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Glaucamine

Reference work entry

CAS Registry Number: 2255-44-9 Open image in new window

Taxonomy: Physicochemical and Pharmacological Properties of Alkaloids – Isoquinoline Alkaloids

Biological sources: Papaver zangezuricum

C21H23NO6: 385.1525

Mp: 218–219°C (MeOH) [1]

[α]D+287° (CHCl3) [1]

UV: 232, 279 [1]

MSm/z: 385(M+), 206(100), 192, 190, 163 [2]

1H NMR: 2.25(3H, s, NCH3), 3.75(6H, s, 2 × OCH3), 3.91, 5.69(each 1H, d, J = 9), 5.88, 5.95(each 1H, d, J = 1, CH2O2), 5.90(1H, s), 6.20, 6.55(each 1H, s, p–H–Ar), 6.85(2H, s, o–H–Ar) [3]

ORD: [3]

References

  1. 1.
    R. Shakirov, M.V. Telezhenetskaya, I.A. Bessonova, S.F. Aripova, I.A. Israilov, M.N. Sultankhodzhaev, V.I. Akhmedzhanova, V.I. Vinogradova, T.S. Tulyaganov, B.T. Salimov, V.A. Tel’nov, Chem. Nat. Comp 32, 216 (1996)Google Scholar
  2. 2.
    L. Dolejs, V. Hanus, Collect. Czech. Chem. Commun. 23, 2997 (1967)Google Scholar
  3. 3.
    F. Santavy, J. Hrubek, K. Blaha, Collect. Czech. Chem. Commun. 23, 4452 (1967)Google Scholar

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© Springer Science+Business Media New York 2013

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