ardelean I, Benning LG (2008) Controlled biomineralization of magnetite (Fe3O4) by Magnetospirillum gryphiswaldense. Mineral Mag 72(1):333–336

    Article  CAS  Google Scholar 

  • Ma J, Zhao M, Zhang C, Wu X, Yang G (2020) Synthesis of L. Acidissima mediated tin oxide nanoparticles for cervical carcinoma treatment in nursing care. J Drug Deliv Sci Technol 57:101745

    Article  CAS  Google Scholar 

  • Najjar M, Hosseini HA, Masoudi A, Sabouri Z, Mostafapour A, Khatami M, Darroudi M (2021) Green chemical approach for the synthesis of SnO2 nanoparticles and its application in photocatalytic degradation of Eriochrome Black T dye. Optik, Int J Light Electron Optics 242:167152

    Article  CAS  Google Scholar 

  • Nayak SS, Wadhawa GC, Shivankar VS, Patil DD, Sonawale MC, Mirgane NA (2021) Tin oxide plant assisted nanoparticle catalyzed green synthesis of imidazole derivatives. Mater Today Proc 37:2490–2494

    Article  CAS  Google Scholar 

  • Oskam G (2006) Metal oxide nanoparticles: synthesis, characterization and application. J Sol-Gel Sci Technol 37:161–164

    Article  CAS  Google Scholar 

  • Prasad AR, Garvasis J, Oruvil SK, Joseph A (2019) Bio-inspired green synthesis of zinc oxide nanoparticles using Abelmoschus esculentus mucilage and selective degradation of cationic dye pollutants. J Phys Chem Solids 127:265–274

    Article  CAS  Google Scholar 

  • Park JK, Rupa EJ, Arif MH, Li JF, Anandapadmanaban G, PyoKang J, Chan Ahn MJ, Akter R, Yang DC, Kang SC (2021) Synthesis of zinc oxide nanoparticles from Gynostemma pentaphyllum extracts and assessment of photocatalytic properties through malachite green dye decolorization under UV illumination-a green approach. Optik 239:166249

    Article  CAS  Google Scholar 

  • Prakash S, Elavarasan N, Venkatesan A, Subashini K, Sowndharya M, Sujatha V (2018) Green synthesis of copper oxide nanoparticles and its effective applications in Biginelli reaction, BTB photodegradation and antibacterial activity. Advanced Powder Technology 29, 12:3315–3326

    Google Scholar 

  • Rademacher L, Beglau THY, Karakas Ö, Spieß A, Woschko D, Heinen T, Juri Barthel J, Janiak C (2022) Synthesis of tin nanoparticles on Ketjen Black in ionic liquid and water for the hydrogen evolution reaction. Electrochem Commun 136:10724

    Article  Google Scholar 

  • Rao SMA, Kotteeswaran S, Visagamani AM (2021) Green synthesis of zinc oxide nanoparticles from Camellia sinensis: organic dye degradation and antibacterial activity. Inorg Chem Commun 134:108956

    Article  Google Scholar 

  • Rehman S, Asiri SM, Khan FA, Jermy BR, Khan H, Akhtar S, Al JR, Khan KM, Qurashi A (2019) Biocompatible tin oxide nanoparticles: synthesis, antibacterial, anticandidal and cytotoxic activities. Chem Select 4(14):4013–4017

    CAS  Google Scholar 

  • Rambabu K, Bharath G, Banat F, Show PL (2021) Green synthesis of zinc oxide nanoparticles using Phoenix dactylifera waste as bioreductant for effective dye degradation and antibacterial performance in wastewater treatment. J Hazard Mater 402:123560

    Article  CAS  Google Scholar 

  • Rafique M, Shafiq F, Gillai SSA, Shakil M, Tahir MB, Sadaf I (2020) Eco-friendly green and biosynthesis of copper oxide nanoparticles using Citrofortunella microcarpa leaves extract for efficient photocatalytic degradation of Rhodamin B dye form textile wastewater. Optik 208:164053

    Article  CAS  Google Scholar 

  • Shukla M, Pal S, Sinha I (2022) Ionic liquid functionalized Cu2O nanoparticles. J Mol Struct 1262:132961

    Article  CAS  Google Scholar 

  • Srivastava N, Mukhopadhyay M (2013) Biosynthesis and structural characterization of selenium nanoparticles mediated by Zooglea ramigera. Powder Technol 244:26–29

