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Fumariline

Reference work entry

CAS Registry Number: 20411-03-4 Open image in new window

Taxonomy: Physicochemical and Pharmacological Properties of Alkaloids – Isoquinoline Alkaloids

Biological sources: Fumaria officinalis, F. vaillantii

C20H17NO5: 351.1107

Mp: 137–138°C [1]

[α]D+66° (EtOH) [1]

UV: 203, 237, 263, 294, 355(4.60, 4.31, 4.05, 3.66, 3.51) [2]

IR: 1709, 1040, 940 [2]

MSm/z: 351(M+), 336, 322(100), 308, 293, 264, 175, 135 [2]

1H NMR: 2.36(3H, s, NCH3), 2.60–3.60(6H, m), 5.80, 6.12(each 2H, s, 2 × CH2O2), 6.16, 6.54(each 1H, s, p–H–Ar), 6.86, 7.07(each 1H, d, J = 8, o–H–Ar) [2]

Abs. conf.: [3]

References

  1. 1.
    M. Alimova, I.A. Israilov, Chem. Nat. Comp. 17, 437 (1981)Google Scholar
  2. 2.
    J.K. Saunders, R.A. Bell, C.Y. Chen, D.B. McLean, R.H.F. Manske, Can. J. Chem. 46, 2873 (1968)Google Scholar
  3. 3.
    M. Shamma, J.L. Moniot, R.H.F. Manske, W.K. Chan, K. Nakanishi, J. Chem. Soc. Chem. Commun. 310 (1972)Google Scholar

Copyright information

© Springer Science+Business Media New York 2013

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