Chelilutine

Reference work entry

CAS Registry Number: 55950-32-8 Open image in new window

Taxonomy: Physicochemical and Pharmacological Properties of Alkaloids – Isoquinoline Alkaloids

Biological sources: Eschscholtzia californica

C22H20N+O5: 378.1342

Mp: 186°C (chloride)

UV(chloride): 230, 241 sh, 280, 340, 420 sh, 470 [1]

IR(chloride): 3640, 3580, 3370, 3260, 1660, 1567, 1549, 1508, 1493, 1330, 1302, 1268, 1237, 1218, 1210, 1143, 1133, 1095, 1078, 1044, 1032, 1018, 990, 954, 941, 918, 888, 872, 864, 846, 818, 784, 755, 745, 733, 722, 709 [1]

1H NMR(DMSO, γ-CN): 2.56(3H, s, NCH3), 3.85(6H, s, 2 × OCH3), 3.98(3H, s, OCH3), 5.88(1H, s), 6.18(2H, s, CH2O2), 6.96, 7.35, 7.57(each 1H, s, 3 × H–Ar), 7.63, 8.33(each 1H, d, J = 8, o-H–Ar) [1]

HPLC: [2]

References

  1. 1.
    B.D. Krane, M.O. Fagbule, M. Shamma, B. Gozler, J. Nat. Prod. 47, 1 (1984)Google Scholar
  2. 2.
    N. Chauret, D. Rho, J. Archambault, J. Chromatogr. 519, 99 (1990)Google Scholar

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© Springer Science+Business Media New York 2013

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