    Article  CAS  Google Scholar 

  • Srivastava N, Mukhopadhyay M (2014) Biosynthesis of SnO2 nanoparticles using bacterium Erwinia herbicola and their photocatalytic activity for degradation of dyes. Ind Eng Chem Res 53:13971–13979

    Article  CAS  Google Scholar 

  • Sankar DH, Kumbhakar P, Mitra AK (2012) Optical properties of tin oxide nanoparticles prepared by laser ablation in water: influence of laser ablation time duration and laser fluence. Mater Charact 73:158–165

    Article  Google Scholar 

  • Shah IH, Ashraf M, Sabir IA, Manzoor MA, Malik MS, Gulzar S, Ashraf F, Iqbal J, Niu Q, Zhang Y (2022) Green synthesis and characterization of copper oxide nanoparticles using Calotropis procera leaf extract and their different biological potentials. J Mol Struct 1259:132696

    Article  CAS  Google Scholar 

  • Siddiqui VU, Ansari A, Chauhan R, Siddiqi WA (2021) Green synthesis of copper oxide (CuO) nanoparticles by Punica granatum peel extract. Mater Today Proc 36, 3:751–755

    Article  Google Scholar 

  • Singh BN, Rawat AKS, Khan W, Naqvi AH, Singh BR (2014) Biosynthesis of stable antioxidant ZnO nanoparticles by Pseudomonas aeruginosa rhamnolipids. PLoS One 9(9):e106937

    Article  Google Scholar 

  • Selvam K, Albasher G, Alamri O, Sudhakar C, Selvankumar T, Vijayalakshmi S, Vennila L (2022) Enhanced photocatalytic activity of novel Canthium coromandelicum leaves based copper oxide nanoparticles for the degradation of textile dyes. Environ Res 211:113046

    Article  CAS  Google Scholar 

  • Tripathi RM, Bhadwal AS, Gupta RK, Singh P, Shrivastav A, Shrivastav BR (2014) ZnO nanoflowers: novel biogenic synthesis and enhanced photocatalytic activity. J Photochem Photobiol B Biol 141:288–295

    Article  CAS  Google Scholar 

  • Vidovix TB, Quesada HB, Januário EFD, Bergamasco R, Vieira AMS (2019) Green synthesis of copper oxide nanoparticles using Punica granatum leaf extract applied to the removal of methylene blue. Mater Lett 257:126685

    Google Scholar 

  • Vidya C, Prabha MNC, Raj MALA (2016) Green mediated synthesis of zinc oxide nanoparticles for the photocatalytic degradation of Rose Bengal dye. Environ Nanotechnol Monit Manag 6:134–138

    Google Scholar 

  • Vasantharaj S, Sathiyavimal S, Saravanan M, Senthilkumar P, Gnanasekaran K, Manikandan MSE, Pugazhendhi A (2019) Synthesis of eco-friendly copper oxide nanoparticles for fabrication over textile fabrics: characterization of antibacterial activity and dye degradation potential. J Photochem Photobiol B Biol 191:143–149

    Google Scholar 

  • Wang D, Tejerina B, Lagzi I, Kowalczyk B, Grzybowski BA (2011) Bridging interactions and selective nanoparticle aggregation mediated by monovalent cations. ACS Nano 5:530–536

    Google Scholar 

  • Wang A, Liu Z, Li S, Liu Y, Zhao H, Liu Y, Ye T, Niu Y, Li W (2021) In-situ preparation and properties of copper nanoparticles/poly (ionic liquid) composites by click chemistry within surfactant-free ionic liquid microemulsions. J Mol Liq 342:117572

    Article  CAS  Google Scholar 

  • Yusof HM, Rosfarizan M, Uswatun HZ (2019) Microbial synthesis of zinc oxide nanoparticles and their potential application as an antimicrobial agent and a feed supplement in animal industry: a review. J Anim Sci Biotechnol 10:1–22

    Google Scholar 

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Bhattacharjee, B., Ahmaruzzaman, M. (2023). Green Synthesis of Metal Oxide Nanomaterials and Photocatalytic Degradation of Toxic Dyes. In: Shanker, U., Hussain, C.M., Rani, M. (eds) Handbook of Green and Sustainable Nanotechnology. Springer, Cham. https://doi.org/10.1007/978-3-031-16101-8_98

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